排序方式： 共有4条查询结果，搜索用时 375 毫秒
1
1.
Partition, not kinetics, ultimately determines the concentration of highly soluble gases in cloud droplets. Partition equations are formulated and applied to idealized air-mass thunderclouds and precipitating stratus. Contribution to aqueous concentrations from sub-cloud scavenging of highly soluble gases is estimated at between 10 and 20% under relatively unpolluted conditions. Data indicate that evaporation can produce enhancements in concentration of as much as a factor of 3. The calculations give large-scale mean coefficients of wet removal of highly soluble gases of about 2.8×10-6 s-1 (4-day residence time) for air-mass thunderclouds and precipitating stratus. Removal is so effective that the mean scale heights of these gases should be decreased to 2 km or less. The criterion of high solubility in this paper is that K
H (Henry's Law coefficient) > 105 mol l-1 atm-1. Gases that are effectively highly soluble include HCl, HNO3, H2SO4, H2O2, NH3 in acid droplets, SO2 in oxidizing droplets (and probably some light amines and sulfonic acids), but not SO2 in the absence of oxidants, nor HCHO. A variation of removal coefficient and scale height with solubility is presented. A comparison of atmospheric NH3 concentrations deduced from rain NH4
+ and measured directly gives reasonable agreement. 相似文献
2.
Jeerapong Laonamsai Kimpei Ichiyanagi Supapap Patsinghasanee Kiattipong Kamdee 《水文研究》2021,35(7):e14202
This study examined the weekly water vapour isotopic composition (δ18Ov) in Thailand. The water vapour was cryogenically collected from eight sites across the country. Two observational samples were collected over one 24-h period each week (a daytime and a night-time sample), from September 2013 to September 2014. The primary aim was to investigate the environmental factors influencing water vapour isotopes. The results revealed differences in water vapour isotopic values between day and night samples. Three periods of depleted δ18Ov were associated with large-scale convective systems in September, December, and May. The statistical relationship between the climate variables and water vapour isotopes indicated that the amount of precipitation and relative humidity were the primary controls on both diurnal and seasonal isotopic variability. The temperature did not affect the δ18Ov, mainly because the atmospheric processes are a function of vertical convection rather than temperature in tropical regions. The water vapour deuterium excess (d-excess) showed greater variability in 2013 than in 2014. The d-excess variation reflected the differences in convection occurring in the day and night. In addition, the vapour phase data were combined with the local meteoric water line to identify the local water vapour line and the interaction between the isotopic composition of water vapour and liquid water. The water vapour isotopic patterns paralleled the precipitation isotopes on rainy days because of equilibrium isotopic exchange. Water vapour and precipitation were isotopically similar under low humidity but showed greater differences from each other under wetter conditions. The study results provide insight into water vapour isotopic characteristics in tropical regions and constrain the role of large-scale atmospheric processes relative to isotopic variability of water vapour in Thailand and nearby countries. 相似文献
3.
The gas phase concentration of hydrogen peroxide at Summit, Central Greenland, has been measured continuously during June/July 1990 using a coil scrubber technique combined with liquid phase fluorometry. The concentrations ranged between 0.3 ppbv and 3.5 ppbv, which is considerably higher than expected from model calculations and can be explained by low deposition rates. The record shows pronounced diurnal variations with minimum concentrations during night and maximum concentrations in the afternoon. The nocturnal minima can be explained by scavenging of H2O2 by hoarfrost. The scavenging mechanisms of H2O2 by snow and the redistribution of H2O2 during firnification are discussed. There is indirect evidence, that H2O2 is uniformly distributed in the ice lattice and that the fractionation between H2O2 and H2O is small during diffusional crystal growth from the vapor phase (co-condensation). 相似文献
4.
A one-dimensional, time-dependent cloud model with parameterized microphysics is used to investigate the processes which control the rainout and washout of soluble gases from warm, precipitating stratiform clouds. Calculations are presented simulating the distributions of soluble species within and below the cloud layer and in the precipitating raindrops as a function of time and species' solubility. Our calculations indicate that for species with low solubility, wet removal processes are relatively slow and thus do not significantly affect the species' gas-phase abundance. As a result, the removal of low-solubility species by rainout and washout is controlled by thermodynamic processes with the concentration of the species in cloud and rainwater largely determined by the species' solubility. For highly soluble species on the other hand, dissolution into cloud droplets and removal in rain is quite rapid and the abundance of highly soluble species within and below the cloud falls rapidly as soon as the precipitation begins. Because of this rapid decrease in concentration, we find that for highly soluble species: concentrations in cloud droplets near the cloud base can exceed that of raindrops by factors of 2 to 10; washout can dominate over rainout as a removal mechanism; and that, after an extended period of rainfall, the rate of removal becomes independent of the microphysical properties and rainfall rate of the cloud and is controlled by the rate of transport of material into the precipitating column by horizontal advection. 相似文献
1