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1.
An Atomic Force Microscopy study of the growth of calcite in the presence of sodium sulfate 总被引:1,自引:0,他引:1
Aikaterini I. Vavouraki Christine V. Putnis Andrew Putnis Petros G. Koutsoukos 《Chemical Geology》2008,253(3-4):243-251
In situ atomic force microscopy (AFM) has been used to compare the growth of pure calcite and the growth of calcite in the presence of sulfate ions from aqueous solutions at a constant value of supersaturation (S.I. = 0.89) with respect to calcite. The effect of sulfate ions on calcite growth rates is determined and a potential incorporation of sulfate ions is identified in the calcite during growth. Solutions supersaturated with respect to calcite with solution concentration ratio of one and a constant pH of 10.2, were prepared and sulfate was added as Na2SO4 aqueous solution. The solution composition was readjusted in order to keep the supersaturation and pH constant. PHREEQC was used to determine relevant solution concentrations. In situ AFM experiments of calcite growth were performed using a fluid cell and flowing solutions passed over a freshly cleaved calcite surface. Growth rates were determined from the closure of the rhombohedral etch pits induced by initial dissolution with pure water. The spreading rate of 2-dimensional nuclei was also measured. At low concentrations of sulfate (≤ 0.5 mM), no effect on the growth rate of the calcite was observed. At higher concentrations (2 to 3 mM) of sulfate, the growth rate increased, possibly because a higher concentration of calcium and carbonate was necessary to maintain the supersaturation constant. At much higher concentrations of additional sulfate (up to 60 mM) the growth rate of the calcite was substantially decreased, despite the fact that a further increase of calcium and carbonate was required. The morphology of 2-dimensional growth nuclei became increasingly elongated with increasing sulfate content. Measurements of step height showed that newly grown steps were approximately 1 Å higher when grown in high sulfate concentrations, compared to steps grown in sulfate-free solutions. At sulfate concentrations above 5 mM the growth mechanism changes from layer growth to surface roughening. These observations suggest that the new growth has incorporated sulfate into the calcite surface. 相似文献
2.
The atomic force microscopy (AFM) is a recently developed, bench-top instrument that can image the surface structures of biological
specimens at high resolution with simultaneous measurement of their size. This paper describes the application of AFM to marine
bacteria. Both natural and cultured bacteria were retained on a filter or placed on glass, washed, air-dried and observed
by AFM. The instrumental condition, the choice of suitable filter, effect of fixation and filtration, comparison with epifluorescent
microscopic (EFM) count, and the size and shape of bacterial cells were investigated. An Isopore filter was best for concentration
and subsequent observation because of its surface flatness. Cross section images showed that both rod and coccoid cells were
flattened, the former usually having a two-humped shape. Bacterial cells were differentiated from non-living particles based
on their cross section shape and size. Bacterial counts by AFM and EFM showed good agreement. Although size measurement is
easily done by the instrument, AFM tends to overestimate the size of microspheres. More work is thus needed on the size measurement
of living organisms. Because AFM easily provides images of natural bacterial cells at high magnification, it can be used as
a new tool to study the fine structures of marine bacteria.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
3.
封闭体系有机质与有机碳氢氮恢复动力学研究 总被引:3,自引:0,他引:3
在封闭体系的条件下,对典型的Ⅰ、Ⅱ、Ⅲ型干酪根在热演化过程中的损失进行生烃动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。用Kinetics软件计算了封闭体系干酪根有机碳丰度、氢碳原子比和氮碳原子比的恢复系数。认为在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要恢复。三种类型干酪根的氢碳原子比均需要进行恢复。 相似文献
4.
多层螺旋CT肝脏三期增强扫描质量评价的探讨 总被引:3,自引:0,他引:3
多层螺旋CT和高压注射器的应用,使全肝动态多期增强扫描成为可能,但具体应用中,要想获得满意的肝脏三期增强效果,技术因素和患者因素也不容忽视。本文从科室影像服务器中提取在线的肝脏三期增强影像资料26例进行主观评价和CT值测量分析,结果表明,所有病例影像显示均无不满意评价,其中门脉期和实质期显示满意率均为100%,但动脉期显示满意率为65.4%,由此看出肝脏三期增强扫描的技术难点在动脉扫描时机的把握上,能否正确设置造影剂注射后的扫描延迟时间至关重要,文中对能够影响扫描延迟时间的因素进行说明并提出相应操作对策。 相似文献
5.
关于绝对重力仪的发展和我们的思考 总被引:1,自引:3,他引:1
介绍了近年来出现的新型绝对重力仪,认为该仪器是控制地球重力场信息的重要工具,特别对FG5型的如何改进及我国绝对重力仪的如何发展,提出了建议。 相似文献
6.
The annual and semi-annual variations of the ionosphere are investigated in the present paper by using the daytime F2 layer peak electron concentration (NmF2) observed at a global ionosonde network with 104 stations. The main features are outlined as follows. (1) The annual variations are most pronounced at magnetic latitudes of 40–60° in both hemispheres, and usually manifest as winter anomalies; Below magnetic latitude of 40° as well as in the tropical region they are much weaker and winter anomalies that are not obvious. (2) The semi-annual variations, which are usually peak in March or April in most regions, are generally weak in the near-pole regions and strong in the far-pole regions of both hemispheres. (3) Compared with their annual components, the semi-annual variations in the tropical region are more significant.In order to explain the above results, we particularly analyze the global atomic/molecular ratio of [O/N2] at the F2 layer peak height by the MSIS90 model. The results show that the annual variation of [O/N2] is closely related with that of NmF2 prevailing in mid-latitudes and [O/N2] annual variation usually may lead to the winter anomalies of NmF2 occurring in the near-pole region. Moreover, NmF2 semi-annual variations appearing in the tropical region also have a close relationship with the variation of [O/N2]. On the other hand, the semi-annual variations of NmF2 in the far-pole region cannot be simply explained by that of [O/N2], but the variation of the solar zenith angle may also have a significant contribution. 相似文献
7.
石墨炉原子吸收分光光度法测定土壤样品中痕量镉 总被引:2,自引:0,他引:2
研究了土壤样品中痕量镉的石墨炉原子吸收分光光度法测定最佳条件以及磷酸二氢铵与硝酸镁作基体改进剂对测定镉的基体改进效应,并比较了两种试样分解体系。方法检出限为0.01pg/L,精密度(RSD,n=8)为3.29%-7.69%,经国家一级标准物质分析验证,结果与标准值符合。 相似文献
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10.
正20140786Deng Zhenping(Institute of Karst Geology,Chinese Academy of Geological Sciences,Guilin 541004,China);Yang Wen-qiong Application of Stripping Voltammetry with a Solid Amalgam Electrode for Determination of Copper in a Tracer and Groundwater Tracing Experiment(Rock and Mineral Analy- 相似文献