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1.
Eleven surface soil samples from calcareous soils of industrial areas in Hamadan Province, western Iran were analyzed for
total concentrations of Zn, Cd, Ni, Cu and Pb and were sequentially extracted into six fractions to determine the bioavailability
of various heavy metal forms. Total Zn, Cd, Ni, Cu and Pb concentrations of the contaminated soils were 658 (57–5,803), 125.8
(1.18–1,361), 45.6 (30.7–64.4), 29.7 (11.7–83.5) and 2,419 (66–24,850) mg kg−1, respectively. The soils were polluted with Zn, Pb, and Cu to some extent and heavily polluted with Cd. Nickel values were
not above regulatory limits. Copper existed in soil mainly in residual (RES) and organic (OM) fractions (about 42 and 33%,
respectively), whereas Zn occurred essentially as RES fraction (about 69%). The considerable presence of Cd (30.8%) and Pb
(39%) in the CARB fraction suggests these elements have high potential biavailability and leachability in soils from contaminated
soils. The mobile and bioavailable (EXCH and CARB) fractions of Zn, Cd, Ni, Cu, and Pb in contaminated soils averaged (7.3,
40.4, 16, 12.9 and 40.8%), respectively, which suggests that the mobility and bioavailability of the five metals probably
decline in the following order: Cd = Pb > Ni > Cu > Zn. 相似文献
2.
干旱区绿洲土壤共存重金属元素形态变化及生物有效性实验分析——以Cd、Zn、Ni元素为例 总被引：3，自引：0，他引：3
采用盆栽试验,初步研究了干旱区绿洲土壤—胡萝卜系统中镉、锌、镍3种重金属的形态变化特征及其生物有效性问题。结果表明:供试绿洲土壤原状土中,Cd、Zn、Ni均以稳定的残渣态形式存在,而处理土壤中重金属被钝化的量有限,Cd的存在形式主要以碳酸盐态为主,Zn、Ni则主要以铁锰氧化态为主;3种元素的活性大小依次为Cd>Ni>Zn。根据回归分析,元素Zn对胡萝卜块茎和茎叶吸收Zn量贡献最大的分别是Zn的碳酸盐结合态和铁锰氧化态;元素Ni对胡萝卜各部位吸收贡献最大的均为Ni的铁锰氧化态。 相似文献
3.
Partitioning,bioavailability and origin of heavy metals from the Nador Lagoon sediments (Morocco) as a basis for their management 总被引：2，自引：0，他引：2
Nador Lagoon sediments show low trace element concentrations, and, in relation to the lagoon geochemical baseline, only some
anomalies for As, Cd, Cu and Pb in the NW of the lagoon deserve to be outstanding. The distribution of major, minor and trace
elements in the lagoon allows a breakdown in four zones. Between “Beni Ensar” and “Atelouane” (zone A), a quite confined zone
rich in organic matter and S, the most important trace-element anomalies (As, Cd, Co, Cu, Mn, Pb, Zn) were found, mainly around
industry and old mining activities. In the surrounding of the city of Nador (zone B), the anomalies correspond to Mn, Cu and
Zn. The coastal barrier and Kebdana channel (zone C) show moderately concentrations of Cd, Cr and Ni at specific sites. The
less polluted area is the SE of the lagoon (zone D), with no outstanding anomaly. In lagoon sediments, metal bioavailability
is very low. The metal partitioning patterns show that Cu, Pb and Zn present a low availability because they are bounded to
the residual, non-mobile phases of the sediments. Only in some sites, the fraction was associated with organic matter, which
could be liberated easily. Arsenic is concentrated in both the residual phases and the organic matter, the latter being more
available. Cadmium is mainly concentrated in some samples in the interchangeable fraction, which could be considered as a
potentially toxic element because it is easily released. Concerning the origin of these trace elements, those found in zone A
correspond mostly to a natural source by weathering of mount Gourougou volcanic rocks (As, Co, Cu, Pb and Zn), and to an anthropogenic
origin (Cd) owing to the presence of industry and old mines. In zone B, contributions of Cu and Zn enter the lagoon through
soil weathering and river-borne, and as anthropogenic pollution from urban wastes. In zone C the most important pollutant
is Cd deduced to be of anthropogenic origin from the close industry and intensive agriculture area. In spite of the intense
socio-economic activities developed in the Nador Lagoon (agriculture, industry, fishing, tourism) trace element concentrations
in the sediments are low and with scarce bioavailability. Only the NW sector is relativity polluted because of geogenic features. 相似文献
4.
Bioconcentration of heavy metals in aquatic environments: the importance of bioavailability 总被引：2，自引：0，他引：2
The importance of heavy metal bioavailability on the bioconcentration in aquatic biota is examined. To this purpose, mono- and multivariate statistical techniques are applied to develop correlations between heavy metal bioconcentration factor and sediment characteristics, that are expected to affect bioavailability, using a database of heavy metal concentrations in biota and sediment along with the available physicochemical characteristics. The statistical analysis shows that satisfactory correlations are obtained only when factors that affect bioavailability, such as metal oxides concentration and organic carbon content in the sediment, are taken into account. 相似文献
5.
Dissolved total carbohydrates (DTCH), dissolved free monosaccharides (DFMS), dissolved organic carbon (DOC), biodegradable DOC (BDOC), and humic substances (HS) were measured in White Clay Creek (WCC), a stream in southeastern Pennsylvania Piedmont, USA. Samples were collected over different seasons and under baseflow and stormflow conditions. DOC concentrations ranged from 1.0 to 12.8 mg/L C with the highest concentrations associated with stormflows. Carbohydrates ranged from 0.42 to 12.4 μM and accounted for 2.9 to 12.7% of the DOC. Humic substances represented the major DOC fraction, accounting for 55 to 72% of the DOC pool under all flow conditions. The humic fraction had a lower carbohydrate content (4.4%) than the non-humic fraction of DOC (7.2%). Stormflow DOC was enriched in carbohydrates relative to baseflow DOC, but the percentage of humic-C changed little. Carbohydrates were primarily present as dissolved polysaccharides (55%), but a significant fraction was bound to humic substances (40%), while a small proportion was present as monosaccharides (5%). The major monosaccharides in stream water, listed in order of decreasing concentration, included glucose, galactose, rhamnose, xylose, arabinose, mannose, and fucose. On average (30.6 ± 7.4)% (n = 44) of the stream water DOC was biodegradable, and carbohydrates accounted for 9.9 to 17.7% of the BDOC. 相似文献
6.
Stable-isotope fractionation has become an established method for the assessment of contaminant biodegradation in groundwater. At the pore scale however, mass-transfer processes can limit the bioavailability of chemical species and therefore affect the observed fractionation. This can challenge the application of stable-isotope analysis in practice. A linear-exchange model provides a computational link between the microbially-induced isotope fractionation, determined under ideal conditions, and the fractionation observed under conditions of limited bioavailability. This simplifying conceptual approach allows for accurately estimating the mass-transfer limited degradation rates but its applicability for stable-isotope fractionation at the pore scale has not been evaluated yet. In this study, we perform high-resolution numerical simulations of microbial degradation and stable-isotope fractionation of a chemical species in a pore-scale model. The numerical results are compared to theoretical predictions derived from the linear-exchange model. Our results show an overall good agreement between numerical simulations and theoretical predictions, which confirms the applicability of the theoretical approach and of the value for the mass-transfer coefficient previously derived from the geometry of the pore space. In addition we provide a quantitative link between the value of the observable fractionation factor and the effective bioavailability of a biodegradable contaminant. 相似文献
7.
8.
Dissolved aluminium (Al) is generally at low concentrations in neutral freshwater due to its insolubility. However, a fall in pH resulting from acid deposition and mining alters the mobility of Al and so entry to adjacent neutral waters. The present study examines the environmental behaviour, cell-associated surface adsorption/absorption and toxicity of Al at neutral pH to the alga Chlamydomonas gigantea in the presence and absence of the key Al-binding ligand silica. We then examined transfer of Al from C. gigantea to the planktonic crustacean Daphnia pulex. Finally, the effect of Al on the elemental composition (and hence nutritional value) of the two organisms was compared to unexposed controls. C. gigantea increased the amount of Al in the algal culture medium. Binding of Al to extracellular glycoprotein is probably the reason why only one-third of the biosorbed Al was absorbed (accumulated) by C. gigantea. Aluminium concentrations between 50 and 500 μg l−1 reduced growth of C. gigantea at 16 days exposure to the metal. Silica reduced biosorption, accumulation and toxicity of Al by C. gigantea. The concentration of Al in D. pulex fed Al-contaminated C. gigantea for 16 days did not differ from those fed alga grown in the absence of added Al. C. gigantea contaminated with Al contained less sulphur, magnesium, potassium and sodium although only sulphur fell in D. pulex subsequently fed the contaminated alga. Chloride, calcium, iron and silicon were significantly higher in D. pulex. 相似文献
9.
The bioavailability of field‐aged Cd and Cu was calculated, and compared to the total concentrations determined by acid digestion. Only 0.60–4.15% for Cd and 0.59–9.43% for Cu were found to be bioavailable when determined by stomach‐phase extraction. The incorporation of bioavailability reduced more than 90% of the calculated risk of the metals at the site of study. It should be noted that such a reduction may not be generalized and the site‐specific bioavailability needs to be determined case by case. 相似文献
10.
采用野外连续调查和实验分析方法,连续3年研究了海三菱藨草根际沉积物重金属（Cu、Zn、Pb和Cd）生物有效性的主要影响因素（生长季节、pH、P、Eh和DO等）。结果表明,植物不同生长季节的变化影响根际沉积物生物有效性的季节变化。具体表现为：Cu和Pb均在春、夏季可交换态含量较高,生物有效性较高,而秋、冬季可交换态较低,生物有效性较低,但碳酸盐结合态和铁锰氧化态二者之和也比较高,具有一定的潜在生物有效性;Zn在任何季节的可交换态比例均不高,以有机结合态和残渣态的形态为主,生物有效性较低;Cd一般以残渣态为主,基本不具有生物有效性。pH值下降,春、夏季可交换态和铁锰氧化物结合态增加,而有机结合态和碳酸盐结合态减少,提高了生物有效性,而秋、冬季正好相反;磷对重金属生物有效具有直接影响的为无机磷,春、夏季随着无机磷的减少,pH值下降,提高了生物有效性。春、夏季根际Eh和溶解氧含量增加,降低了其生物有效性。 相似文献