Optical properties of low molecular weight and colloidal organic matter: Application of the ultrafiltration permeation model to DOM absorption and fluorescence   总被引：4，自引：1，他引：4  

Claude Belzile  Laodong Guo   《Marine Chemistry》2006,98(2-4):183-196

Cross-flow ultrafiltration (CFF) is often used to obtain separation and concentration of colloids from bulk natural water samples. Application of the ultrafiltration permeation model allows the quantitative determination of the low molecular weight material (LMW, < 1 kDa) and colloids in bulk dissolved organic matter (DOM) from measurements of time series permeate samples obtained from CFF. Detailed analysis of a Yukon River water sample shows that DOM absorption coefficient and fluorescence follow the permeation model and that the complex spectral optical properties of LMW DOM can be reconstructed from CFF data. A combination of measured and modeled data indicates that the LMW contribution to bulk DOM optical properties obtained from CFF can be grossly underestimated by the use of a low concentration factor (CF, the ratio of initial sample volume to retentate volume). Even at a relatively high CF of 19, optical properties of LMW DOM calculated from measurements of the retentate or integrated permeate would underestimate true values by 5–36%. In the Yukon River sample, LMW dissolved organic carbon represented 26% of the bulk concentration, but only 3–14% of the colored DOM was in the LMW fraction while 31–33% of bulk DOM florescence was due to LMW DOM. The contrasting optical properties of LMW and colloidal DOM support the concept that analysis of bulk DOM absorption and fluorescence properties reveals information about DOM molecular weight.  相似文献   

Patterns of dissolved organic matter in subarctic peatlands     

T. R. Moore 《地球表面变化过程与地形》1987,12(4):387-397

Samples of water from poor to very rich fens in the Schefferville region of subarctic Quebec revealed strong spatial and temporal variations in dissolved organic carbon (DOC), ranging from 2 to 40 mg 1^?1. Concentrations of DOC tend to increase during the summer and decrease in the autumn, at most sites, which probably reflects increased plant tissue decomposition and higher rates of evapotranspiration. Principal components analysis revealed that DOC is strongly associated with Fe, NO^?₃-N and NO^?₂-N, but essentially independent of other chemical properties of the peat water, such as pH, Ca, Mg, K, P, and NH⁺₄-N. Based on observed concentrations of DOC and estimates of summer runoff (June to September), export of DOC from four peatlands ranges from 1·1 to 4·9 gCm^?2, with the lowest values for peatlands underlain by dolomite. Molecular weight fractionation of four samples revealed significant differences in the dissolved organic matter (DOM), with the largest fractions (GF/C to 10 000 nmw) being dominant in the more acid samples. The ratio of absorbance at 400 and 600 nm wavelengths (E₄:E₆) has been used as a simple indicator of differences in DOM type, ranging from 3 to 15. There is a strong seasonal pattern of increasing E₄:E₆ ratio during the summer at many sites, though this ratio is essentially independent of other chemical properties of peat waters.  相似文献   

Geobotanical and biogeochemical reconnaissance of the ultramafics of Central Iran     

S.M. Ghaderian  A.J.M. Baker 《Journal of Geochemical Exploration》2007

In Iran, ultramafic rocks cover substantial areas at many locations in the country. These rocks consist predominantly of peridotite which has been serpentinized to some degree. Anarak and Nain are two ultramafic areas in Central Iran comprising about 180 and 270 km², respectively, located in a coloured melange zone. There is little information available regarding the geobotany and biogeochemistry of these areas. They have a dry climate, with low rainfall and high temperatures in summer which encourages mostly annual and perennial herbaceous types of plants. In this paper, we report a reconnaissance study of these two ultramafic areas of Iran. Soil analysis of total elements indicates that typical concentrations of Ni, Cr, Co, Mn, Fe, Mg and Ca are about 1500, 300, 75, 800, 45.000 150.000 and 2000 μg g^− 1, respectively. During this study 176 plant species were collected, belonging to 29 families. The species diversity at Anarak is more than at Nain, possibly due to microclimatic differences and a greater precipitation. The number of plants endemic to ultramafic soils of these two areas is very low. The herb Cleome heratensis (Capparaceae) appears to be an indicator of ultramafics in Central Iran. Populations of this plant cover quite extensive areas during summer and autumn when there is no rainfall. Analysis of the dry matter of the leaves of all plants collected did not reveal any hyperaccumulator of nickel or any other ‘serpentine’ metals. The ultramafic endemic plant C. heratensis contained low concentrations of all metals and thus it possesses exclusion mechanisms to restrict excessive metal uptake. The Mg/Ca ratio for some plants collected is high—up to 4.9. This initial survey suggests that a more complete investigation of the ultramafic areas of Iran would be valuable.  相似文献   

Benthic nitrate biogeochemistry affected by tidal modulation of Submarine Groundwater Discharge (SGD) through a sandy beach face, Ria Formosa, Southwestern Iberia     

C. Rocha  J. Ibanhez  C. Leote   《Marine Chemistry》2009,115(1-2):43-58

To investigate both the role of tides on the timing and magnitude of Submarine Groundwater Discharge (SGD), and the effect on benthic nitrogen biogeochemistry of nitrate-enriched brackish water percolating upwards at the seepage face, we conducted a study of SGD rates measured simultaneously with seepage meters and mini-piezometers, combined with sets (n = 39) of high resolution in-situ porewater profiles describing NH₄⁺, NO₃⁻, Si(OH)₄ and salinity distribution with depth (0–20 cm). Sampling took place during two consecutive spring tidal cycles in four different months (November 2005, March, April and August 2006) at a backbarrier beach face in the Ria Formosa lagoon, southern Portugal. Our results show that the tide is one of the major agents controlling the timing and magnitude of SGD into the Ria Formosa. Intermittent pumping of brackish, nitrate-bearing water at the beach face through surface sediments changed both the magnitudes and depth distributions of porewater NH₄⁺ and NO₃⁻ concentrations. The most significant changes in nitrate and ammonium concentrations were observed in near-surface sediment horizons coinciding with increased fraction of N in benthic organic matter, as shown by the organic C:N ratio. On the basis of mass balance calculations executed on available benthic profiles, providing ratios of net Ammonium Production Rate (APR) to Nitrate Reduction Rate (NRR), coupled to stoichiometric calculations based on the composition of organic matter, potential pathways of nitrogen transformation were speculated upon. Although the seepage face occasionally contributes to reduce the groundwater-borne DIN loading of the lagoon, mass balance analysis suggests that a relatively high proportion of the SGD-borne nitrogen flowing into the lagoon may be enhanced by nitrification at the shallow (1–3 cm) subsurface and modulated by dissimilatory nitrate reduction to ammonium (DNRA).  相似文献   

Dimethylsulfide production in Sargasso Sea eddies     

K.E. Bailey  D.A. Toole  B. Blomquist  R.G. Najjar  B. Huebert  D.J. Kieber  R.P. Kiene  P. Matrai  G.R. Westby  D.A. del Valle 《Deep Sea Research Part II: Topical Studies in Oceanography》2008,55(10-13):1491

Lagrangian time series of dimethylsulfide (DMS) concentrations from a cyclonic and an anticyclonic eddy in the Sargasso Sea were used in conjunction with measured DMS loss rates and a model of vertical mixing to estimate gross DMS production in the upper 60 m during summer 2004. Loss terms included biological consumption, photolysis, and ventilation to the atmosphere. The time- and depth (0–60 m)-averaged gross DMS production was estimated to be 0.73±0.09 nM d⁻¹ in the cyclonic eddy and 0.90±0.15 nM d⁻¹ in the anticyclonic eddy, with respective DMS replacement times of 5±1 and 6±1 d. The higher estimated rate of gross production and lower measured loss rate constants in the anticyclonic eddy were equally responsible for this eddy's 50% higher DMS inventory (0–60 m). When normalized to chlorophyll and total dimethylsulfoniopropionate (DMSP), estimated gross production in the anticyclonic eddy was about twice that in the cyclonic eddy, consistent with the greater fraction of phytoplankton that were DMSP producers in the anticyclonic eddy. Higher rates of gross production were estimated below the mixed layer, contributing to the subsurface DMS maximum found in both eddies. In both eddies, gas exchange, microbial consumption, and photolysis were roughly equal DMS loss terms in the surface mixed layer (0.2–0.4 nM d⁻¹). Vertical mixing was a substantial source of DMS to the surface mixed layer in both eddies (0.2–0.3 nM d⁻¹) owing to the relatively high DMS concentrations below the mixed layer. Estimated net biological DMS production rates (gross production minus microbial consumption) in the mixed layer were substantially lower (by almost a factor of 3) than those estimated in a previous study of the Sargasso Sea, which may explain the relatively low mixed-layer DMS concentrations found here during July 2004 (3 nM) compared to previous summers (4–6 nM).  相似文献   

Enhanced concentrations of dissolved gaseous mercury in the surface waters of the Arctic Ocean   总被引：2，自引：0，他引：2  

M.E. Andersson  J. Sommar  K. Grdfeldt  O. Lindqvist 《Marine Chemistry》2008,110(3-4):190-194

During an almost three months long expedition in the Arctic Ocean, the Beringia 2005, dissolved gaseous mercury (DGM) was measured continuously in the surface water. The DGM concentration was measured using an equilibrium system, i.e. the DGM in the water phase equilibrated with a stream of gas and the gas was thereafter analysed with respect to its mercury content. The DGM concentrations were calculated using the following equation, DGM = Hg_eq / k_H' where Hg_eq is the equilibrated concentration of elemental mercury in the gas phase and k_H' is the dimensionless Henry's law constant at desired temperature and salinity. During the expedition several features were observed. For example, enhanced DGM concentration was measured underneath the ice which may indicate that the sea ice acted as a barrier for evasion of mercury from the Arctic Ocean to the atmosphere. Furthermore, elevated DGM concentrations were observed in water that might have originated from river discharge. The gas-exchange of mercury between the ocean and the atmosphere was calculated in the open water and both deposition and evasion were observed. The measurements showed significantly enhanced DGM concentrations, compared to more southern latitudes.  相似文献   

Flood pattern and weather determine Populus leaf litter breakdown and nitrogen dynamics on a cold desert floodplain     

D.C. Andersen  S.M. Nelson 《Journal of Arid Environments》2006,64(4):626-650

Patterns and processes involved in litter breakdown on desert river floodplains are not well understood. We used leafpacks containing Fremont cottonwood (Populus deltoides subsp. wislizenii) leaf litter to investigate the roles of weather and microclimate, flooding (immersion), and macroinvertebrates on litter organic matter (OM) and nitrogen (N) loss on a floodplain in a cool-temperate semi-arid environment (Yampa River, northwestern Colorado, USA). Total mass of N in fresh autumn litter fell by 20% over winter and spring, but in most cases there was no further N loss prior to termination of the study after 653 days exposure, including up to 20 days immersion during the spring flood pulse. Final OM mass was 10–40% of initial values. The pattern of OM and N losses suggested most N would be released outside the flood season, when retention within the floodplain would be likely. The exclusion of macroinvertebrates modestly reduced the rate of OM loss (by about 10%) but had no effect on N dynamics over nine months. Immersion in floodwater accelerated OM loss, but modest variation in litter quality did not affect the breakdown rate. These results are consistent with the concept that decomposition on desert floodplains progresses much as does litter processing in desert uplands, but with periodic bouts of processing typical of aquatic environments when litter is inundated by floodwaters. The strong dependence of litter breakdown rate on weather and floods means that climate change or river flow management can easily disrupt floodplain nutrient dynamics.  相似文献   

Speleothems from Mawsmai and Krem Phyllut caves,Meghalaya, India: some evidences on biogenic activities     

Sushmitha Baskar  R. Baskar  Natuschka Lee  P. K. Theophilus 《Environmental Geology》2009,57(5):1169-1186

The Mawsmai cave and Krem Phyllut caves, East Khasi hills, Meghalaya, India has so far not yet attracted the attention of geomicrobiologists. Observations and hypotheses on the possible influence of identified microorganisms for speleothem formations in Meghalaya are reported for the first time. XRD studies identified calcite in speleothems and gypsum in cave wall deposits as the dominant minerals. SEM-EDAX showed interesting microfabric features showing strong resemblance with fossilised bacteria, calcified filaments, needle calcite and numerous nano scale calcite crystals, highly weathered and disintegrated crystals of calcite, that point towards a significant microbial influence in its genesis. Thin section petrography showed laminated stromatolitic features. The microorganisms identified by conventional isolation and further evaluation of isolates by molecular techniques include Bacillus cereus, Bacillus mycoides, Bacillus licheniformis, Micrococcus luteus, and Actinomycetes. Microscopic observations also showed unidentifiable cocci and four unidentifiable strains of CaSO₄ (gypsum) precipitating bacteria. Experimental studies confirmed that these bacteria are able to precipitate calcium minerals (calcite, gypsum, minor amounts of dolomite) in the laboratory. These results allow us to postulate that species like these may contribute to active biogenic influence in the cave formations at Meghalaya.  相似文献   

Global change and the biogeochemistry of the North Sea: the possible role of phytoplankton and phytoplankton grazing     

Justus E. E. van Beusekom  Sabine Diel-Christiansen 《International Journal of Earth Sciences》2009,98(2):269-280

Phytoplankton plays a dominant role in shelf biogeochemistry by producing the major part of organic matter. Part of the organic matter will reach the sediment where diagenetic processes like denitrification, apatite formation or burial will remove nutrients from the biogeochemical cycle. In this article current knowledge on the decadal plankton variability in the North Sea is summarized and possible implications of these changes for the biogeochemistry of the North Sea are discussed. Most of the observed interdecadal dynamics seem to be linked to large-scale oceanographic and atmospheric processes. Prominent changes in the North Sea ecosystem have taken place around 1979 and 1988. In general, the phytoplankton color (CPRS indicator of phytoplankton biomass) reached minimum values during the end of the 1970s and has increased especially since the mid 1980s. Changes with a similar timing have been identified in many time series from the North Sea through the entire ecosystem and are sometimes referred to as regime shifts. It is suggested that the impact of global change on the local biogeochemistry is largely driven by the phyto- and zooplankton dynamics during spring and early summer. At that time the extent of zooplankton–phytoplankton interaction either allows that a large part of the new production is settling to the sediment, or that a significant part of the new production including the fixed nutrients is kept within the pelagic system. The origin of the extent of the phytoplankton–zooplankton interaction in spring is probably set in the previous autumn and winter. In coastal areas, both large-scale atmospheric and oceanographic changes as well as anthropogenic factors influence the long-term dynamics. Due to eutrophication, local primary production nowadays still is up to five times higher than during pre-industrial conditions, despite a decreasing trend. Recently, introduced species have strengthened the filter feeder component of coastal ecosystems. Especially in shallow coastal seas like the Wadden Sea, this will enhance particle retention, shift organic matter degradation to the benthic compartment and enhance nutrient removal from the biogeochemical cycle by denitrification or apatite formation.  相似文献   

Assessment of iron(II) binding by a cryptoendolithic bacterial community: Implications for iron cycling in the Jurassic Navajo Sandstone     

《Journal of Arid Environments》2013

Previous work showed the cryptoendolithic microbial communities of the Colorado Plateau act to harden the surfaces of Jurassic Navajo Sandstone outcrops via the production of extracellular polymeric substances (EPS). It is our hypothesis that EPS produced in these systems serve to trap ions and maintain hydration. EPS isolated from in vitro and in vivo biofilms bind 200–600 nmol of ferrous iron per 10 g of biofilm sample. Initial characterizations of the EPS used preparations from two distinct microbial cultures grown in semi-submerged conditions with EPS harvested from approximately one-half of each culture immediately, the remaining biofilm was allowed to dry before the EPS was harvested. Analysis of ferrous iron binding of the four preparations showed that the culture dominated with non-filamentous cells only produced a chelating moiety after desiccation. Conversely, the second culture dominated by filamentous cells produced a ferrous iron binding activity when semi-submerged. Biochemical characterization showed that the extracted EPS was acidic, containing 37% uronic acid. Neither the EPS nor the biofilms had the ability to retain water though an increase in the rate of water loss was noted. We conclude that EPS produced by these communities are involved in nutrient capture as well as stabilization.  相似文献