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The discharge of organic matter, nutrients, and heavy metals from the river Odra into the Baltic Sea is compared with the combined discharge of the same substances from other Polish rivers into the Baltic during 1988–1997. The impact of the summer flood of 1997 is also discussed. The discharges of organic matter, nitrogen and phosphorus compounds were closely correlated with the flow rate. The annual loads of these nutrients measured in 1988 and 1996 under similar flow conditions decreased by 15 to 40% in these rivers as a result of the reduction of point sources. A steady decrease in the heavy metal load, independent of weather conditions, has been recorded during the past decade. Zinc decreased by up to 85% in the Odra and 99% in the Wisła. Although the water outflow from the Odra was half that of the Wisła, it transported a proportionally higher load of chemical compounds. Despite the differences in flow rates, the contribution of both rivers to the total riverine phosphorus discharge was approximately the same. The total water outflow during the flood (from 1 July to 28 August 1997) increased by 65% near the mouth of the Odra in comparison to 1996. The phosphate discharge increased by 34%, that of nitrite nitrogen by 88%  相似文献   
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The distribution and fate of polycyclic aromatic hydrocarbons (PAHs) were investigated in surface sediments (0...2 cm) and fluffy layer material of the internal and external coastal waters of the Odra river estuary (north-eastern Germany). The area includes the Odra Lagoon (Oderhaff), the Greifswalder Bodden, the Pomeranian Bight, and the Arkona Basin. Elevated concentrations were observed in the surface sediments of the internal coastal waters with highest concentrations in the Odra Lagoon. This indicates a significant contribution of river discharge to the contamination of sediments with PAHs. During the exceptional Odra flood in the summer of 1997 significantly higher concentrations of PAHs were found in the fluffy layer material of the Odra Estuary. The distribution of the individual PAH compounds varies widely depending on their structure and molecular weight. A concentration gradient of the lower molecular weight PAHs was found from the Odra Lagoon to the open sea areas. The concentrations decreased rapidly from the Oder Haff to the Arkona Basin. These results were found in both sediments and fluffy layer material. This is attributed to the degradation of the lower molecular weight PAHs during transport from the urban regions to the sedimentation basins. A decrease of this magnitude was not found for the higher molecular weight PAHs (i.e. benzo(a)pyrene) due to their higher persistence. An enrichment of these compounds was measured in the Arkona Basin.  相似文献   
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