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Binding Character of Selected Elements in Acidic Mining Lake Sediments To investigate the vertical element distribution in an acidic mining lake the concentrations of selected elements were measured by ICP‐MS and ICP‐OES. By knowing the metal concentrations in different depths it is possible to divide these metals into three groups. While the concentrations of iron, manganese, and zinc decline with decreasing depth, those of aluminium, copper, and nickel rise up. For lead and cobalt no distinct tendency could be determined. The limit value for all measured elements was not exceeded in any sampling location. The binding character of the metals is, besides the seasonal conditions of the lake (circulation in spring and stagnation in summer), influenced by the sediment depth. The addition of Carbokalk® for lake water neutralization had no significant effect on binding character of the analyzed metals. The application of a sequential extraction procedure enabled a classification of the available metal binding forms. All analyzed metals occurred mainly in compounds which are difficult to mobilize and for environment only slightly available. 相似文献
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In this work a coupling method for the characterisation of colloid‐mediated transport of the metal(loid) species in porous media was developed. For this transport experiments quartz sand was used as column packing material and the synthetic three‐layer clay mineral laponite as model colloid. The determination of colloids was conducted by means of UV detection. The quantification of the metal(loid) ions was carried out in two different ways: (1) The fractions collected at the column outlet were analysed with an inductively coupled plasma mass spectrometer (ICP‐MS) (offline measurements); (2) the column system was directly coupled with ICP‐MS (online measurements). In the column experiments the influence of laponite colloids on the transport of Cu, Pb, Zn, Pt and As species was investigated. In the offline experiments as a consequence of dilution during sample preparation no metal(loid) species at the column outlet could be found. Unlike this the breakthrough of all metal(loid)s could be detected under the same experimental column conditions in the coupling experiments. This coupling technique offers the online detection of the metal species and colloidal particles with high resolution even at low concentrations and without any time‐consuming preparation. The coupling experiments have shown that the laponite particles accelerate the transport of the cationic metals. For anionic metal(loid) species no influence of laponite on their transport behaviour was found. 相似文献
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The present study elucidates the remediation of mine waters by means of geochemical barriers („active barriers“). Active barrier systems (ABS) are developed, which can prevent heavy metal dispersion by introducing the barrier into the mine. Therefore, low‐cost materials are investigated which can remove contaminants by chemical, and/or physical mechanisms from water. The materials investigated are industrial by‐products (e.g. fly ash, red mud, scale arrears), natural wastes (e.g. tree bark), and relatively cheap natural products (bentonite, zeolites). Red mud and fly ash show the best results for the removal of Zn, Cd, Ni, and Mn from model water. Cd seems to have the strongest binding of the investigated metals on the sorption sites. The main mechanisms of metal removal from solution in this case are sorption and precipitation. Both materials have very good sorption and acid neutralization capacities (ANC), but ANC seems to be the determining factor. 相似文献
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