排序方式: 共有1条查询结果,搜索用时 15 毫秒
1
1.
Color-change processes of a plinian pumice and experimental constraints of color-change kinetics in air of an obsidian 总被引:1,自引:0,他引:1
Mihoko Moriizumi Satoru Nakashima Satoshi Okumura Yuta Yamanoi 《Bulletin of Volcanology》2009,71(1):1-13
Colors of plinian pumices were measured by spectrocolorimetry, and their quantitative color parameters in the L*a*b* color
space were determined. A series of heating experiments of obsidian was conducted to simulate the color-change processes of
rhyolitic glasses. In these experiments, following three stages of color-change processes were observed. Stage I showed a
rapid b* (yellowishness) increase associated with fast dehydration controlled by water diffusivity (D
water). In stage II, a* (reddishness) increase was accompanied by Fe2+ decrease. Both a* increase and Fe2+ decrease can be simulated by a diffusion model. Obtained diffusivity D
oxidation were about two orders of magnitude smaller than D
water
. The a*-value increase after the oxidation in stage III appeared to be quasi-linear with time, indicating the zeroth order
reaction corresponding to the formation of hematite-like structures in rhyolitic glasses. The diffusion-limited a* increase
model in stage II was applied to a natural plinian pumice fall unit to evaluate time periods of color-change processes through
oxidation by air of fragmented rhyolitic materials. 相似文献
1