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Knowledge of shale poromechanical behavior is proven to be essential for various environmental issues such as deep geological storage of CO2, high level radioactive waste storage, oil field abandonment and so forth… This paper sets out the key points of shale experimental characterization within the framework of Biot's mechanics of fluid saturated porous solids. Shales are well known to present a more or less transverse isotropy. This paper describes a full methodology for ?dometric tests on such sensitive and weakly permeable material. To illustrate this methodology, measurements carried out on Tournemire argillite are proposed. A transverse isotropic poroelastic model is also used to give a more in depth understanding of the hydromechanical coupling. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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《Comptes Rendus Geoscience》2015,347(2):77-83
Bacterial activity in the near-field environment of radioactive waste disposal facilities in deep argillaceous rocks is currently under investigation. Bacterial development could be enhanced by the availability of low-molecular-weight organic acids (LMWOA) dissolved in the pore water of clayey rocks. This study firstly aimed at isolating and characterizing the LMWOA of the Toarcian argillite from the Tournemire Underground Research Laboratory (France, Aveyron). It also aimed at assessing the disturbing effects that could be induced by a disposal facility on the type and release of LMWOA (exposure to oxygen, alkaline pH, temperature increase). Under the experimental conditions investigated at 60 °C, the mean dissolved organic carbon (DOC) is about 15 mg L−1 with a LMWOA proportion of 35 %. The main LMWOA are composed of formate, fumarate, propionate, acetate, and lactate. DOC is mainly influenced by both temperature and pH increases, whereas the LMWOA type nature and release are more specifically affected by the exposure to oxygen. 相似文献
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中国南方震旦纪碎屑岩的成岩作用主要有压实和压溶、胶结和固结、重结晶、交代作用及自生矿物形成等,泥质岩的成岩作用主要为压实作用和成岩过程中粘土矿物的转化。其成岩过程可分为同生、成岩、后生、表生四个成岩作用阶段。在沉积盆地演化的不同阶段和处在盆地的不同部位,出现了不同的岩石类型,往往呈现各自的成岩作用变化特点。 相似文献
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巴音沟蛇绿混杂岩带中成薄层状产出的硅质岩、硅质泥岩的Si02：55．37％～91．19％,Al2O3含量较高,变化在3．07～17．66,TiO2=0．12～0．8,Al2O3与TiO2具有较好的正相关关系,表明它们含有较高比例的陆源泥质沉积物质。样品经北美页岩标准化的稀土模式呈现无Ce负异常（Ce／Ce^＊=1．03～1．45）的平坦稀土谱型,球粒陨石标准化稀土模式为轻稀土富集,Eu具明显负异常的右倾谱型。均显示与大陆边缘沉积硅质岩、硅质泥岩相似的稀土配分模式。它们的（La／Ce）N=0．62～0．92,V／Y=0．32～8．87,Th／U=2．99～6．45,表明这些硅质岩、硅质泥岩形成于与陆源物质输入密切相关的大陆边缘环境,综合大地构造背景、蛇绿岩带中超基性、基性岩元素地球化学以及年代学分析认为,蛇绿岩就位于早石炭世晚期,形成在大陆裂谷向大洋裂谷转换并形成小洋盆的环境。 相似文献
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为研究贵州北部马鬃岭铝土矿床中富锂铝质粘土岩的物源体系及其锂的来源,对出露于大竹园组顶部的该类岩石进行了锆石U-Pb定年、Lu-Hf同位素及锆石微量元素分析。分析结果表明富锂铝质粘土岩中碎屑锆石普遍发育岩浆振荡环带,为造山作用/弧作用相关的岩浆岩类锆石。碎屑锆石U-Pb年龄从早泥盆世到太古宙（411~3001 Ma）均有分布,具627~879 Ma和925~1018 Ma两个主峰及539~602 Ma一个次峰。εHf(t)值为-27.61~7.03之间,二阶段模式年龄（tDM2）分布在1242~3387 Ma之间。结合碎屑锆石U-Pb-Hf同位素、微量元素特征及区域地质对比,认为富锂铝质粘土岩中碎屑锆石最主要的初始物源区为南岭-云开地体、江南造山带西段新元古代岩浆岩,其锂可能来源于江南造山带西段桂北-黔东地区860~750 Ma的基性岩。 相似文献
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陕甘宁盆地泥质岩氧化物的比值及其古气候意义 总被引：2，自引：0，他引：2
应用泥质岩的多种氧化物比值,探讨了陕甘宁盆地石炭至侏罗纪的古气候状况及其演变规律,自中石炭世至中三叠世,再由晚三叠世至安定期,泥质岩的各种氧化物比值有着逐渐依次增大或减小的两个互不雷同的旋回,与之相应,以上时期反映在古气候上存在着由潮湿→半潮湿→半干燥的早、晚两个旋回。 相似文献
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For a potential geological barrier of high-level radioactive waste repositories in France, the long-term mechanical behavior of the Callovo-Oxfordian (COx) argillite is the most concern for engineers. In this paper, a micromechanical-based elasto-viscoplastic model is proposed, and its numerical realization is our main object. The COx argillite is considered as a three-phase composite consists of porous clay, quartz, and calcite. By assigning appropriate constitutive laws to those constituents, the macroscopic elasto-viscoplastic behavior of the COx argillite is determined with an extended Hill's incremental approach. The numerical aspects includes (a) a new formulation is proposed for the plastic multiplier when adopting the overstress (Perzyna) model to define the viscoplastic strain. Meanwhile, a new formulation is also proposed to solve it within the framework of an implicit returning mapping scheme. (b) The corresponding consistent tangent moduli are strictly derived by extending the method proposed for solving plastic problems; (c) the efficiency of the proposed integration algorithms for the local constitutive equations and the homogenization procedure are validated, receptively, by a built-in porous plasticity model of a commercial finite element (FE) program ABAQUS and by FE computations of a two-phase unit cell; and (d) the proposed micromechanical model is finally applied to simulate experiment data in short-term triaxial compression tests and long-term triaxial creep tests. And the numerical results show that it is able to reflect the variation of the mechanical behavior with respect to the varied mineralogical compositions. 相似文献
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Numerical prediction of gas migration properties in Callovo‐Oxfordian (COx) argillite using morpho‐mathematical operations 
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下载免费PDF全文 The feasibility study of long‐term radioactive waste storage in low‐permeable rocks has been performed by considering various damage and failure scenarios. This study aims at the numerical investigation of gas (mainly produced by corrosion of metallic parts) migration properties through the low‐permeable formation of Callovo‐Oxfordian argillite. Traditional methods, based on macroscopic approaches or homogeneous transport properties, are inappropriate to analyze this issue at the mesoscopic/microscopic scale. In this study, realistic porous space morphologies are constructed through union of excursions of random fields considering different experimental pore size distributions. Afterwards, purely geometric analysis of pore space is conducted by morpho‐mathematical operations for the purpose of the extraction of preferential gas transport pathways and the prediction of the gas entry pressure, the gas breakthrough pressure, and the following imbibition process. 相似文献
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古代深海硅质岩-粘土岩-碳酸盐岩系列(SAC)是沉积在远洋或深海的硅质岩、粘土岩和碳酸盐岩及其过渡岩石类型的统称.在借鉴现有相关分类的基础上,提出了基于三端元矿物组成的SAC岩石系列的三角图分类新方案.以碳酸盐矿物-粘土矿物-石英作为三端元组分,按照"纯"(>90%)、"主"(50%～90%)、"质"(50%～25%)、"含"(<25%)的定量分类标准,并利用等边三角形中线,将SAC岩石系列划分为4大类21类.利用新的分类方案,将下扬子地区寒武统SAC岩石系列划分出硅质岩大类、碳酸盐岩大类和混合泥岩大类,描述了它们的岩石学特征.该SAC岩石系列体现了自下而上由硅质岩端元向碳酸盐岩端元混合沉积演化的趋势.对国内外典型SAC岩石系列重新分类的结果表明,新的分类方案能够清晰反映端元矿物之间混合沉积演化的趋势.SAC岩石系列的分类和命名是定量描述古代深海或远洋沉积作用的基础,也是探索其沉积环境演变的重要依据. 相似文献