Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

The Roche Limit     

I. P. Williams 《Celestial Mechanics and Dynamical Astronomy》2003,87(1-2):13-25

The role of tides in deforming and possibly disrupting a secondary body orbiting about a primary body has been known for a considerable time. This was first inspired by the observations of ocean tides on Earth and then seen as playing an important role in the formation and evolution of the Earth–Moon system. Finally, in the beginning of the 20th century it was generally thought to have a significant role in the formation of the solar system through the tidal disruption of the Sun. Here, an overview of the historical developments of the ideas concerned with tidal disruption of a secondary body that can lead to mass loss is given. Some discussion of possible extensions to consider more realistic situations where the secondary body may not be moving on a circular orbit and may not rotate so as to maintain the phase-on configuration to the primary body is also given.  相似文献   

板翅式换热器综合性能优化的设计方法     

高俊忠  陈维汉 《广东海洋大学学报》2003,23(6):45-49

应用给定换热器结构材料而使换热量最大的两侧换热表面的最佳匹配准则和使可用能损失率最小的最佳运行参数准则。利用两个准则间的关系 ,采用迭代的方式完成换热器的优化设计 ,使换热器的设计达到材料省、换热效果好及运行费用低的目的 ,且能在设计阶段实现。  相似文献   

柴达木盆地东北缘古元古代变质镁铁—超镁铁质岩的地质特征及成因探讨     

王毅志  梁超云 《青海国土经略》2001,(Z1)

1:5万区域地质调查工作中,在柴达木陆块北缘首次发现古元古代变质镁铁—超镁铁质岩,获得成岩年龄为1952±15Ma,其岩石化学、地球化学特征反映出岩浆来源于亏损地幔,反映出该地区克拉通在古元古代(19亿年)发生了一次强烈的裂解(洋)事件,对于研究柴达木盆地北缘元古代结晶基底地质构造演化及进一步探讨柴达木盆地的起源及构造演化过程提供了重要地质线索。  相似文献   

关于网络用户经济效益评测模型的研究     

岳正华  李黎 《成都信息工程学院学报》2001,16(2):141-144

着重讨论了网络用户经济效益的内涵以及用户的投入量和产出量，并提出了评价网络用户经济效益的指标体系，包括成本降低率，成本利润增长率、产品开发时间约率、市场占有增长率等系列指标。  相似文献   

Wolf-Rayet stars     

K. A. van der Hucht 《Astronomy and Astrophysics Review》1992,4(2):123-159

Summary Recent literature on Population I Wolf-Rayet star research extending from the Milky Way to blue compact dwarf galaxies is reviewed, broken down into inventory, basic parameters and galactic distribution, atmospheres, binaries, intrinsic variability, mass loss, enrichment and evolution. Also the incidence of Wolf-Rayet stars with variable non-thermal radio emission, excess X-ray fluxes, and episodic/periodic IR excesses is reviewed. These phenomena appear to be associated with wind-wind interaction in wide long-period WR+OB binaries and with wind-compact object interaction in WR+c binaries, with orbit sizes of the order of magnitude of the WR radio photosphere sizes or larger.  相似文献   

THE CORPORATE INTERVIEW AS A RESEARCH METHOD IN ECONOMIC GEOGRAPHY*     

Erica Schoenberger 《The Professional geographer》1991,43(2):180-189

The open-ended corporate interview as a qualitative research method is proposed as a valuable component of an evidentiary strategy in economic geography. It is argued to be more sensitive than other survey methods to historical, institutional, and strategic complexity. The corporate interview method is particularly appropriate in periods of economic and social change that challenge traditional analytical categories and theoretical principles. Some problems inherent to the method, and strategies for minimizing their impact on the research project, are described.  相似文献   

Observations of hydrogen deficient binary Upsilon sagittarii     

N. Kameswara Rao  V. R. Venugopal 《Journal of Astrophysics and Astronomy》1985,6(2):101-112

The absolute magnitudeM _v of the hydrogen deficient binary υ Sgr has been estimated as -4.8 ± 1.0 from the distribution of the interstellar reddening, polarization and interstellar lines of the surrounding stars. From the ANS observations obtained at the time of the secondary eclipse, it appears that the hotter secondary is surrounded by a disc with colours of a B8-B9 star. The λ 1550 CIv absorption line arising in the stellar wind does not show any change in strength during the secondary minimum. The upper limit to the mass-loss rate from the high temperature wind is estimated as ≤ 5 × 10^-7 M⊙ yr^-1 from the 2 cm and 6 cm radio observations. Based on observations obtained with the Astronomical Netherlands Satellite and VLA. The National Radio Astronomy Observatory’s Very Large Array at Socorro, New Mexico is operated by Associated Universities Inc. under contract with the National Science Foundation.  相似文献   

GROWTH OF NEW ECONOMIC SECTORS IN SECOND-TIER EXTENDED CITIES IN THE CHANGJIANG RIVER DELTA——Case of Suzhou, Wuxi, Changzhou     

《中国地理科学(英文版)》2004,14(4):296-303

1INTRODUCTIONUrbanrelationshipaswellasurbansystemhas beenthemostimportantandlastingdirectioninthestudyofur-bangeographysinceCHRISTALLER(1933)putfor-wardthecentralplacetheory.Alongwiththepaceofglobalizationinthe1980s,somepioneer researchessen-sitivelyexpoundedaworldcitysystem,includingworldcity,internationalcity,nationalcity,regionalcityandlocalcity(FRIEDMAN,1986).Lotsofresearchesfo-cusedonthedevelopingmechanismofthebigcitiesandurbansystemnetwork(GU,2000;ZHOU,1997;CUI,1992;HUeta…  相似文献   

An approach to quantitative analysis of regional economic links     

Dezhong Wang  Renxing Zhuang 《中国地理科学(英文版)》1997,7(2):149-156

Aimed at promoting regional coalitions and expanding the approach to economic links, this paper puts forward some new concepts such as link intensity and receiving coefficient, expounds the indexes of quantitative analysis of economic links and establishes the quantitative-analysis model of economic links. With help of the model, this paper calculates the values of the link intensities between Su-Xi-Chang (Suzhou-Wuxi-Changzhou) region and Shanghai, and analyzes the regional difference of the economic links.  相似文献