简单分段法在地层划分中的应用     

庞兴南 《南方国土资源》1993,(2)

本文简介海南省1:5万坝王岭、猴狝岭幅区域地质调查的地球化学简单分段法在地层划分中的应用。根据对下古生界变质岩与白垩系红层两条地层实测剖面的地球化学资料整理,用简单分段法进行划分、其效果较好。它的地球化学组分基本能反映原始沉积物的特点和其沉积环境,且与岩石地层的划分相互印证。  相似文献   

地球化学景观吸引子的发现及其意义     

李长江  麻土华  徐有浪 《浙江国土资源》1995,(1)

勘查地球化学对异常评价的最大不确定性源于对地球化学景观特性的认识不够。我们应用构造相空间的方法分析了浙江儒岙幅（1:5万）水系沉积物测量的Ag含量数据，揭示了地球化学景观是具有低维吸引子（DZ≈2．9）的混饨系统。这一发现将对勘查地球化学中采样密度的选择、地球化学场模拟、异常评价等根本性问题产生重大影响。  相似文献   

    

Guocheng Pan  D. P. Harris 《Mathematical Geology》1991,23(6):861-886

A new multidimensional scaling (MS) technique, referred to as the Pijk model, is formulated on the basis of associations among triple objects (samples or variables), instead of pairs of objects as used in the usual MS methods, such as factor analysis. The computational scheme provided for this method is the reduction of an original problem to a standard eigenvalue-eigenvector problem. The major goal of the technique is simplification and reduction of data structures and the rescaling of original objects into a new and reduced space, so that patterns and relations of the original objects can be conventiently examined in two-dimensional factor plots. The Pïjk method is illustrated and tested by using a set of geochemical data related to the epithermal gold and silver vein deposits in the Walker Lake quadrangle of Nevada and California. The characteristics of element associations suggested in the Pijk analysis are consistent with field observations. A preliminary comparison between the new method and the ordinary factor analysis also is made on the basis of the same data set. Results are encouraging in that analysis by the Pijk model captures triple-object associations that might be missed by the ordinary factor analysis which considers only pair-variable correlations  相似文献   

氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲   总被引：2，自引：1，他引：1  

林光西 《岩矿测试》2008,27(2):151-152

采用硝酸-氢氟酸-高氯酸溶解样品,以Fe3+作减缓剂,不需分离富集,用氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲。对测定介质、KBH4浓度、铁盐的作用等条件进行试验。方法检出限为0.0031μg/g,精密度(RSD,n=11)<6.10%。方法用于国家一级地球化学标准物质中痕量碲的测定,结果与标准值一致。  相似文献   

攀西地区铂族元素地球化学异常分布及其筛选   总被引：1，自引：0，他引：1  

任光明  李佑国  陈旭  骆耀南  费光春  包凤琴  陈杰 《地质与勘探》2008,44(1):62-66

攀西地区不同时代地层的水系沉积物中铂族元素地球化学背景值具有明显的规律性分布.笔者通过对该地区铂族元素含量在各地层中的分布以及地球化学异常的圈定、归并和分类,结合有关铂族矿床地球化学特征的认识,通过对水系沉积物中Pt、Pd综合异常的筛选,在铂族元素综合衬值异常图的基础上共划分出Ⅰ类异常4个、Ⅱ类异常19个、Ⅲ类异常23个以及Ⅳ类异常14个.初步筛选出的19个Ⅱ类异常子区可为进一步开展铂族矿床找矿工作提供依据.  相似文献   

Mo稳定同位素研究进展     

张羽旭  温汉捷  樊海峰 《岩石矿物学杂志》2008,27(5):457-464

随着表面热离子质谱(TIMS)和多接收器电感耦合等离子体质谱(MC-ICP-MS)的广泛应用以及同位素分析方法的改进,近10年来非传统稳定同位素(Cu、Zn、Fe、Se、Mo、Cr、Hg等)的研究得到迅速发展.其中,由于Mo同位素的分馏明显受氧化还原条件的控制,使其在指示古环境及古气候的变化方面有独特的地球化学指示意义.同时,Mo同位素在指示成矿物质来源和海洋Mo循环等方面也取得较大成果.因此,Mo同位素地球化学研究已成为国际地学领域的一个前沿和热点.本文综合前人的研究成果,结合近期自己的工作,论述了Mo同位素地球化学研究领域的一些重要进展,详细介绍了Mo同位素的化学分离、提纯和质谱分析技术,并对其应用前景进行了展望.  相似文献   

全球地球化学填图——历史发展与今后工作之建议   总被引：3，自引：0，他引：3       下载免费PDF全文

谢学锦 《中国地质》2008,35(3):357-374

区域性与国家性的地球化学填图已取得进展,如何在可期待的未来以极低密度采样获得周期表内大多数元素在全球的分布,有赖于对填图理念的更新及采样介质、采样部署与采样方法研究的进展。英国Webb等发现在数平方千米至数十平方千米汇水盆地之河口采集水系沉积物样品,其分析结果可大致逼近其上游汇水盆地内土壤中元素之平均值。挪威及中国的研究工作表明在更大河流(其汇水盆地达数百、数千以至数万平方千米)的河口采样,这一规律依旧适用。看来,这种分形规律还可进一步延展至世界上一些汇水盆地达数十万至百万以上平方千米的主要入海河口,但这方面尚需作更多的研究。在这种新的填图理念指导下,提出了为实现全球地球化学填图的短期研究与试点计划和长期全面实现之规划。  相似文献   

南海沉积岩芯的地球化学研究     

何良彪  辛春英 《海洋科学进展》1992,(4)

本文对南海中部陆坡区和海盆区的5个岩芯中的 Si,Al,Fe,Mn,Ca,Mg 和 CaCO_3成分做了分析,并对其分布特征与有关影响因素进行了讨论。受沉积区环境差异的影响,元素的分布具有区域性特征;受海区特定地理位置的影响,元素的分布呈现出过渡性特征(浅海到大洋的过渡);受沉积过程中环境变化的影响,元素的分布展示了周期性变化或旋回性。根据岩芯中元素的分布特征,并参考有关古地磁,氧碳同位素和钙质超微化石的测试分析结果,将本区岩芯划分为14层地球化学层,并将本区划分为两个沉积地球化学区,揭示了早更新世以来本区沉积环境的变化和存在的两种沉积模式。  相似文献   

Fluxes and sources of suspended organic matter in an estuarine turbidity maximum region during low discharge conditions   总被引：6，自引：1，他引：6  

Miguel A. Goni  Mary W. Cathey  Yong H. Kim  George Voulgaris 《Estuarine, Coastal and Shelf Science》2005,63(4):683-700

Water column concentrations of total suspended solids (TSS), particulate organic carbon (POC) and particulate nitrogen (PN) were measured at three different depths in four different locations bracketing the estuarine turbidity maximum (ETM) along the main channel of a temperate riverine estuary (Winyah Bay, South Carolina, USA). Measurements were carried out over full tidal cycle (over 24 h). Salinity, temperature, current magnitude and direction were also monitored at the same time throughout the water column. Tidally averaged net fluxes of salt, TSS, POC and PN were calculated by combining the current measurements with the concentration data. Under the extreme low river discharge conditions that characterized the study period, net landward fluxes of salt were measured in the lower part of the study area, suggesting that the landward transport through the main channel of the estuary was probably balanced by export out through the sides. In contrast, the net fluxes of salt in the upper reaches of the study area were near zero, indicating a closed salt balance in this part of the estuary. In contrast to salt, the net fluxes of TSS, POC and PN in the deeper parts of the water column were consistently landward at all four sites in Winyah Bay indicating the non-conservative behavior of particulate components and their active transport up the estuary in the region around the ETM.The carbon contents (%POC), carbon:nitrogen ratios (org[C:N]a) and stable carbon isotopic compositions (δ¹³C_POC) of the suspended particles varied significantly with depth, location and tidal stage. Tidally averaged compositions showed a significant increase up the estuary in the %POC and org[C:N]a values of suspended particles consistent with the preferential landward transport of carbon-rich particles with higher vascular plant debris content. The combination of tidal resuspension and flood-dominated flow appeared to be responsible for the hydrodynamic sorting of particles along the estuary that resulted in denser, organic-poor particles being transported landward less efficiently. The elemental and isotopic compositions indicated that vascular C₃ plants and estuarine algae were the major sources of the particulate organic matter of all the samples, without any significant contributions from salt marsh C₄ vegetation (Spartina alterniflora) and/or marine phytoplankton.  相似文献   

Seasonal Variations in Benthic Community Metabolism and Nitrogen Dynamics in a Shallow, Organic-Poor Danish Lagoon     

Erik Kristensen 《Estuarine, Coastal and Shelf Science》1993,36(6)

The dynamics of benthic primary production and community respiration in a shallow oligotrophic, marine lagoon (Fællestrand, Denmark) was followed for 1·5 years. The shape of the annual primary production cycle was explained primarily by seasonal changes in temperature (r² = 0·67-0·72) and daylength (r² = 0·63), whereas temperature almost explained all variation in benthic community respiration (r² = 0·83-0·87). On a daily basis the benthic system was autotrophic during spring and summer supplied by 'new' and 'regenerated' nitrogen and predominantly heterotrophic during fall and winter caused by light and nutrient limitation. The linear depth-relationship between porewater alkalinity and ammonium indicated that the C:N ratio of mineralized organic matter is low in spring and summer (3-6) and high in fall and winter (9-16). This is inversely related to net primary production and thus the input of labile, nitrogen-rich algal cells. Accordingly, mineralization occurred predominantly in the upper 2-5 cm of the sediment. The pool of reactive material (microalgal cells) was estimated to account for 12% of total organic carbon in the upper 3 cm, and had an average turnover time of less than 1 month in summer. Assimilation of organic carbon by benthic animals was equivalent to about 30% of the annual gross primary production. Grazing reduced chlorophyll a concentration in the sediment during summer and spring to values 30-40% lower than in winter, but maintained a 3-4 times higher specific microalgal productivity. The rapid turnover of organic carbon and nitrogen, and important role of benthic microalgae showed that the benthic community in this oligotrophic lagoon is of a very dynamic nature.  相似文献