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HanBin Xue René Gächter Laura Sigg 《Aquatic Sciences - Research Across Boundaries》1997,59(2):176-189
Data on the cycling of Cu and Zn in two eutrophic lakes are presented: Lake Greifen that becomes seasonally anoxic in its
hypolimnion and Lake Sempach that is aerated during winter and oxygenated during summer. They suggest that hypolimnetic oxygenation
1) enhances the release of copper from the sediment but 2) also accelerates the entrapment and deposition of Cu and Zn by
freshly formed Mn- and Fe-oxides. 相似文献
2.
A recent article (Said-Ahmad, W., Amrani, A., Aizenshtat, Z., 2013. The action of elemental sulfur plus water on 1-octene at low temperatures. Organic Geochemistry 59, 82–86) is commented on in this discussion. Radical mechanisms proposed by Said-Ahmad et al. (2013) for the formation of sulfurized and oxidized organic compounds in experiments involving elemental sulfur and 1-octene under aqueous conditions, aimed at investigating the interaction of organic matter and sulfur compounds under geological conditions, are not compatible with their experimental results and other studies. In addition, results from the experiments aimed at demonstrating the role of HO radicals in the formation of oxidized organic compounds were incorrectly interpreted by the authors. In this discussion, alternative mechanisms for the formation of the sulfurized and oxygenated products reported by Said-Ahmad et al. (2013) are proposed. 相似文献
3.
Betty K. Pun Christian Seigneur Daniel Grosjean Pradeep Saxena 《Journal of Atmospheric Chemistry》2000,35(2):199-223
Atmospheric particles contain a myriad of organiccompounds, including many multifunctional,water-soluble organic compounds. Many of thesecompounds are postulated to be secondary of origin. This work investigates the possible precursors ofseveral classes of multifunctional, water-solublesecondary organic compounds by analyzing the pathwaysleading to their formation, based on known gas-phasereactions. The analysis is termed `retrosynthetic'due to the backward direction of the analysis, fromproducts to precursors. Pathways for multi-functionalcompounds were generated combinatorially, consideringthe formation of one functional group at a time.Many multifunctional organic compounds with carboxylicacid, carbonyl, and hydroxy functional groups werefound to be first- or second-generation products ofcommon anthropogenic and biogenic volatile organiccompounds such as alkanes, alkenes, aromatics, andcyclic alkenes. The estimated yields of water-solubleorganic compounds from primary precursors ranged fromless than 1% to over 10%, based on stoichiometricconsiderations. The SOA formation index, whichcombines the concepts of yields and rates, was used tocompare the feasibility of the retrosyntheticpathways. Many of the candidate pathways involve theisomerization reaction of alkoxy radicals andoxygenated intermediate products such asmonocarboxylic acids and hydroxyaldehydes. 相似文献
4.
Biogenic Volatile Organic Compounds (VOC): An Overview on Emission, Physiology and Ecology 总被引：50，自引：0，他引：50
This overview compiles the actual knowledge of the biogenic emissions of some volatile organic compounds (VOCs), i.e., isoprene, terpenes, alkanes, alkenes, alcohols, esters, carbonyls, and acids. We discuss VOC biosynthesis, emission inventories, relations between emission and plant physiology as well as temperature and radiation, and ecophysiological functions. For isoprene and monoterpenes, an extended summary of standard emission factors, with data related to the plant genus and species, is included. The data compilation shows that we have quite a substantial knowledge of the emission of isoprene and monoterpenes, including emission rates, emission regulation, and biosynthesis. The situation is worse in the case of numerous other compounds (other VOCs or OVOCs) being emitted by the biosphere. This is reflected in the insufficient knowledge of emission rates and biological functions. Except for the terpenoids, only a limited number of studies of OVOCs are available; data are summarized for alkanes, alkenes, carbonyls, alcohols, acids, and esters. In addition to closing these gaps of knowledge, one of the major objectives for future VOC research is improving our knowledge of the fate of organic carbon in the atmosphere, ending up in oxidation products and/or as aerosol particles. 相似文献
5.
《水文科学杂志》2013,58(6)
Abstract In water reservoirs (lakes) in the summer period, three layers can be observed: the epilimnion, metalimnion and hypolimnion. In summer an increase in the thickness of the epilimnion layer is observed together with a movement of the metalimnion towards the bottom and a significant increase in the temperature of the two layers. An increase in hypolimnion temperature is observed in autumn during the cooling of the surface layers of the water. The increase in temperature of the epilimnion and metalimnion in summer and the downward movement of the metalimnion has not been clearly explained. The movement of the metalimnion is connected with thermal energy transfer, but previous theories do not take into account the phenomenon observed. In this paper, a new theory of thermal energy transfer in water reservoirs is elaborated and subsequently checked by laboratory experiments. A physical model of the water reservoir was designed and constructed. During the investigations it was noted that thermal energy can be transferred towards the bottom of the reservoir due to the existence of anti-convectional currents, which appear with the water temperature inversion in the upper part of the water column. The results obtained in the laboratory were confirmed by measurements in the Solina Reservoir in Poland. 相似文献
6.
SEA SURFACE SALINITY AND BOTTOM WATER OXYGENATED CONDITIONS IN WESTERN EQUATORIAL PACIFIC MARGINAL SEAS DURING THE LAST GLACLAL AGE 总被引：1，自引：0，他引：1
ImODUcrIONThewesternPadricconsistSofaseriesofrnarginalbasins(twoofwhicharetheSrsandSuluSea)thatareseparatalfromeachotherbysdriofvaryingdepths.The25OOmdepthsiliseparatingtheSrsfromthewesternNorthPadricallowiPadricinteediatewatertoentertheSCS.Inconhast,theSuluSeaiscomPldelysurmundedbyasill,mostofwhichisshallowerthanlOomindepth.Thedeepestchanne1intotheSLduSeais42Omdeep(MindoroStrait)andcutSacrossthesillthatseparateStheSuluSeafromtheSrs.TheseenvironmntSresultalinspeda1hydrographicse… 相似文献
7.
A chironomid‐based model for inferring late‐summer hypolimnetic oxygen in southeastern Ontario lakes
Hypolimnetic oxygen depletion has been accelerated in many lakes due to cultural eutrophication. However, the extent and magnitude of environmental change is difficult to ascertain due to the lack of historical records. Larval Chironomidae (Diptera) are useful proxy indicators of oxygen, as they show a wide range of tolerances to oxygen conditions and their chitinous head capsules preserve well in lake sediments. Using paleolimnological techniques, chironomid assemblages from the surface sediments of 42 southeastern Ontario lakes were related to environmental conditions. Hypolimnetic oxygen conditions, measured as the average endofsummer hypolimnetic dissolved oxygen (AvgDO(Summ)), explained the most variation in the chironomid assemblages, whereas dissolved inorganic carbon, the Anoxic Factor, max. depth and total phosphorus concentrations were also correlated with assemblage composition. Based on the relative abundances of 45 chironomid taxa, a robust, partial least squares (PLS) regression transfer function for AvgDO(Summ) was constructed (r2 = 0.74, r2
(jack) = 0.58, n = 40). This new transfer function should allow paleolimnologists to directly track past trends in hypolimnetic oxygen levels. 相似文献
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