Heat capacity and phase equilibria of wadeite-type K2Si4O9     

Wenjun Yong  E. Dachs  A. C. Withers  E. J. Essene 《Contributions to Mineralogy and Petrology》2008,155(2):137-146

The low-temperature heat capacity (C _p) of Si-wadeite (K₂Si₄O₉) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured heat capacity data is 253.8 ± 0.6 J mol⁻¹ K⁻¹, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the system K₂O–Al₂O₃–SiO₂ are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order approximations were undertaken to calculate the phase diagram in the system K₂Si₄O₉ at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure phase relations of the K₂Si₄O₉ polymorphs. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

长江中下游金属矿找矿前景与找矿方法   总被引：14，自引：3，他引：11       下载免费PDF全文

赵文津 《中国地质》2008,35(5):771-802

本文论述了长江中下游地区金属矿床的地质、地球物理和地球化学特点,提出今后深部找矿的主要对象是：找隐伏含矿岩体及有关的各类矿体,找岩体中的大型斑岩型矿床,找受岩体和五通砂岩联合控制的层状矿;讨论了地球物理和地球化学方法应用中要注意解决的几个主要问题,强调应发挥包括重力、磁法、激发极化法、电磁法、岩性探测仪及多种天然地震法和化探方法等综合方法的作用,并与地质矿床成矿规律研究密切结合;讨论了方法应用试验中要注意的几个问题。文章最后一部分是从本区大地构造的演化探讨了区域构造岩浆活动与成矿前景,认为这一地区是扬子板块与华北板块陆-陆碰撞挤压造山带及其前陆区,在岩石圈强烈挤压下形成地壳增厚和深部物质的挤出折返,使深部的高压和超高压变质岩层推到地壳浅部;深部生成的柯石英等高压超高压矿物及地幔熔融岩浆同时上侵;生成大量钙碱性岩浆并存储在中地壳部位,通过长期与中下地壳金属物质进行交换,形成矿液的集中优势,通过后期出现的张性断裂构造而进入地壳表层,再经过与围岩发生物理化学成矿作用后沉淀成矿。归纳出扬子板块与华北板块陆-陆碰撞造山带一种新的构造模式。  相似文献   

一种计算台风风场的方法     

陈孔沫 《热带海洋学报》1994,(2)

揭示Ｒａｎｋｉｎｅ涡风场模式和Ｊｅｌｅｓｎｉａｎｓｋｉ风场模式之间的联系，并设计了一种台风风场分布模式，它的风速分布曲线落在Ｊｅｌｅｓｎｉａｎｓｋｉ和Ｒａｎｋｉｎｅ涡两个风场模式的风速分布曲线之间，具有一个既优于Ｊｅｌｅｓｎｉａｎｓｋｉ又优于Ｒａｎｋｉｎｅ涡的风速衰减速率，因此它同时克服了Ｒａｎｋｉｎｅ涡模式计算风速偏小和Ｊｅｌｅｓｎｉａｎｓｋｉ模式计算风速偏大的缺点，以一种比较合理的变化趋势向远方衰减，成为一个比较切合实际的台风风场分布模式。同时，文中提出的移行台风风场计算方法对宫崎正卫、上野武夫和Ｊｅｌｅｓｎｉａｎｓｋｉ模式都有一定的改进。  相似文献   

Numerical and simplified methods for the calculation of the total horizontal wave force on a perforated caisson with a top cover     

Xuefeng Chen  Yucheng Li  Bin Teng 《Coastal Engineering》2007

The VOF method and the k–ε model, combined with the equation of state of air at constant temperature, have been used to calculate the total horizontal wave force caused by monochromatic waves acting on a perforated caisson with a top cover. From comparison of various parameters, such as the total horizontal force, the pressure difference on the front wall, the pressure on the back wall and the pressure on the top cover, between the numerical results and test data, it can be seen that the numerical results agree well with the test data. It is concluded that the method described in this paper can be utilized to calculate wave forces acting on perforated caissons with a top cover in the case of nonovertopping, nonbreaking waves. A simplified method to calculate the total horizontal force has been developed, based on test data, using a least-squares method. A comparison between the numerical results and the values calculated from the simplified equations shows good agreement. Therefore the simplified equations can be used in engineering applications to evaluate the total horizontal force on a perforated caisson with a top cover.  相似文献   

黑潮区台风域海-气热输送量的计算          下载免费PDF全文

林晓能 《海洋与湖沼》1993,24(3):319-324

根据1972和1974年经过黑潮区的两个台风个例,计算和分析了台风各部位在不同的海气条件下热量输送的垂直分布特点。表明,在台风前部信风带中,热量垂直输送限于700hPa以下,在1000hPa处有约167.47—209.34J/(cm~2·h)的最大值,700hPa以上热量向下输送;在台风中心区,热量输送量最大,在1000hPa处接近420J/(cm~2·h),在850hPa附近可能有热输送量的最大值,其上随高度减小;在台风后部偏南气流中,向上热输送量较小;各层最大值不超过84J/(cm~2·h)。  相似文献   

斜坡提砌石护面厚度的计算     

张怀慧  李玉成 《海洋工程》2002,20(2):14-18

介绍了斜坡式防波堤砌石护面中的插砌条石和干砌块石在波浪作用下的力学图式及作用机理 ,重点给出考虑摩擦力作用时的砌石块体稳定厚度的计算公式 ,并结合工程实例验证了公式的适用性  相似文献   

港口靠船桩工作性状计算的双参数法   总被引：8，自引：0，他引：8  

谢耀峰 《海洋工程》2002,20(2):38-42,48

港口靠船桩是承受重复性荷载或多循环荷载的一种横向承载桩。双参数法能较好地描述靠船桩 (单桩、群桩 )的桩土工作性状。用双参数法进行计算时 ,所给的地面条件必须由重复荷载或多循环荷载作用下实测出来。根据现场试桩资料 ,标定桩土参数 ,即k =mx1/n的指数l/n、桩土相对柔度系数α、桩土综合刚度EI等值 ,可以用来设计试桩附近局部地区同类条件下的其它长桩。对于没有进行试桩的某些工程 ,可以联合运用双参数法和p -y曲线法进行桩的分析  相似文献   

Resources calculation of cobalt-rich crusts with the grid subdivision and integral method     

WU Ziyin  CHU Fengyou  MA Weilin  LI Shoujun  SHANG Jihong 《海洋学报(英文版)》2007,26(5):43-53

On the basis of three geological models and several orebody boundaries,a method of grid subdivision and integral has been proposed to calculate and evaluate the resources of cobalt-rich crusts on the seamounts in the central Pacific Ocean.The formulas of this method are deduced and the interface of program module is designed.The method is carried out in the software "Auto mapping system of submarine topography and geomorphology MBChart".This method and program will possibly become a potential tool to calculate the resources of seamounts and determine the target diggings for China's next Five-year Plan.  相似文献   

东海XH凹陷烃资源预测──勘探层分析及石油资源专家系统分析     

肖国林  周才凡  李桂群 《中国海洋大学学报(自然科学版)》1995,(3)

应用勘探层分析及石油资源专家系统对ＸＨ凹陷下第三系勘探目的层的三个勘探层烃资源量作出了综合预测，结果表明，凹陷内各勘探层，尤其是渐新统勘探层，烃资源量相当可观。提出在渐新统内的地层圈闭中可进一步作详细的勘探工作。  相似文献   

Post-Miocene stratigraphy and depositional environments of valley-fill sequences at the mouth of Tampa Bay, Florida     

Thomas W. Ferguson  Richard A. Davis  Jr.   《Marine Geology》2003,200(1-4):157-170

Post-Miocene sea-level low stands allowed rivers and karst processes to incise the exposed carbonate platform along the Gulf Coast of Florida. Few Miocene to mid-Pleistocene deposits survived erosion along the present coast except within incised valleys. Since their formation, these valleys have been filled and incised multiple times in response to sea-level changes. The thick sedimentary sequences underlying the mouth of Tampa Bay have been recorded as a range of depositional environments and multiple sea-level incursions and excursions during pre-Holocene time and subsequent to the accumulation of the Miocene carbonate sequences. Sediment analysis of cores collected from a north–south transect across the mouth of Tampa Bay has enabled the identification of lithofacies, ranging from well-sorted, quartz sand to dense, fossiliferous, phosphatic grainstone. These facies were deposited in freshwater, estuarine, and shallow, open marine environments. As a result of channel development and migration within the paleovalley, and cut-and-fill associated with individual transgressions and regressions, correlation of the lithofacies does not extend across the entire transect. Fining-upward sequences truncated by tidal ravinement surfaces that extend throughout the paleovalley can, however, be identified. Age determinations based on 14-C analysis, amino-acid racemization, and strontium isotope analysis dating of numerous samples yield ages of Miocene, Pliocene, early Pleistocene, and late Pleistocene, as well as Holocene for sequences that accumulated and were preserved in this valley-fill complex. Numerous inconsistencies in the stratigraphic organization of the age determinations indicate that there are bad dates, considerable reworking of shells that were dated, or both. For this reason as well as the lack of detailed correlation among the three relatively complete cores, it is not possible to place these strata in a sequence stratigraphic framework.  相似文献