A 3D finite element simulation model for TBM tunnelling in soft ground     

Thomas Kasper  Günther Meschke 《国际地质力学数值与分析法杂志》2004,28(14):1441-1460

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柿竹园矿床大理岩型锡矿石工艺矿物学研究   总被引：1，自引：0，他引：1  

谭延松 《湖南地质》1991,10(3):223-228

大理岩型锡矿石产于燕山早、中期千里山花岗岩与中、上泥盆统灰岩的外接触带。矿石呈细脉、网脉浸染状,锡矿物有:锡石、黄锡矿,富钛尼日利亚石、尼日利亚石和木锡矿,脉石矿物绿帘石、石榴石、电气石、萤石、方解石及磁黄铁矿等亦含锡,锡主要呈锡的浊立矿物存在,占总锡量的89.78％,其中锡石锡占总锡量的80.01％,其次有呈类质同象形式存在的锡,在绿帘石、石榴石、电气石等矿物中以Sn~(4+)取代Fe~(3+),这类锡占总量的8.33％。工艺矿物学研究表明,该类锡矿石以“贫”、“细”、“杂”为特征。锡不仅十分分散,而且品位偏低,矿石矿物组合及镶嵌关系复杂、相互包裹,紧密连生;锡矿物粒度微细,粒径一般为0.2～0.01mm,部分为<0.0l～0.002mm,是一种难选的锡矿石类型。通过锡的回收试验,采用选冶联合工艺流程,预测锡的最佳回收率可达50％以上。  相似文献   

Techniques to measure grain-size distributions of loamy sediments: a comparative study of ten instruments for wet analysis   总被引：2，自引：0，他引：2  

DIRK GOOSSENS 《Sedimentology》2008,55(1):65-96

Ten instruments for measuring the grain‐size distribution of loamy sediments in water were tested in a comparative study. Instruments tested were: the Malvern Mastersizer S, the Coulter LS 200, the Fritsch Analysette 22 (version C), the Horiba Partica LA‐950, the Sedigraph 5100, the Atterberg cylinder, the Coulter Multisizer 3, the CIS‐100, the EyeTech and the image analysis software Histolab. The first four instruments use laser diffraction. The Sedigraph and Atterberg cylinder are based on sedimentation. The Coulter Multisizer 3 uses impedance measurements and the last three instruments use optical techniques. Grain‐size analyses were carried out on four sediments with median grain diameters of approximately 35, 30, 12 and 9 μm, respectively, and with no particles >90 μm. The laser diffraction instruments produced the best results for the various criteria considered in this study, followed by the Coulter Multisizer 3 (electrical sensing zone technique), the sedimentation techniques and the optical methods. However, the study also showed that there is no such thing as an ‘ideal’ method because techniques may score differently according to the criterion tested. An appropriate evaluation thus requires that various criteria be considered. Issues to be taken into account are: type of sediment, quantity of sediment available, speed of measurement, complexity of the measurement protocol, processing of the data, reproducibility of the results and the specific aims of the study undertaken.  相似文献   

Diagenesis, palaeoclimate and tectono-sedimentary influences on clay mineralogy and stable isotopes from Upper Cretaceous marine successions of the Basque-Cantabrian Basin (N Spain)     

lvaro Jimnez Berrocoso  Maria Cruz Zuluaga  Javier Elorza 《Cretaceous Research》2008,29(3):386-404

Clay mineralogy and whole-rock stable isotopes (δ¹⁸O and δ¹³C) of Upper Cretaceous marly sediments on the Basque-Cantabrian Basin have been integrated to determine the main effects of diagenesis, palaeoclimate and tectono-sedimentary factors in sections belonging to deep- (Barrika) and platform-marine (Isla de Castro, Villamartín and Olazagutía) settings.The mean values for the clay assemblages and δ¹⁸O exhibit notable differences among the sections, partially explainable by the influence of diagenesis. The Barrika sediments, with more diagenetically advanced illite-smectite (I-S) mixed-layer (R1, 70% illite), authigenic chlorite, and low δ¹⁸O (−4.05‰ PDB), experienced higher diagenetic grade than Isla de Castro and Olazagutía, which have R0 I-S (20% illite) and heavier δ¹⁸O. Villamartín was also affected by higher diagenesis than Isla de Castro and Olazagutía, given the occurrence of R1 I-S (60% illite) and low δ¹⁸O (−4.11‰ PDB). However, the absence of other clays in Villamartín (e.g. authigenic chlorite) is indicative of less diagenetic grade than Barrika. These results show the useful integration of clay mineralogy and stable isotopes to detect different diagenetic grades in distinct marine successions of the same basin.Despite being influenced by diagenesis, the clay mineralogy partially preserves its inherited signature. This allows detection of major contents of I-S and mica, and minor kaolinite, interpreted as indicative of warm palaeoclimatic conditions. High kaolinite content in Villamartín and absence of kaolinite in Isla de Castro, though, are considered to be a product of neither diagenesis nor palaeoclimatic influences. Instead, tectono-sedimentary causes, related to unsuitable conditions for clay formation and transport from the local source areas, contributed to original clay differences. The inferred effects of diagenesis, palaeoclimate and tectono-sedimentary factors make this work important to show the potentially great variety of controls on the clay mineralogy of marine sections, which are often uncritically treated in studies concerning the Late Cretaceous.  相似文献   

内蒙古天和永玄武岩成因：岩相学与矿物学分析     

杨宗锋  程黎鹿  罗照华  梁涛  潘颖  李德东  黄凡 《岩石学报》2008,24(11):2548-2562

天和永地区南北向出露的小面积单层碱性玄武岩,岩石中出现至少三种矿物共生组合关系。所有岩石均以橄榄石作为主要斑晶矿物,大颗粒环带橄榄石斑晶中心镁值为89．5,边缘镁值为70．3,小颗粒环带橄榄石镁值46．2～78．9。粒径最小的橄榄石聚集体和散布的基质橄榄石均无明显环带,前者镁值67．4～68．1,后者镁值65．5—72．1;单斜辉石由相对高钛高铝贫硅的散布柱状辉石和相对低钛低铝富硅的聚集粒状辉石组成,前者形成于低压快速淬火环境,镁值65．1—77．1,后者形成于富含挥发份的低压低过冷度环境,镁值77．7～78．0。所有单斜辉石均以次透辉石为主,个别为深绿辉石;斜长石以包含结构产出为主,为相对偏酸性的中长石An=33．7～37．4,CaO含量低与早期大量单斜辉石结晶有关。由于残余岩浆内K,0和Na20含量富集且极不均一,晚期结晶的长石同时出现了高钠长石、K-高钠长石（歪长石）和K-透长石;钛铁氧化物多数为晚期结晶的细粒基质矿物,少量以0．3ram左右的斑晶和橄榄石斑晶中的包裹体形式存在,可归属为钛铁尖晶石（Usp）-磁铁矿（Mt）固溶体系列,晚期逐渐向贫铝、铬和富钛方向演化。由于以上各种造岩矿物的晶出,导致残余岩浆形成的火山玻璃向贫镁、铁、钙和富铝、钾方向演化,火山玻璃的全碱含量变异趋势与全岩类似,均和SiO2含量无明显相关性,火山玻璃具有响岩和粗面安山岩成分特征,K2O／Na2O值变化大0．68～1．61,均为钾玄岩系列,Na2O含量依然呈现宽区间特征,是天和永玄武岩由钾质过渡到钠质的主要原因。天和永玄武质岩浆从地幔运移到地表仅需5小时-5天,大颗粒斑晶橄榄石和小颗粒基质橄榄石生长仅需几小时到几天,前者形成无须深部岩浆房停留,后者近似晚期岩浆快速淬火时间。高镁橄榄石斑晶与残余岩浆的扩散平衡时间约42天～252天。深部结晶的橄榄石在运移途中和地表流动过程中缺乏足够的时间和适宜的动力学条件而无法离开岩浆体系。全岩与火山玻璃间缺少中间过渡成分,呈两个相对集中的端元组分存在亦由晶出矿物无法离开岩浆体系所致。天和永玄武岩的成岩时间尺度远小于同化混染和岩浆分异的时间尺度,是岩浆作用过程未能明显影响其不均一原生岩浆性质的主要原因。因此,岩浆作用的某些物理过程分析是认识岩浆起源与岩浆作用过程及其对火成岩多样性的贡献的重要方面,同时对于理解和约束岩浆作用的某些化学过程也是十分有益的。  相似文献   

新疆巴里坤膨润土的工艺应用矿物学特性研究   总被引：1，自引：0，他引：1  

汪立今  张娜  宋来忠 《矿物学报》2008,28(1):84-88

从工艺矿物学角度系统研究了新疆巴里坤膨润土矿的矿石特征、化学成分、物理性质、矿物组成与结构、工艺应用属性等,认为巴里坤膨润土矿蒙脱石相对含量高,原土适用于石油钻井、铸造和冶金工业,将膨润土深加工后,可制得符合市场需求的有机膨润土、无机凝胶和高纯度蒙脱石等深加工产品.  相似文献   

乌兰图嘎超大型锗矿床含锗煤的矿物学   总被引：2，自引：0，他引：2  

张琦  戚华文  胡瑞忠  王小飞 《矿物学报》2008,28(4)

内蒙古乌兰图嘎锗矿是我国近年来发现的产在煤层中的超大型锗矿床,锗金属储量达1600 t。以乌兰图嘎超大型锗矿床的含锗煤为研究对象,利用X射线衍射(XRD)、带能谱的扫描电镜(SEM-EDX)和电子探针(EPMA)详细研究了乌兰图嘎含锗煤及其同时代的红旗煤矿无矿煤的矿物学特征。分析结果表明,乌兰图嘎含锗煤中的主要矿物包括石英、蒙脱石;次要矿物包括长石、高岭石、伊利石;另含少量三水铝石、角闪石、叶蜡石、石膏、绿泥石、锐钛矿、黄铁矿、方解石、白云石和草酸钙石;微量的锆石、闪锌矿、白钨矿、重晶石、黄铜矿、卤化物、磷酸盐以及含Pb、Bi、Cr、As和Sb矿物。未发现含锗矿物。推测含锗煤中的锗可能主要呈有机结合,而Ba、Zn、Ti、W、Pb、Bi、Cr、Fe、As、Zr、Sb、Cu和REE可能主要与矿物相结合。此外,首次在乌兰图嘎含锗煤及红旗煤矿无矿煤中发现含银颗粒或自然银,推测胜利煤田的褐煤可能有相当规模的Ag矿化。  相似文献   

南海尖峰海山多金属结壳地球化学   总被引：4，自引：5，他引：4  

梁宏锋  姚德  刘新波  梁德华 《海洋地质与第四纪地质》1991,(4)

南海尖峰海山多金属结壳富含30多种元素,其锰铁矿物主要由钡镁锰矿,δ-MnO_2和FeOOH·xH_2O组成。与其它海区的结壳相比,尖峰海山结壳富含Cu、Ni、Ba、Zn、Pb等元素,而Co、Ti、稀土元素(REE)、Sr等元素相对较贫。研究表明,HREE亏损,具明显的Ce正异常,较明显的Tb正异常和Yb负异常。这是氧化弱碱性海洋环境所致。结壳是水成作用的产物,它的形成受南海独特的古海洋环境所控制,海底火山热液作用,可能也是影响因素之一。  相似文献   

Degradation in Cemented Marine Clay Subjected to Cyclic Compressive Loading   总被引：1，自引：0，他引：1  

G. Gerald Moses  S. Narasimha Rao 《Marine Georesources & Geotechnology》2003,21(1):37-62

The influence of cyclic loading on the strength and deformation behavior of cemented marine clay has been studied. This marine clay is of recent Pleistocene origin and deposited in a shallow water marine environment. Open pits were dug in sheeted enclosures and from these pits, undisturbed samples were taken for strength testing. A series of standard triaxial shear tests and stress controlled one-way cyclic load tests were conducted at consolidation stress ranges below and above the preconsolidation pressure. For the stress levels below the preconsolidation pressure, the cyclic loading has brought about the collapse of the cementation bond through an increase in strains, and at higher pressure ranges, the soil behaves like typical soft clay. This experiment studied the rate of development of strain and pore water pressure and shows that rate is a function of number of cycles, applied stress, and stress history. In addition, soil degradation during cyclic loading is studied in terms of Degradation Index. Attempt has been made to predict stain, pore water pressure, and degradation index through an empirical model.  相似文献   

Petroleum geochemistry of the Kimmeridge Clay of onshore Southern and Eastern England     

Paul F. V. Williams 《Marine and Petroleum Geology》1986,3(4)

The Kimmeridge Clay is considered a major oil source rock for the North Sea hydrocarbon province. The formation is also developed onshore in an organic-rich mudstone facies. This paper examines the possibility of onshore oil generation from the Kimmeridge Clay. Geochemically, onshore basin margin sediments contain rich, potential source horizons with mainly Type l/Type ll oil-prone kerogen, but are immature. Some deeper Cleveland Basin sediments have reached marginal maturity. Burial history reconstruction suggests significant formation palaeoburial depths in central areas of the Cleveland and Wessex Basins. Computed vitrinite isoreflectance contours show the Wealden and Isle of Wight Kimmeridge Clay to be thermally mature. Basin modelling suggests an early Palaeogene onset of oil generation in parts of the Cleveland Basin, while maximum oil generation could have been reached by the formation base in the Isle of Wight area during the late Cretaceous. Although basin subsidence ceased in the Neogene, in the Weald and Isle of Wight, where the formation is still deeply buried, oil generation probably continued for some time during uplift. Thus significant quantities of oil could have been generated. Whether or not this oil is present today however, would depend on the correct timing of suitable migration and trap structures.  相似文献