Ultrahigh pressure macro diamonds from Copeton (New South Wales, Australia), based on Raman spectroscopy of inclusions   总被引：1，自引：0，他引：1  

L.M. Barron  B.J. Barron  T.P. Mernagh  W.D. Birch 《Ore Geology Reviews》2008,34(1-2):76

Mining of Cenozoic alluvial deposits at Copeton and Bingara (Eastern Australia) has produced two million macrodiamonds (0.25 ct median size). Raman spectroscopy is used to identify included minerals within uncut Copeton diamonds, with sealed chamber remnant pressures of 31.7 to 35.6 kbar for coesite, 13.6 and 22.7 kbar for clinopyroxene, and 7.6 kbar for grossular garnet. Assuming elastic behaviour, these values generate inclusion entrapment PT loci which intersect, restricting diamond formation conditions: from 250 °C, 43 kbar to 800 °C, 52 kbar. Larger than error (± 100 °C and ± 4 kbar), this range shows a systematic variation in inclusion composition with diamond zoning and N properties. Published research shows 1) Copeton and Bingara diamonds are unique, and 2) modern alluvium in the Bingara district carries mantle-formed garnet, captured by post-tectonic alkali basalt from an extensive diamondiferous ultrahigh pressure (UHP) terrane that stalled at depth because it is dominated by mafic eclogite. The combined Raman and geological results indicate two sets of subduction UHP diamond formation conditions/protolith are required, firstly cooler oceanic slab and secondly including higher temperature continental crust. The Copeton and Bingara stones are UHP macrodiamonds, and Carboniferous ⁴⁰Ar/³⁹Ar age dates on clinopyroxene inclusions should be interpreted as ages of crystallisation, representing the termination of subduction. The characteristic features of ruptured inclusions and etched percussion marks on Copeton and Bingara diamond indicate volcanic delivery to the earth's surface. Alluvial deposits elsewhere in Eastern Australia may carry similar diamond along with diamond of different origin.  相似文献   

不同年度收存的褶皱臂尾轮虫休眠卵的孵化及滞育胚胎“激活”效果的研究   总被引：3，自引：0，他引：3  

周利  相建海  郑严 《海洋与湖沼》2002,33(6):648-656

比较了 1 985— 1 998年间由同一褶皱臂尾轮虫 (Brachionusplicatilis)种群在实验室内历年产生并收存的休眠卵的孵化效果 ,并初步探讨了胚胎“激活”处理对孵化的影响。结果表明 ,休眠卵的收存年度或时间对其在一定孵育期内的总孵化率 (THR)和日孵化率 (DHR)有极显著影响 (x2 检验 ,p<0 .0 0 1 ) ,但THR和DHR与储存时间间均无显著的相关性 ,而是呈极大波动。同时发现“激活”作用具有促使孵化高峰提前到来、增强孵化同步性的双重功效 ,从而可明显缩短孵育时间 ,提高孵化速率。但“激活”前后多数卵样的总孵化率无显著变化 (p >0 .0 5 )。详细讨论了可能导致孵化率波动的多种因素 ,例如遗传变异、培养历史、储存及孵化的环境条件等。  相似文献   

中国南方含油气区构造—沉积类型及其勘探潜力   总被引：1，自引：0，他引：1  

赵喆  钟宁宁  梁狄刚  陈建平 《海相油气地质》2008,13(1):51-54

南方含油气的复杂构造区根据构造—沉积类型的不同,可将其分为四种类型。通过对不同类型典型含油气区的生烃量及非构造运动天然气散失量的化学动力学计算,认为这四种类型含油气区的油气聚集潜力从好到坏依次为:喜马拉雅运动抬升暴露型、燕山运动抬升暴露型、反复抬升—沉降型和海西—印支运动抬升暴露—后期浅埋型。主要构造运动发生越晚,对油气保存越有利。  相似文献   

寒武系古流体地球化学特征及其对页岩气保存的指示意义 ——以中扬子地区寒武系页岩气发现井宜地2井为例     

刘安  陈孝红  肖七林  黄惠兰  包汉勇  危凯  曾雄伟  王传尚 《地质学报》2022,96(7):2573-2584

保存条件是中扬子地区页岩气富集的关键因素之一，宜地2井是中扬子寒武系页岩气发现井，通过对该井全井段岩芯裂缝古流体的地球化学分析，探讨了寒武系古流体成因和对水井沱组页岩气保存条件的指示意义。结果认为：① 覃家庙组膏岩层之上方解石脉缺少Fe2+、Mn2+，且δ13C和δ18O值较围岩偏负，指示其形成于氧化的环境，石牌组方解石脉δ13C偏负，黄铁矿脉δ34S值与膏盐相似，表明其成因与TSR密切相关；水井沱组脉体δ13C和δ18O与围岩相似，形成于封闭的环境。② 方解石脉包裹体群SO42-、Ca2+、Mg2+含量整体上由覃家庙组向上向下分别递减，钠氯系数以水井沱组最低，整体上向上升高，表明覃家庙组是高盐度卤水的主要来源，水井沱组受外来流体影响弱；包裹体水溶液δD和δ18O也指示娄山关组、石牌组方解石脉成因分别与大气水、TSR相关。③ 古流体地球化学研究表明宜昌地区页岩气保存条件整体较好，页岩气散失的主要通道是垂直裂缝，页岩气保存条件好与膏盐盖层发育、后期构造破坏弱、脉体对裂缝的及时封闭以及白垩系盖层等因素密切相关。  相似文献   

Melting of β-quartz up to 2.0 GPa and thermodynamic optimization of the silica liquidus up to 6.0 GPa     

Pierre Hudon  In-Ho Jung  Don R. Baker 《Physics of the Earth and Planetary Interiors》2002,130(3-4):159-174

Melting relations of β-quartz were experimentally determined at 1.0 GPa (1900±20 °C), 1.5 GPa (2033±20 °C), and 2.0 GPa (2145±20 °C) using a new high-pressure assembly in a piston–cylinder apparatus and substantial differences were found with data previously reported. The new melting data of β-quartz were combined and optimized with all available thermodynamic, volumetric, and phase equilibria data for β-cristobalite, β-quartz and coesite to produce a P–T liquidus diagram for silica valid up to 6.0 GPa. Using the new optimized thermodynamic parameters, the invariant point β-cristobalite+β-quartz+liquid and β-quartz+coesite+liquid were determined to lie at 1687±17 °C and 0.457 GPa, and 2425±25 °C and 5.00 GPa, respectively.  相似文献   

Compression mechanisms of coesite     

R. J. Angel  C. S. J. Shaw  G. V. Gibbs 《Physics and Chemistry of Minerals》2003,30(3):167-176

 The structure of coesite has been determined at ten pressures up to a maximum of 8.68 GPa by single-crystal X-ray diffraction. The dominant mechanism of compression is the reduction of four of the five independent Si–O–Si angles within the structure. There is no evidence of the fifth linkage, Si1–O1–Si1, deviating from 180°. Some Si–O bond distances also decrease by up to 1.6% over the pressure range studied. The pattern of Si–O–Si angle reduction amounts to a rotation of the Si2 tetrahedron around the [001] direction. This rotation induces significant internal deformation of the Si1 tetrahedron. Comparison of the experimental data with rigid-unit distance least-squares simulations of coesite suggests that this pattern of compression, the anomalous positive values of both s₂₃ and K′′ in the equation of state of coesite, its high elastic anisotropy and the unusual straight Si1–O1–Si1 linkage within the structure are all consequences of the connectivity of the tetrahedral framework. Received: 11 July 2002 / Accepted: 14 January 2003 Acknowledgements The help of Christian Baerlocher of ETH Zurich in providing both the DLS-76 software and advice in its use is gratefully acknowledged, as are discussions with Paul Ribbe of Virginia Tech and the comments of two anonymous reviewers. The data analysis was supported by the National Science Foundation under grant EAR-0105864 to N.L. Ross and R.J. Angel.  相似文献   

Comparative studies of the kinetic parameters of various algaenans and kerogens via open-system pyrolyses     

Daniel Dessort  Jacques Connan  Sylvie Derenne  Claude Largeau 《Organic Geochemistry》1997,26(11-12)

Kinetic parameters were determined for the first time, via open-system pyrolyses, on algaenans (highly resistant biomacromolecules that are selectively preserved during kerogen formation) isolated from extant microalgae. Parallel studies were also carried out on 10 kerogens exhibiting, with one exception, a low level of maturity. These kerogens included samples chiefly derived from the selective preservation of the above algaenans and samples mainly, or almost exclusively, derived from the “natural vulcanization” pathway. Important differences in activation energy (E_a) distributions were observed between the four algaenans investigated and correlated with their chemical structures. The kerogens predominantly derived from algaenan-selective preservation (Pula alginite, NE 70 and BJ 248 Torbanites, Rundle Oil Shale) also exhibited pronounced differences in E_a distributions. These distributions provided: (i) information on the diversity of the source materials; and (ii) reflected the occurrence of important differences in chemical structures and thermal behaviour between three of the tested kerogens, even though they are all classified as low maturity type I. The Kimmeridge Clay samples and the Lorca Oil Shale showed broad E_a distributions shifted to low energies when compared with the above algaenans and kerogens. Such shifts reflect an important (or even almost exclusive for some of these kerogens) contribution of materials originating from sulphur incorporation into various lipids during early diagenesis. Finally, the kinetic data derived for the nine low maturity fossil samples were extrapolated to a very low, geological heating rate of 3°C Ma⁻¹ and the generation rate curves and cumulative yield curves thus obtained were compared.  相似文献   

Past imperfect, future tense: Archaeology and development     

Karen D. Vitelli  K. Anne Pyburn 《Natural Resources Research》1997,6(2):71-84

Archaeological sites are valuable nonrenewable resources and they are being destroyed rapidly by modern development projects of all kinds, worldwide. The contextual information in these sites could tell surprising and valuable stories of human behavior over an enormous sweep of time and might contribute to a better future. Archaeologists’ experience of site destruction and their recent efforts to work with local communities toward alternatives to site destruction may offer examples for others concerned with the treatment of nonrenewable resources  相似文献   

The evolution of the Huangling uplift and its control on the accumulation and preservation of shale gas     

《China Geology》2018,1(3):346-353

There are plenty of Sinian and Cambrian potential shale gas resources in South China, which is characterized by high thermal evolution degrees, poor drilling performances and only occurs in local areas. Taking the principle “high to find low” is the key issue to achieving a breakthrough in older shale. China Geological Survey drilled in the periphery of the Proterozoic basement, i.e. the Huangling anticline, in the western Hubei, and Hannan paleocontinent in the southern Shanxi. It received high-quality gas-bearing shale with relatively low Ro in the in Lower Cambrian Niutitang formation and Sinian Doushantuo formation. Based on geological conditions of shale gas reservoirs in the Huangling anticline, this paper puts forward the new model named “Control over reservoirs by periphery of basement” about shale gas accumulation, suggesting that the shale deposited in a deepwater continental shelf in the periphery of the basement is characterized by shallow burial, a short burial time, stable tectonics, relatively low thermal evolution degrees, and shale gas reservoirs in a good condition. The shale of the Sinian-Cambrian strata deposited in deepwater continental shelves in the periphery of Chuanzhong paleo-uplift in Sichuan, Hannan paleocontinent in the southern Shanxi, Huangling anticline in western Hubei and Jiangnang-Xuefeng paleo-uplift in Hunan and Guizhou province have good shale gas exploration potential.  相似文献   

What is preserved in the aeolian rock record? A Jurassic Entrada Sandstone case study at the Utah–Arizona border     

《Sedimentology》2018,65(4):1301-1321

Aeolian dune fields evolve from protodunes and small dunes into a pattern of progressively fewer, larger and more widely spaced dunes within limits defined by boundary conditions. However, the allogenic boundary conditions that promote aeolian dune‐field development, accumulation of strata and preservation of accumulated strata are not the same. Autogenic processes, such as dune interactions, scour‐depth variation along migrating dunes and substrate cannibalization by growing dunes, result in removal of the stratigraphic record. Moreover, dune‐field events may be collapsed into major erosional bounding surfaces. The question is what stages of evolving dune fields are represented in the rock record? This case study of ca 60 m of Jurassic Entrada Sandstone on the Utah/Arizona border (USA) defines stratigraphic intervals by gross architecture of bounding surfaces and sets of cross‐strata. The interpreted intervals in stratigraphic order consist of: (i) a lower sabkha bed that transitions upward into erosional remnants of small sets representing an initial wet aeolian system; (ii) large, compound cross‐strata representing a mature dune field; (iii) isolated scour‐fill representing negatively climbing dunes that produced ca 25 m of palaeo‐topographic relief; (iv) downlapping sets that fill the landscape‐scale relief; (v) four intervals of stacked climbing sets that each represent short periods of time; and (vi) an upper sabkha bed that again transitions into small sets representing a wet system. Accumulations appear to be associated with sediment pulses, a rising water table, and filling of scoured troughs and landscape‐scale depressions. Preservation of the accumulations is selective and associated with a rising water table, burial and subsidence. The preserved record appears remarkably incomplete. Speculation about missing strata gravitates towards cannibalization of the record of early dune‐field construction, and strata removed during the formation of bounding surfaces. This local Entrada record is thought to represent a point in the spectrum of preservation styles in the rock record.  相似文献