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1.
The behaviour of quartz during metamorphism is studied based on two case studies from the Barrovian terrains of Sulitjelma in arctic Scandinavia and Loch Tay in the Central Highlands Dalradian of Scotland. Both terrains preserve evidence for metamorphism in pelites involving nucleation and growth of garnet at different times in the deformation history. Data are presented on the size, shape and crystallographic orientation of quartz preserved as inclusions in garnet and as grains in the surrounding matrix. While quartz-grains remain small and dispersed between mica grains, deformation appears to be dominated by grain-boundary sliding accommodated by dissolution–precipitation. At amphibolite facies, textural coarsening occurs by dissolution of small quartz grains and growth of larger quartz grains, coupled with segregation of quartz from mica. As a result, quartz deforms by dislocation creep, developing crystallographic preferred orientations (CPO) consistent with both coaxial and non-coaxial strain. Quartz CPOs with <0001> axes lying parallel to foliation and stretching direction are commonly developed, and best explained by mechanical rotation of inequant (detrital?) quartz grains. There is no evidence for selective entrapment of quartz inclusions in garnet on the basis of quartz crystallographic orientation.  相似文献   
2.
A sequence of prograde isograds is recognized within the Dalradian Inzie Head gneisses where pelitic compositions have undergone variable degrees of partial melting via incongruent melting reactions consuming biotite. Three leucosome types are identified. At the lowest grades, granitic leucosomes containing porphyroblasts of cordierite (CRD‐melt) are abundant. At intermediate grades, CRD‐melt mingles with garnetiferous leucosomes (GT‐melt). At the highest grades, CRD‐melt coexists with orthopyroxene‐bearing leucosomes (OPX‐melt), while garnet is conspicuously absent. The prograde metamorphic field gradient is constrained to pressures of 2–3 kbar below the CRD‐melt isograd, and no greater than 4.5 kbar at the highest grade around Inzie Head. A petrogenetic grid, calculated using thermocalc , is presented for the K2O–FeO–MgO–Al2O3–SiO2–H2O (KFMASH) system for the phases orthopyroxene, garnet, cordierite, biotite, sillimanite, H2O and melt with quartz and K‐feldspar in excess. For the implied field gradient, the reaction sequence predicted by the grid is consistent with the successive prograde development of each leucosome type. Compatibility diagrams suggest that, as anatexis proceeded, bulk compositions may have been displaced towards higher MgO content by the removal of (relatively) ferroan granitic leucosome. An isobaric (P = 4 kbar) TaH2O diagram shows that premigmatization fluids must have been water‐rich (aH2O > 0.85) and suggests that, following the formation of small volumes of CRD‐melt, the system became fluid‐absent and melting reactions buffered aH2O to lower values as temperatures rose. GT‐ and OPX‐melt formed by fluid‐absent melting reactions, but a maximum of 7–11% CRD‐melt fraction can be generated under fluid‐absent conditions, much less than the large volumes observed in the field. There is strong evidence that the CRD‐melt leucosomes could not have been derived by buoyantly aided upwards migration from levels beneath the migmatites. Their formation therefore required a significant influx of H2O‐rich fluid, but in a quantity insufficient to have exhausted the buffering capacity of the solid assemblage plus melt. Fluid : rock ratios cannot have exceeded 1 : 30. The fluid was channelled through a regionally extensive shear zone network following melt‐induced failure. Such an influx of fluid at such depths has obvious consequences for localized crustal magma production and possibly for cordierite‐bearing granitoids in general.  相似文献   
3.
Grampian migmatites in the Buchan Block,NE Scotland   总被引:1,自引:0,他引:1       下载免费PDF全文
Rocks exposed along the Scottish coast between Fraserburgh and Inzie Head contain information critical to understanding the evolution of the Buchan Block, the type locality for low‐P, high‐T regional metamorphism, and its relationship with the rest of the Grampian terrane, one of the major tectonostratigraphic components of the Scottish Caledonides. The ~8 km long section traverses a regional network of shear zones and, at the highest grades around Inzie Head, passes into the core of the Buchan Anticline, a large‐scale open fold that is commonly regarded as a late structure, post‐dating metamorphism. The metasedimentary rocks increase in grade from upper amphibolite to granulite facies and preserve unequivocal evidence for partial melting. The diatexite migmatites around Inzie Head, along with other gneissose units within the Buchan Block, have been regarded as allochthonous Precambrian basement rocks that were thrust into their current position during the Grampian orogenesis. However, field observations show that the onset of in situ partial melting in metapelitic rocks, which was associated with the formation of garnet‐bearing aplites and associated pegmatites, occurred around Fraserburgh, where shear fabrics are absent. Thus, the rocks preserve a continuous metamorphic field gradient that straddles the shear zone network. This observation supports an alternative interpretation that anatexis was the result of mid‐Ordovician (Grampian) metamorphism, rather than an older tectonothermal event, and that the Inzie Head gneisses are autochthonous. Using an average mid‐Dalradian pelite as a plausible representative protolith, phase equilibria modelling satisfactorily reproduces the observed appearance and disappearance of key minerals providing that peritectic garnet produced with the first formed melts (represented by the garnet‐bearing aplites) depleted the source rocks in Mn. The modelled metamorphic field gradient records a temperature increase of at least 150 °C (from ~650 °C near Fraserburgh to in excess of 800 °C at Inzie Head) but is isobaric at pressures of 2.7–2.8 kbar, suggesting the Buchan Anticline developed synchronous with partial melting. The Buchan Anticline is likely an expression of crustal thinning and asthenospheric upwelling, which produced voluminous gabbroic intrusions that supplied the heat for Buchan metamorphism.  相似文献   
4.
The type locality for high-temperature,low-pressure regional metamorphism,the Buchan Block in NE Scotland,exhibits profound differences to the rest of the Grampian Terrane.These differences have led some to regard the Buchan Block as an exotic crustal fragment comprising Precambrian basement gneisses and cover rocks thrust into their current position during Grampian orogenesis.Although rocks of the Buchan Block are now generally correlated with Dalradian strata elsewhere,the origin of the gneisses and the cause of the high heat flow and associated magmatism is debated.We report SIMS U-Pb and LA-ICPMS Hf isotopic data in zircon from high-grade rocks from the northeast(Inzie Head Gneiss)and northwest(Portsoy)corners of the Buchan Block.Around Inzie Head,upper amphibolite to granulite facies metasedimentary gneisses coexist with diorite sheets that were emplaced contemporaneously with partial melting of their host rocks,at least locally.U-Pb geochronology indicates a crystallisation age for the diorite of 486±9 Ma.Highly-deformed diorites within the Portsoy Gabbro have a crystallisation age of 493±8 Ma.Ages of ca.490 Ma for magmatism and high-grade metamorphism,which are broadly contemporaneous with ophiolite obduction and the onset of orogenesis,are significantly older than the established peak of Grampian metamorphism(ca.470 Ma).We propose a new model for the Grampian Orogeny involving punctuated tectonothermal activity due to tectonic switching during accretionary orogenesis.Rollback of a NW-dipping subduction zone at ca.490 Ma produced a back-arc environment(the Buchan Block)with associated arc magmatism and high dT/dP metamorphism.Arrival of an outboard arc resulted in shortening(the initial phase of the Grampian Orogeny)at ca.488 Ma.Rollback of a NW-dipping subduction zone to the SE of the ca.488 Ma suture began at 473 Ma and led to lithospheric-scale extension,decompression melting and advective heating of the middle crust,producing the widespread ca.470 Ma Grampian(classic Barrovian and Buchan)regional metamorphism.Resumed hinge advance and the final phase of shortening cut off the heat supply at ca.465 Ma,marking the end of the Grampian Orogeny.  相似文献   
5.
The structure of the Dalradian rocks of the Banffshire coast has been re-examined. It is shown that D1 structures face upwards along the entire section and the major Boyndie Syncline (Sutton and Watson 1956) must also be of D1, age and not D3 as proposed by Johnson (1962). D2 structures are developed in the west, most strongly in the Portsoy Group and Cowhythe Gneiss where they may be related to the Portsoy Thrust (Elles 1931). East of the Cowhythe Gneiss D2 structures are not developed but D3 structures are of local importance. Porphyroblast growth is considered to be post-D1, pre-D3 related to the ‘active’ D2 deformation in the west (Barrovian) and to the ‘static’ D2 interval in the east (Buchan). The wider implications of these conclusions for Dalradian structure are briefly considered.  相似文献   
6.
Komatiite lavas occur in the Dunrossness Spilitic Group in southeast Shetland in the Cunningsburgh area. This metavolcanic group is the easternmost member of the East Mainland Succession of Shetland and probably the youngest. It overlies a thick succession of deep-water metasediments and metavolcanic rocks probably forming part of an extensional basin and has been correlated with a part of the upper Dalradian of Scotland. Komatiites are not common in rock sequences as young as this. Their eruption is thought to require tectonic and thermal conditions which have been unusual since Archean times. Such conditions could arise when the crust beneath an extensional basin splits to form a constructive margin.  相似文献   
7.
Vein-controlled retrograde infiltration of H2O-CO2 fluids into Dalradian epidote amphibolite facies rocks of the SW Scottish Highlands under greenschist facies conditions resulted in alteration of calcite-rich marble bands to dolomite and spatially associated 18O enrichment of about 10%. on a scale of metres. Fluid inclusion data indicate that the retrograde fluid was an H2O-salt mixture with a low CO2 content, and that the temperature of the fluid was about 400d? C. Detailed petrographic and textural (backscattered electron imaging) studies at one garnet-grade locality show that advection of fluid into marbles proceeded by a calcite-calcite grain edge flow mechanism, while alteration of non-carbonate wall-rock is associated with veinlets and microcracks. Stable isotopic analysis of carbonates from marble bands provides evidence for advection of isotopic fronts through carbonate wall-rocks perpendicular to dolomite veins, and fluid fluxes in the range 2.4–28.6 m3/m2 have been computed from measured advection distances. Coincidence of isotope and reaction fronts is considered to result from reaction-enhanced kinetics of isotope exchange at the reaction front. Front advection distances are related to the proportion of calcite to quartz in each marble band, with the largest advection distance occurring in nearly pure calcite matrix. This relationship indicates that fluid flow in carbonates is only possible along fluid-calcite-calcite grain edges. However, experimental constraints on dihedral angles in calcite-fluid systems require that pervasive infiltration occurred in response to calcite dissolution initiated at calcite-calcite grain junctions rather than to an open calcite pore geometry. The regional extent of the retrograde infiltration event has been documented from the high δ18O of dolomite-ankerite carbonates from veins and host-rocks over an area of least 50 × 50 km in the SW Scottish Highlands. Isotopically exotic 18O-rich retrograde fluids have moved rapidly upwards through the crust, inducing isotopic exchange and mineral reaction in wall-rocks only where lithology, pore geometry or mineral solubilities, pressure and temperature have been appropriate for pervasive infiltration to occur.  相似文献   
8.
Abstract A major system of steep Caledonian shear zones, of regional extent, has been identified in NE Scotland. The shear zones affect a wide range of lithologies, including Argyll and Southern Highland Group Dalradian, 'Younger Basic'intrusives and their hornfelses, and also the earlier of the more acid intrusions. The observed fabrics and parageneses are consistent with low-pressure amphibolite facies metamorphism. These shear zones represent a phase of movement which occurred in the 490-465 Ma interval when ambient temperatures were still high, and it is concluded that this is the principal control on the metamorphic grade achieved within the shear zones, although local anomalies may exist.  相似文献   
9.
The Connemara region of the Irish Caledonides is a classic example of regional-scale metamorphism of low pressure and high temperature. This terrane is considered as part of a fold belt comprising metasedimentary and metavolcanic rocks that are correlated with the Neoproterozoic–Lower Paleozoic Dalradian Supergroup of Scotland. In mid-Ordovician time, the extensive and high-temperature metamorphism was superimposed on the Dalradian rocks resulting in the Connemara zoning. The key feature of the zoning is elevated horizontal thermal gradient of ca. 14 °C/km. Geological data and geochronological evidence point to a causative link between metamorphism and associated magmatic intrusions, and a brief period of development for the metamorphic zoning. Magmatic intrusion into the middle part of continental crust is treated as a most plausible source of heat for metamorphism, and other conjectures as to the origin of the zoning (flow of hot fluid through the permeable rocks, fracture conduit flushed by flowing magma) are believed to be improbable. To examine in sufficient detail the problem of the nature of heat source, a series of appropriate calculations have been performed to reach the best agreement between the observed and simulated spatial distribution of maximum temperatures at different times. The mathematical modelling shows that the temperature–spatial structure of the Connemara zoning is best explained by the model version based on mid-crustal heating above the upper contact of magmatic intrusive body gently curved and tilted at an angle between 20° and 40°, with an initial temperature of the magma appropriate to a basaltic melt. The model estimate of total lifetime of the temperature anomaly in the crust is of the order of 5–6 Ma. In general, this is in rather good agreement with the currently available evidence of geochronological duration of metamorphism and magmatism in Connemara.  相似文献   
10.
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