Glass inclusions in volcanic rocks in the Okinawa Trough back-arc basin:constraints on magma genesis and evolution   总被引：1，自引：0，他引：1  

Yu Zenghui  Zhai Shikui  Li Xianzhong 《海洋学报(英文版)》2001,20(3):383-390

INTROOUcr1ONThe Okinawa Trough is a typical marginal back-arc basin, where its oPening began in rela-tively recent years* There is a great controversy about the origin of its initial magYna. haltand acid volcanic pumice make up the bimedal volcanism in the Okinawa Trough. MOSt of geol-ogists believed that the acid pumice was the preduct of extremely crystal fractionation of baseltInagTna, but the others argued that it should com from the melting of lower-crust. Som de-tailed petrolOgic…  相似文献   

Recognition features of felsic pyroclastics of Serra do Tombo formation,Minas Gerais,Brazil     

《Journal of South American Earth Sciences》2016

In this contribution we report a study of poorly exposed, rhyodacitic welded-ignimbrite deposit from Minas Gerais. A petrographic study of textures indicate high temperature of emplacement. Key features include eutaxitic texture, flattened and agglutinated lapilli and glass menisci. Most of the feldspar minerals and glass are extensively altered to clay minerals, which pseudomorph the original volcanic textures. Glass menisci and spherules suggest a possible process of liquid immiscibility. Immobile trace element distribution indicates a possible link with other post-Palaeozoic felsic volcanic rocks in Brazil, a magmatism interpreted as due to basaltic underplating and partial melting of a hydrous continental crust. A peculiar feature is a high Light REE/Heavy REE ratio. Depletion in heavy rare earth elements is possibly due to a residual HREE-bearing phase in the source. The geologic context of these rocks suggests a Lower Cretaceous age and a tectonic relationship with a continental rifting event.  相似文献   

193nmLA-ICPMS对国际地质标准参考物质中42种主量和微量元素的分析   总被引：31，自引：16，他引：31  

柳小明  高山  袁洪林  Bodo HATTENDORF  DetlefGNTHER  陈亮  胡圣红 《岩石学报》2002,18(3):408-418

本文采用配备有 193nm Ar F准分子 (excimer)激光器的 Geo L as2 0 0 M剥蚀系统和 Elan6 10 0 DRC ICP- MS对 4个美国地质调查所 (USGS)玻璃标准参考物质以及 3个美国国家标准技术研究院 (NIST)人工合成硅酸盐玻璃标准参考物质中几乎覆盖整个质量数范围 (从 7L i到 2 38U)的 38个微量和 4个主量 (Na、Mg、Ti和 Mn)元素进行了分析。分析结果表明 ,无论是对 USGS还是 NIST玻璃 ,元素分析的相对标准偏差 RSDs和分析值与参考值之间的相对偏差 (RDs)一般优于 10 % ,RSD和RD较大的元素主要出现在含量很低或不均匀样品中。稀土元素的 RSD显示 ,除 AGV- 2 G可能存在不均匀现象外 ,其它所测样品在 6 0 μm尺度上 ,元素分布是均匀的。本研究证明 ,由于 ICP- MS具有 10 8cps(每秒计数 )的动态线性范围 ,本实验室的L A- ICPMS系统可定量分析含量在百分之几的主量元素及微量元素。分析精密度和准确度可与常规溶液雾化进样 ICP- MS方法相媲美  相似文献   

The ‘Stained Glass Procedure’, a new method to compare classification performance of images acquired with different pixel sizes     

E.A. Addink  J.G.P.W. Clevers  S.M. de Jong  G.F. Epema  F.D. van der Meer  A.K. Skidmore  W.H. Bakker 《International Journal of Applied Earth Observation and Geoinformation》2006,8(4):237-245

Objective comparison of classification performance of earth observation images, acquired at different spatial resolutions (e.g. NOAA-AVHRR, IRS-MOS, IRS-WiFS, Landsat-TM, IRS-LISS), is complicated because both class definition and training site selection are hampered by the inherent scale differences. This paper presents a new, generic method to compare the information content of such a set of images, the “Stained Glass Procedure”. It overcomes the stated problems by computing the scale-dependent, internal spectral variation in an image and by using this as an indicator for land cover information. The Stained Glass Procedure creates segments in the images and calculates the internal spectral variation in a high-spatial-resolution image for each segment. For each image from the set the average variance, weighted to area, is calculated. The Stained Glass Procedure can be used to predict the performance of sensors that are not available, yet, or to roughly determine the optimal spatial resolution for the classification of a specific area.The procedure was applied to images with pixel sizes ranging from 23 to 1100 m. Classification detail of Envisat-MERIS (300 m pixel size), not included in the image set, could be predicted accurately using the Stained Glass Procedure.The Stained Glass Procedure applies one procedure to all images, without any subjective decision during the analysis, thus offering a method to compare images with different pixel sizes in terms of classification detail that is truly objective.  相似文献   

Calcio-carbonatite melts and metasomatism in the mantle beneath Mt. Vulture (Southern Italy)     

Gianluigi Rosatelli  Frances Wall  Francesco Stoppa 《Lithos》2007,99(3-4):229-248

At Mt. Vulture volcano (Basilicata, Italy) calcite globules (5–150 μm) are hosted by silicate glass pools or veins cross-cutting amphibole-bearing, or more common spinel-bearing mantle xenoliths and xenocrysts. The carbonate globules are rounded or elongated and are composed of a mosaic of 2–20 μm crystals, with varying optical orientation. These features are consistent with formation from a quenched calciocarbonatite melt. Where in contact with carbonate amphibole has reacted to form fassaitic pyroxene. Some of these globules contain liquid/gaseous CO₂ bubbles and sulphide inclusions, and are pierced by quench microphenocrysts of silicate phases. The carbonate composition varies from calcite to Mg-calcite (3.8–5.0 wt.% MgO) both within the carbonate globules and from globule to globule. Trace element contents of the carbonate, determined by LAICPMS, are similar to those of carbonatites worldwide including ΣREE up to 123 ppm. The Sr–Nd isotope ratios of the xenolith carbonate are similar to the extrusive carbonatite and silicate rocks of Mt. Vulture testifying to derivation from the same mantle source. Formation of immiscibile silicate–carbonatite liquids within mantle xenoliths occurred via disequilibrium immiscibility during their exhumation.  相似文献   

Chromium speciation in oxide-type compounds: application to minerals,gems, aqueous solutions and silicate glasses     

François Farges 《Physics and Chemistry of Minerals》2009,36(8):463-481

Cr K-edge XANES spectra were obtained for a variety of Cr-bearing model compounds containing Cr(II), Cr(III), Cr(IV), Cr(V) and Cr(VI), in which the Cr-site symmetry is D4h, Oh and Td. The centroid position of the pre-edge feature is a better indicator of the Cr valence than the edge position. In Cr-rich oxides, higher-energy transitions must be excluded in order to refine a robust valence for Cr. The pre-edge for chromates is not unique and varies as a function of the CrO₄ ^2? moiety distortion, which is often related to Cr-polymerization (monochromate vs. dichromate). Both the analogy with the Mn K-pre-edge information and ab initio FEFF calculations of the pre-edge feature for Cr(III) and Cr(VI) confirm the experimental trends. This methodology is applied to the Cr K-edge pre-edge feature collected in gems (emerald, spinel and ruby), the layered minerals fuchsite and kämmererite, two Cr-bearing aqueous solutions and a set of sodo-calcic silicate glasses used for bottling sparkling white wine. In emerald and fuchsite, the Cr-site is differently distorted than its ruby or spinel counterpart. In a Cr(III)-bearing aqueous solution and sodo-calcic glass, no evidence for Cr(III) with Td and C3v symmetry is detected. However, minor amounts of chromate moieties (most likely monomeric) are detected in a glass synthesized in air. Preliminary spectra for the wine bottle glass suggest that only trace amounts of chromates might possibly be present in these glasses.  相似文献   

Advancements and best practices for analysis and correlation of tephra and cryptotephra in ice     

《Quaternary Geochronology》2017

Geochemical analysis of fine grained (<20 μm) tephra found in ice cores is inherently difficult, due to the typically low number and small size of available particles. Ice core tephra samples require specialized sample preparation techniques to maximize the amount of information that can be gained from these logistically limited samples that may provide important chronology to an ice record, as well as linking glacial, marine and terrestrial sediments. We have developed a flexible workflow for preparation of tephra and cryptotephra samples to allow accurate and robust geochemical fingerprinting, which is fundamental to tephrochronology. The samples can be prepared so that secondary electron imagery can be obtained for morphological characterization of the samples to ensure that the sample is tephra-bearing and then the sample can be further prepared for quantitative electron microprobe analysis using wavelength dispersive techniques (EMP-WDS), scanning electron microscopy with energy dispersive spectrometry (SEM-EDS), laser ablation inductively coupled mass spectrometry (LA-ICP-MS) or secondary ion mass spectrometry (SIMS). Some samples may be too small for typical instrumentation conditions to be used (i.e. 20 μm beam on the EMP) to analyze for geochemistry and we present other techniques that can be employed to obtain accurate, although less precise, geochemistry. Methods include analyzing unpolished tephra shards less than 5 μm in diameter with a 1 μm beam on an SEM; using the “broad beam overlap” EMP method on irregular particles less than 20 μm in diameter, and analyzing microlitic shards as well as aphyric shards using EMP to increase the number of analyzed shards in low abundance tephra layers. The methods presented are flexible enough to be employed in other geological environments (terrestrial, marine and glacial) which will help maximize and integrate multiple environments into the overall tephra framework.  相似文献   

MAGNETOTELLURIC SOUNDING AND LATERAL INHOMOGENEITIES IN THE LITHOSPHERE     

《International Geology Review》2012,54(11):1340-1369

ABSTRACT

Libyan Desert Glass (LDG), rediscovered in modern times in 1932, is an ultrahigh-temperature glass composed of nearly pure SiO₂. LDG is found as surface float in Egypt’s Libyan (Western) Desert, its strewnfield defined by the intersection of major faults. Extra-terrestrial components are present in LDG but there is no associated impact crater. LDG is not an impactite, nor do pieces exhibit aerodynamic forms. Extremely viscous silica remained hot long enough to flow several centimetres. Additional constraints on the origin of LDG are imposed by exotic materials found nearby: a dark 30-gram granular micro-diamond mass, mullite-magnetite-silica glass rocks with micro-diamonds, lumps of fine-grained magnetite, titanium filaments, titanium nitride, titanium aluminide, aluminium oxycarbonitride, phosphides, silver, zirconium, zinc, carbonaceous grains, and metal grains coated with carbonaceous materials. The region is underlain by 500–3000 m of flat-lying sandstone composed of quartz grains and little else. To account for LDG and the other unusual materials and nearby outgassing vents, serpentinization is evoked. Products of this complex low-temperature crustal process include serpentine, magnetite, aqueous silica, and great quantities of hydrogen. The hydrogen, produced in Basement rocks beneath the sandstones, may have risen along faults, passing around grains of quartz (with which it does not react) until slowed by tight conditions, perhaps self-sealed by silica produced during serpentinization. Columns of quartz hundreds or thousands of metres high with intergranular spaces filled with H₂ (±CH₄) may have been established with some hydrogen leaking into the surface domain while still more was produced at depth. Disturbance by occasional impacts or airbursts, large or small, would violently release great columns of pressurized hydrogen, which, ignited, would burn until exhaustion. Such sustained heating events could be repeated. Exotic products might come from materials formed cold in the outer solar system, transformed in a great flickering flame with temperatures perhaps exceeding 1800°C.  相似文献   

Vitreous state in nature—Origin and properties     

Klaus Heide  Gerhard Heide 《Chemie der Erde / Geochemistry》2011,71(4):305-335

Vitreous materials are quite routinely found in natural settings. Most of them are aluminosilicates, which often occur in large deposits. Considering the geological formations in which naturally occurring vitreous aluminosilicates are found, they have generally remained stable for more than 1 Ma on the earth's surface, even in different geological and climatic environments. These non-crystalline solids played a very important role in the development of ancient human civilizations, long before the introduction of metallic tools. Today, however, the properties of natural glasses are of interest to mankind for completely different reasons. For example, industrial glasses are used today for encapsulating toxic wastes, especially radioactive waste, which remains active for centuries or more, in order to prevent the unwanted transfer of harmful materials to the environment. The chemical compositions of industrially produced glasses are in large part different from the compositions of natural glasses. Little is quantitatively known about the stability of industrial glasses over very long periods of time (>10,000 years). However, the physical and chemical stability of natural aluminosilicate glasses is known to extend over very long periods of time.The advancement of technological design to prevent or at least minimize the melt down of toxic waste during the encapsulation process is currently a major challenge, using glasses of natural chemical composition. Brecciated glass, which is found frequently in natural settings, provides a special clue to the possibility of producing vitreous solids by sintering glass fragments without melting the cullets. It is essential to prevent melting of the cullets because the melt has the potential of chemically reacting with the toxic waste.This paper summarizes the geological, chemical, and physical facts concerning naturally produced glasses, and seeks to establish a recognized database for further research in the domain of understanding the glass-forming processes that occur in nature. Furthermore, the authors hope to stimulate research into the utilization of natural resources that to solve the problem of storing of toxic waste safely.Major and trace element data have been collected over the past 100 years. These data constitute a sufficient basis for the chemical characterization of natural glasses. More information about the major elements is not required, in order to understand the chemical properties of these materials. On the other hand, large gaps in compositional data exist where other related components are concerned: e.g., in the case of “water-species”, with its different forms of bonding in silicates or oxygen (oxygen fugacity), CO₂-, sulphur - or hydrocarbons (methane)-, hydrogen-, chlorine-and fluorine-species. All these components have a significant impact on the properties of glasses, even when present only in minor quantities. Glass textures and crystal morphologies reflect the processes of nucleation and crystal growth in a glass-forming matrix during the cooling and reheating cycles which are currently not thoroughly understood. In nature, the processes that led to the formation of vitreous materials are very different from those used in the production of industrial glasses. The different genetic conditions under which glass formation occurs permit differentiation between magmatic and metamorphic vitreous solids. Sedimentary and biogenetic processes also contribute to the formation of non-crystalline solids.  相似文献   

Experimental abiotic alteration of igneous and manufactured glasses     

Martin R. Fisk  Jean-Louis Crovisier  José Honnorez 《Comptes Rendus Geoscience》2013,345(4):176-184

Pits in ocean basalt glass are often attributed to the activity of microorganisms, however, neither the mechanism of formation of pits in glass nor the involvement of microorganisms have been confirmed by experimentation. Experimental abiotic corrosion of basalt glass with 1% hydrofluoric acid (HF), a proxy for more slowly acting organic acids, produces pits that are similar in size, shape, and distribution to pits found in basalt glass collected from the ocean floor and basalt glass incubated with microorganisms. This pit formation by HF etching was demonstrated by comparing secondary electron images taken before and after the acid treatment. The formation of pits by abiotic corrosion of basalt glass is an alternate hypothesis for the origin of these features, and the interpretation of these features as biomarkers may require a resolution of these alternative hypotheses.  相似文献