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1.
Methodology for preliminary assessment of Natech risk in urban areas   总被引:1,自引:0,他引:1  
Concern for natural hazard-triggered technological disasters (Natech disasters) in densely populated and industrialized areas is growing. Residents living in urban areas subject to high natural hazard risk are often unaware of the potential for secondary disasters such as hazardous materials releases from neighboring industrial facilities, chemical storage warehouses or other establishments housing hazardous materials. Lessons from previous disasters, such as the Natech disaster during the Kocaeli earthquake in Turkey in 1999 call for the need to manage low frequency/high consequence events, particularly in today’s densely populated areas. However, there is little guidance available on how local governments and communities can assess Natech risk. To add to the problem, local governments often do not have the human or economic resources or expertise to carry out detailed risk assessments. In this article, we propose a methodology for preliminary assessment of Natech risk in urban areas. The proposed methodology is intended for use by local government officials in consultation with the public. The methodology considers possible interactions between the various systems in the urban environment: the physical infrastructure (e.g., industrial plants, lifeline systems, critical facilities), the community (e.g., population exposed), the natural environment (e.g., delicate ecosystems, river basins), and the risk and emergency management systems (e.g., structural and nonstructural measures). Factors related to vulnerability and hazard are analyzed and qualitative measures are recommended. Data from hazardous materials releases during the Kocaeli, Turkey earthquake of August 17, 1999 are used as a case study to demonstrate the applicability of the methodology. Limitations of the proposed methodology are discussed as well as future research needs.
Norio OkadaEmail:
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The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu2+ concentrations in excess of 10− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu2+ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems.  相似文献   
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在山西省重点地区固体废弃物现状调查研究的基础上,通过试样试验,分析研究了固体废弃物对土壤、大气、水环境的污染,探讨了对固体废弃物的治理及利用,为研究矿山生态环境地质研究提供参考,同时积累工作经验。  相似文献   
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This paper examines historical and spatial trends in hazardous materials transportation spills from 1971 to 1991. While the number of spills Inc.reased steadily during the 1970s, peaking in 1978–1979, there has been a decline in frequency sInc.e then largely due to modifications in reporting. Monetary damages have the opposite temporal pattern, with major Inc.reases recorded from 1982 onward. Death and injury statistics are more variable. Spatially, accidents are more prevalent in the Rust Belt extending from the Northeast corridor westward to the Great Lakes states, as well as in the Southeast. The greatest potential risk to the public is found in smaller, more densely populated industrial states such as New Jersey, Delaware, and Maryland. The spatial distribution, however, has not changed. Potential risk sources (e.g., chemical industry, number of hazardous waste facilities, number of railroad miles) are the best predictors of hazmat Inc.ident frequency. Mitigation efforts (statewide regulatory and/or management policies) also help explain the variability in hazmat Inc.idents.  相似文献   
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垃圾产生于社会的每一个角落,垃圾也反映了人类生活的各个方面。可是,直至最近,社会依然极少理会垃圾中真正蕴藏着些什么,以及垃圾能够告诉我们些什么。1973年美国图森市亚利桑那大学威廉·拉舍基博士(WilliamLRathje)及其同事们所建立并发展的垃级计划,标志着一门新科学──垃圾学的兴起,即垃圾的系统研究、垃圾产生、运移、利用和处置的机理以及相关的社会经济和环境问题。美国和其它少数国家的垃圾学研究所揭示的各种事实、定律和原理,正划时代地碰击着现代社会、社会心理学、市场和许多其它领域,大量的城市固体废物不仅意味着自然资源的巨大浪费,而且垃圾处理,无论焚化或者填埋,都对环境构成了严重污染的威胁,尤其是对地下水资源。垃圾的管理、再循环和处置费用是昂贵的,而且总是受到错综复杂的社会和法律冲突的挑战,纽约和美国东部其它人口稠密地区所面临的严峻形势就是最好的例证,解决现今进退维谷的垃圾问题,需要包括技术的、社会的、环境的、经济的、政治的、法律的和公共教育在内的多方面协作。中国正经历着令人振奋的经济发展时期。预计以现在的国民经济发展速度,以及因巨量人口而导致的社会消费的急剧增长,在未来10~20年内,很有可能导致严重的  相似文献   
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Quality Requirements for Fresh Waters: Water Quality Targets, Water Quality Objectives, and Chemical Water Quality Classification In the Federal Republic of Germany, water quality requirements for the protection of inland surface waters against hazardous substances are formulated on the basis of a quality targets derivation concept developed jointly by the Federal Government and the Federal States. The quality requirements were termed “water quality targets” in order to make it clear that the values derived are orientational values rather than legally binding limit values. The international comparison of quality requirements for surface waters shows that, on the whole, the national quality targets ensure a high level of protection. According to present scientific knowledge, impairments of uses, such as supply of drinking water, or risks to aquatic communities need not to be expected if the quality targets are complied with. A comparison of water quality data with the water quality targets makes it possible, on the one hand, to identify those substances whose inputs must be further reduced; on the other hand, it also shows that, for a number of substances, there is no need at present for concern over their adversely water quality. A further differentiation of the aquatic hazard potential of pollutants allows a water quality classification system to be developed on the basis of the quality targets derivation concept. The basic elements of this water quality classification system are presented, and its application is explained by way of examples.  相似文献   
8.
Tooeleite, nominally Fe63+(As3+O3)4(SO4)(OH)4·4H2O, is a relatively uncommon mineral of some acid-mine drainage systems. Yet, if it does occur, it does so in large quantities, indicating that some specific conditions favor the formation of this mineral in the system Fe-As-S-O-H. In this contribution, we report the thermodynamic properties of synthetic tooeleite. The sample was characterized by powder X-ray diffraction, scanning electron microscopy, extended X-ray absorption fine-structure spectroscopy, and Mössbauer spectroscopy. These methods confirmed that the sample is pure, devoid of amorphous impurities of iron oxides, and that the oxidation state of arsenic is 3+. Using acid-solution calorimetry, the enthalpy of formation of this mineral from the elements at the standard conditions was determined as −6196.6 ± 8.6 kJ mol−1. The entropy of tooeleite, calculated from low-temperature heat capacity data measured by relaxation calorimetry, is 899.0 ± 10.8 J mol−1 K−1. The calculated standard Gibbs free energy of formation is −5396.3 ± 9.3 kJ mol−1. The log Ksp value, calculated for the reaction Fe6(AsO3)4(SO4)(OH)4·4H2O + 16H+ = 6Fe3+ + 4H3AsO3 + SO42− + 8H2O, is −17.25 ± 1.80. Tooeleite has stability field only at very high activities of aqueous sulfate and arsenate. As such, it does not appear to be a good candidate for arsenic immobilization at polluted sites. An inspection of speciation diagrams shows that the predominance field of Fe3+ and As3+ overlap only at strongly basic conditions. The formation of tooeleite, therefore, requires strictly selective oxidation of Fe2+ to Fe3+ and, at the same time, firm conservation of the trivalent oxidation state of arsenic. Such conditions can be realized only by biological systems (microorganisms) which can selectively oxidize one redox-active element but leave the other ones untouched. Hence, tooeleite is the first example of an “obligatory” biomineral under the conditions prevailing at or near the Earth's surface because its formation under these conditions necessitates the action of microorganisms.  相似文献   
9.
Understanding transpiration and plant physiological responses to environmental conditions is crucial for the design and management of vegetated engineered covers. Engineered covers rely on sustained transpiration to reduce the risk of deep drainage into potentially hazardous wastes, thereby minimizing contamination of water resources. This study quantified temporal trends of plant water potential (ψp), stomatal conductance (gs), and transpiration in a 4‐year‐old evergreen woody vegetation growing on an artificial sandy substrate at a mine waste disposal facility. Transpiration averaged 0.7 mm day?1 in winter, when rainfall was frequent, but declined to 0.2 mm day?1 in the dry summer, when the plants were quite stressed. In winter, the mean ψp was ?0.6 MPa at predawn and ?1.5 MPa at midday, which were much higher than the corresponding summer values of ?2.0 MPa and ?4.8 MPa, respectively. The gs was also higher in winter (72.1–95.0 mmol m?2 s?1) than in summer (<30 mmol m?2 s?1), and negatively correlated with ψp (p < 0.05, r2 = 0.71–0.75), indicating strong stomatal control of transpiration in response to moisture stress. Total annual transpiration (147.2 mm) accounted for only 22% of the annual rainfall (673 mm), compared with 77% to 99% for woody vegetation in Western Australia. The low annual transpiration was attributed to the collective effects of a sparse and young vegetation, low moisture retention of the sandy substrate, and a superficial root system constrained by high subsoil pH. Amending the substrate with fine‐textured materials should improve water storage of the substrate and enhance canopy growth and deep rooting, while further reducing the risk of deep drainage during the early stages of vegetation establishment and in the long term. Overall, this study highlights the need to understand substrate properties, vegetation characteristics, and rainfall patterns when designing artificial ecosystems to achieve specific hydrological functions. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
10.
本文论述了某污染的工业废物填埋场场址的地质、水文地质条件,应用水化学方法、环境同位素技术(地下水中氚及氢、氧稳定同位素)和同位素单孔示踪技术等同位素水文学领域中的新方法对区内地下水的活动条件以及填埋场场址区分布的第四系孔隙潜水和第三纪红层孔隙-裂隙水的成因进行了分析,测量并确定了填埋场下部地下水的流速及流向。研究结果表明场区地下水的运动与地表水无直接水力联系。污染的工业废物填埋后不会通过地下水的迁移造成对地表水的污染,进而证实填埋场的地质、水文地质条件对处置污染的工业废物是安全可靠的。  相似文献   
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