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1.
Laboratory experiments on the New Zealand freshwater mussel Echyridella menziesii were used to investigate the short-term effects (7–8 days) of food type on rates of biodeposition and benthic substrate respiration. Post-feeding biodeposition rates ranged from 0.34 to 1.52?mg?g?1?h?1 (mean?=?0.50?mg g?1?h?1) and were unaffected by the addition of toxin-producing Microcystis. Addition of suspended sediment (30?mg?L?1) visibly altered substrate composition, and increased total and inorganic biodeposit production rates by 24–33% compared to mussels fed commercial phytoplankton stock. Biodeposition rates of mussels in lake bed substrates were 38% higher than those in silica sand for identical feeding regimes, suggesting that a significant proportion of material produced in this experiment could have been derived from feeding on organic matter in the lake bed sediments. Respiration rates were higher in treatments with Microcystis but were unaffected by the presence of mussels. This laboratory study suggests that biodeposition by E. menziesii is resilient to short-term exposure to Microcystis, and highlights the ability of mussels to alter benthic substrate composition by incorporating suspended sediment into substrates.  相似文献   
2.
A critical evaluation of literature values for the solubility products, K sp NBS = [Fe2+][HS] Fe2+ HS (H NBS + )–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe2S2 species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)2 and (Fe (HS)3) are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.  相似文献   
3.
Due to the high number of variables involved in mine profitability studies, it is often very difficult to establish connections among them in order to provide a blend of market saleable quality products. In this sense, analytical chemistry together with chemometry are essential and indispensable disciplines to tackle these studies. The aim of this work was to demonstrate the utility of these disciplines to carry out optimization studies of iron mines. For this purpose, one of the most important iron mines of the Iberian Peninsula was chosen, sited in the mountain range of Sierra Menera, near the location of Ojos Negros (Teruel, Spain). Geological, mineralogical and chemical composition of 148 samples was analyzed, corresponding to different depths of three drill holes (named TE1, TE2 and TE3). In particular, aspects concerning to chemical composition are very important, since the mean contents of certain elements, such as phosphorus, sodium and potassium, should be restricted to the established limits to prevent that companies can drive back the raw material if they do not fulfil the necessary requirements. On the other hand, the large number of analysed samples drove us to use a statistical processing of the data. Among other aspects, it provides a way to find possible connections among a high number of variables and classify samples into compositional groups sharing similar composition, in order to limit the mineralised area and to obtain enough information about the amount of those chemical elements associated to iron ores. Data obtained from all these analytical techniques were in good agreement and provide a methodology that can be of wide interest applied to different geological studies.  相似文献   
4.
Abstract. The oxygen consumption of Eudendrium glomeratum was measured monthly, throughout the period of active presence of the species in the field, to obtain indications on its physiological condition in the different phases of the cycle. Sets of one hundred polyps were assayed in the laboratory under normothermic (according to field temperature: 14–19°C) and hyperthermic conditions (22–25°C). The different response to identical temperatures at the extremes of the cycle, together with a differential ability to face stressful conditions in the same periods, suggests that other factors, besides temperature, regulate the seasonal cycle of Eudendrium glomeratum.  相似文献   
5.
Carbon cycle is connected with the most important environmental issue of Global Change.As one of the major carbon reservoirs, oceans play an important part in the carbon cycle. In recent years, iron seems to give us a good news that oceanic iron fertilization could stimulate biological productivity as CO2 sink of human-produced CO2. Oceanic iron fertilization experiments have verified that adding iron into high nutrient low chlorophyll (HNLC) seawaters can increase phytoplankton production and export organic carbon, and hence increase carbon sink of anthropogenic CO2, to reduce global warming. In sixty days, the export organic carbon could reach 10 000 times for adding iron by model prediction and in situ experiment, i.e. the atmospheric CO2 uptake and inorganic carbon drawdown in upper seawaters also have the same magnitude. Therefore, oceanic iron fertilization is one of the strategies for increasing carbon sink of anthropogenic CO2. The paper is focused on the iron fertilization, especially in situ o  相似文献   
6.
Christian  Schiller 《Marine Ecology》1993,14(3):221-238
Abstract. The temperate, symbiotic coral Cladocora caespitosa occurs naturally with variable numbers of zooxanthellae. This allows us to study differences in the physiology of symbiotic and "non-symbiotic" polyps and to correlate them with zooxanthellae activities.
Zooxanthellae density in "dark" (normal-colored) polyps was 50 times higher than in "white" (bleached) polyps.
The chlorophyll a content per zooxanthella was 3 times, and Chi c was 13 times higher in white polyps than in dark ones. O2-flux experiments were conducted with colonies in situ and with single polyps - dark and white - under laboratory conditions. Two approaches were used to evaluate the contribution of zooxanthellae translocation products to animal respiration. Both revealed that the animal tissues derive a higher benefit from the zooxanthellae during periods of low water temperature than during warm periods.  相似文献   
7.
The dynamics of benthic primary production and community respiration in a shallow oligotrophic, marine lagoon (Fællestrand, Denmark) was followed for 1·5 years. The shape of the annual primary production cycle was explained primarily by seasonal changes in temperature (r2 = 0·67-0·72) and daylength (r2 = 0·63), whereas temperature almost explained all variation in benthic community respiration (r2 = 0·83-0·87). On a daily basis the benthic system was autotrophic during spring and summer supplied by 'new' and 'regenerated' nitrogen and predominantly heterotrophic during fall and winter caused by light and nutrient limitation. The linear depth-relationship between porewater alkalinity and ammonium indicated that the C:N ratio of mineralized organic matter is low in spring and summer (3-6) and high in fall and winter (9-16). This is inversely related to net primary production and thus the input of labile, nitrogen-rich algal cells. Accordingly, mineralization occurred predominantly in the upper 2-5 cm of the sediment. The pool of reactive material (microalgal cells) was estimated to account for 12% of total organic carbon in the upper 3 cm, and had an average turnover time of less than 1 month in summer. Assimilation of organic carbon by benthic animals was equivalent to about 30% of the annual gross primary production. Grazing reduced chlorophyll a concentration in the sediment during summer and spring to values 30-40% lower than in winter, but maintained a 3-4 times higher specific microalgal productivity. The rapid turnover of organic carbon and nitrogen, and important role of benthic microalgae showed that the benthic community in this oligotrophic lagoon is of a very dynamic nature.  相似文献   
8.
The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.  相似文献   
9.
不同pH海水和不同时间处理紫菜、石莼对呼吸强度和致死酸度试验结果表明,紫菜比石莼耐酸力强。在海水温度为18℃条件下,分别用pH_2、pH_3、pH_4、pH_5、pH_6、pH_7、pH_8处理,处理时间20分钟,紫菜除pH_2处理对呼吸强度有抑制作用和培养5天后有20%死亡外,pH_3、pH_4、pH_5、pH_6、pH_7、pH_8各组处理对呼吸强度都有促进作用,培养5天后没有死亡现象,而石莼经pH_2、pH_3处理,对呼吸强度都有抑制作用,培养5天后,pH_2处理组全部死亡,pH_3处理有50%死亡。pH_3和pH_4在海水温度为18℃条件下,处理时间为40分钟时,对紫菜呼吸强度有促进作用,培养5天报,pH_3处理组仅有20%死亡。而pH_3对石莼呼吸强度有抑制作用,培养5天后,全部灭亡。在生产上是否可以考虑用pH_3的海水处理紫菜网帘以达到消除石莼(杂藻)的目的,将是一项具有生产意义的待试验课题。  相似文献   
10.
In July 2002, a combination of underway mapping and discrete profiles revealed significant along-shore variability in the concentrations of manganese and iron in the vicinity of Monterey Bay, California. Both metals had lower concentrations in surface waters south of Monterey Bay, where the shelf is about 2.5 km wide, than north of Monterey Bay, where the shelf is about 10 km wide. During non-upwelling conditions over the northern broad shelf, dissolvable iron concentrations measured underway in surface waters reached 3.5 nmol L−1 and dissolved manganese reached 25 nmol L−1. In contrast, during non-upwelling conditions over the southern narrow shelf, dissolvable iron concentrations in surface waters were less than 1 nmol L−1 and dissolved manganese concentrations were less than 5 nmol L−1. A pair of vertical profiles at 1000 m water depth collected during an upwelling event showed dissolved manganese concentrations of 10 decreasing to 2 nmol L−1, and dissolvable iron concentrations of 12–20 nmol L−1 in the upper 100 m in the north, compared to 3.5–2 nmol L−1 Mn and 0.6 nmol L−1 Fe in the upper 100 m in the south, suggesting the effect of shelf width influences the chemistry of waters beyond the shelf.These observations are consistent with current understanding of the mechanism of iron supply to coastal upwelling systems: Iron from shelf sediments, predominantly associated with particles greater than 20 μm, is brought to the surface during upwelling conditions. We hypothesize that manganese oxides are brought to the surface with upwelling and are then reduced to dissolved manganese, perhaps by photoreduction, following a lag after upwelling.Greater phytoplankton biomass, primary productivity, and nutrient drawdown were observed over the broad shelf, consistent with the greater supply of iron. Incubation experiments conducted 20 km offshore in both regions, during a period of wind relaxation, confirm the potential of these sites to become limited by iron. There was no additional growth response when copper, manganese or cobalt was added in addition to iron. The growth response of surface water incubated with bottom sediment (4 nmol L−1 dissolvable Fe) was slightly greater than in control incubations, but less than in the presence of 4 nmol L−1 dissolved iron. This may indicate that dissolvable iron is not as bioavailable as dissolved iron, although the influence of additional inhibitory elements in the sediment cannot be ruled out.  相似文献   
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