Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Overview of In - Situ Biodegradation and Enhancement     

DONG Jun  Anthony Adzomani  Zhao Yongsheng 《世界地质(英文版)》2002,5(1)

Microbial degradation technologies have been developed to restore ground water quality in aquifers polluted by organic contaminants effectively in recent years. However, in course of the degradation, the formation of biofilms in ground water remediation technology can be detrimental to the effectiveness of a ground water remediation project. Several alternatives are available to a remedial design engineer, such as Permeable Reactive Barriers (PRBs) and in -situ bioremediation, Hydrogen Releasing Compounds (HRCs) barrier, Oxygen Releasing Compounds (ORCs) barrier etc. which are efficient and cost- effective technologies. Excessive biomass formation renders a barrier ineffective in degrading the contaminants, Efforts are made to develop kinetics models which accurately determine bio - fouling and bio - filn formation and to control excessive biomass formation.  相似文献   

Discovery of 13 New Variable Stars in the Field of the Open Cluster NGC 2168 （M35）     

Juei-Hwa Hu  Wing-Huen Ip 《中国天文和天体物理学报》2005,5(4):356-362

A wide-field time-series CCD photometric survey of variable stars in the field of the open cluster NGC 2168 was carried out using the BATC Schmidt telescope. In total 13 new variable stars are discovered with three W UMa systems, one EA type and two EB type eclipsing binaries (one of them could be a W UMa system), and seven pulsating stars including three candidates of δScuti stars.  相似文献   

Metamorphic phase relations in orthopyroxene-bearing granitoids: implication for high-pressure metamorphism and prograde melting in the continental crust     

S. K. BHOWMIK  L. SAHA  S. DASGUPTA  M. FUKUOKA 《Journal of Metamorphic Geology》2009,27(4):295-315

In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K₂O, Ca/(Ca + Na)_rock and FeO_tot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H₂O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB.  相似文献   

LU Vel (GJ 375): A M3.5Ve Flare and Double-Lined Spectroscopic Binary     

D. Montes  M. C. Gálvez  M. J. Fernández-Figueroa  I. Crespo-Chacón 《Astrophysics and Space Science》2006,304(1-4):367-369

High resolution echelle spectroscopic observations taken with the FEROS spectrograph at the 2.2 m telescope ESO confirm the binary nature of the flare M3.5V star LU Vel (GJ 375, RE J0958-462) previously reported by Christian and Mathioudakis (2002). Emission of similar intensity from both components is detected in the Balmer, Na i D₁&D₂, He i D₃, Ca ii H&K, and Ca ii IRT lines. We have determined precise radial velocities by cross correlation with radial velocity standard stars, which have allowed us to obtain for the first time the orbital solution of the system. The binary consists of two near-equal M3.5V components with an orbital period shorter than 2 days. We have analyzed the behaviour of the chromospheric activity indicators (variability and possible flares). In addition, we have determined its rotational velocity and kinematics.  相似文献   

Reef exploration in the East Sengkang Basin,Sulawesi, Indonesia     

A.M. Grainge  K.G. Davies 《Marine and Petroleum Geology》1985,2(2):142-155

Reconnaissance seismic shot in 1971/72 showed a number of well defined seismic anomalies within the East Sengkang Basin which were interpreted as buried reefs. Subsequent fieldwork revealed that Upper Miocene reefs outcropped along the southern margin of the basin. A drilling programme in 1975 and 1976 proved the presence of shallow, gas-bearing, Upper Miocene reefs in the northern part of the basin. Seismic acquisition and drilling during 1981 confirmed the economic significance of these discoveries, with four separate accumulations containing about 750 × 10⁹ cubic feet of dry gas in place at an average depth of 700 m. Kampung Baru is the largest field and contains over half the total, both reservoir quality and gas deliverability are excellent. Deposition in the East Sengkang Basin probably started during the Early Miocene. A sequence of Lower Miocene mudstones and limestones unconformably overlies acoustic basement which consists of Eocene volcanics. During the tectonically active Middle Miocene, deposition was interrupted by two periods of deformation and erosion. Carbonate deposition became established in the Late Miocene with widespread development of platform limestones throughout the East Sengkang Basin. Thick pinnacle reef complexes developed in the areas where reef growth could keep pace with the relative rise in sea level. Most reef growth ceased at the end of the Miocene and subsequent renewed clastic sedimentation covered the irregular limestone surface. Late Pliocene regression culminated in the Holocene with erosion. The Walanae fault zone, part of a major regional sinistral strike-slip system, separates the East and West Sengkang Basins. Both normal and reverse faulting are inferred from seismic data and post Late Pliocene reverse faulting is seen in outcrop.  相似文献   

Petroleum exploration potential of Tamtsag Basin     

SUN Guo-qing  GUO Qing-xia  ZHANG Ya-jin  ZHAO Hong-wen 《世界地质(英文版)》2004,7(1)

The Tamtsag Basin is located in the extreme eastern portion of the Mongolia. The Basin and its counterpart in China (the Hailar Basin) are united a whole basin on the structural setting. In recent years, the Tamtsag Basin attracts more and more attention with the important exploration discovered in the 19th block by SOCO and in Hailar Basin of China. This paper discusses the exploration potential of Tamtsag Basin from the viewpoint of petroleum geology.  相似文献   

多条太阳光球FeI线在磁场中形成及形成深度的综合分析(Ⅰ)     

宋慰鸿  艾国祥  张洪起  李孝昌 《中国天文和天体物理学报》1990,(1)

针对多通道滤光器太阳磁场望远镜的磁场观测定标及掌握(所采用的)谱线特征之需要,取VAL宁静太阳大气模型计算了7条Fel光球线的Stokes轮廓、形成深度、贡献函数分布,从而较为系统地对多条反常及正常Zeeman线的特征及性质作出了分析与总结,解释了在磁光效应影响下Stokes Q,U参量的形成深度曲线在近线心区域处出现陡峭峰值的原因。  相似文献   

NGC 1883: a neglected intermediate-age open cluster located in the outskirts of the Galactic disc     

Giovanni Carraro  Gustavo Baume  Sandro Villanova 《Monthly notices of the Royal Astronomical Society》2003,343(2):547-551

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The evolution of binary fractions in globular clusters     

N. Ivanova  K. Belczynski  J. M. Fregeau  F. A. Rasio 《Monthly notices of the Royal Astronomical Society》2005,358(2):572-584

We study the evolution of binary stars in globular clusters using a new Monte Carlo approach combining a population synthesis code ( startrack ) and a simple treatment of dynamical interactions in the dense cluster core using a new tool for computing three- and four-body interactions ( fewbody ). We find that the combination of stellar evolution and dynamical interactions (binary–single and binary–binary) leads to a rapid depletion of the binary population in the cluster core. The maximum binary fraction today in the core of a typical dense cluster such as 47 Tuc, assuming an initial binary fraction of 100 per cent, is only ∼ 5–10 per cent. We show that this is in good agreement with recent Hubble Space Telescope observations of close binaries in the core of 47 Tuc, provided that a realistic distribution of binary periods is used to interpret the results. Our findings also have important consequences for the dynamical modelling of globular clusters, suggesting that 'realistic models' should incorporate much larger initial binary fractions than has usually been the case in the past.  相似文献