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1.
Mineral assemblages in Al2O3‐rich, SiO2‐ and K2O‐poor metapelitic rocks from the western Odenwald Crystalline Complex (Variscan Mid‐German Crystalline Rise, southern Germany) include corundum, spinel, cordierite, sillimanite, garnet and staurolite. Quartz is absent from almost all samples. Therefore, the applicability of conventional geothermobarometry is very limited or even impossible. Detailed petrographic investigation on selected samples permits inference of the sequence of appearance and disappearance of several mineral assemblages. The recognition of such partial re‐equilibration stages and their associated mineral assemblages, together with mineral stabilities predicted from KFMASH pseudosections, enables the determination of the pressure‐temperature (P–T) trajectories experienced by these rocks during the Variscan metamorphism. The rocks were metamorphosed under low‐P/high‐T conditions and underwent an anti‐clockwise P–T evolution. A pressure increase from about 2 kbar to 4 ± 0.5 kbar was accompanied by heating. Peak metamorphic conditions were reached at pressures of 4 ± 0.5 kbar and temperatures of at least 640 °C, probably even higher. The retrograde evolution is characterised by near‐isobaric cooling from ≥ 640 °C to approximately 550 °C. The rocks underwent the anti‐clockwise evolution in a subduction‐related magmatic arc setting. The close spatial association of the low‐P/high‐T rocks with recently discovered metabasic eclogites in the eastern part of the Odenwald Crystalline Complex may indicate a fossil paired metamorphic belt in the Central European Variscides. 相似文献
2.
A. Zeh 《Journal of Metamorphic Geology》2001,19(4):329-350
Generally, P–T pseudosections for reduced compositional systems, such as K2O–FeO–MgO–Al2O3–SiO2–H2O, Na2O–K2O–FeO–MgO–Al2O3–SiO2–H2O and MnO–K2O–FeO–MgO–Al2O3–SiO2–H2O, are well suited for inferring detailed P–T paths, comparing mineral assemblages observed in natural rocks with those calculated. Examples are provided by P–T paths inferred for four metapelitic samples from a 1 m2 wide outcrop of the Herbert Mountains in the Shackleton Range, Antarctica. The method works well if the bulk composition used is reconstituted from average mineral modes and mineral compositions (AMC) or when X‐ray fluorescence (XRF) data are corrected for Al2O3 and FeO. A plagioclase correction is suitable for Al2O3. Correction for FeO is dependent on additional microscopic observations, e.g. the kind and amount of opaque minerals. In some cases, all iron can be treated as FeOtot, whereas in others a magnetite or hematite correction yields much better results. Comparison between calculated and observed mineral modes and mineral compositions shows that the AMC bulk composition is best suited to the interpretation of rock textures using P–T pseudosections, whereas corrected XRF data yield good results only when the investigated sample has few opaque minerals. The results indicate that metapelitic rocks from the Herbert Mountains of the Northern Shackleton Range underwent a prograde P–T evolution from about 600 °C/5.5 kbar to 660 °C/7 kbar, followed by nearly adiabatic cooling to about 600 °C at 4.5 kbar. 相似文献
3.
J. RECHE F. J. MARTINEZ M. L. ARBOLEYA C. DIETSCH & W. D. BRIGGS 《Journal of Metamorphic Geology》1998,16(3):379-394
Kyanite replaces andalusite in a belt of Ordovician and Silurian pelitic rocks that form a narrow synform pinched between high-grade antiforms in NW Variscan Iberia. Kyanite occurs across the belt in Al-rich, black pelites in assemblages I: kyanite–chloritoid–chlorite–muscovite and II: kyanite–staurolite– chlorite–muscovite. In I, kyanite occurs in the matrix and in kyanite–muscovite aggregates that pseudomorph earlier andalusite porphyroblasts. The aggregates are found across the belt and can still be recognized in assemblage II and even in III: andalusite–staurolite–biotite–muscovite, this latter being a hornfelsic Silurian schist where kyanite is relic and staurolite occurs in the matrix, and is resorbed inside new massive pleochroic andalusite. KFMASH and MnKFMASH pseudosections have been constructed using Thermocalc for Al-rich and Al-poorer compositions from the belt. Chloritoid zoning in Al-rich rocks containing assemblage I, plus chloritoid–chlorite thermometry complemented with garnet–chlorite thermometry in Al-poorer lithologies, mean that the path is one of increasing pressure and temperature. Conditions prior to assemblage I, with earlier andalusite stable, are those of the andalusite–chloritoid– chlorite field as testified by chloritoid enclosed in andalusite porphyroblast rims. The passage from assemblage I to II implies a prograde path within the kyanite field. Assemblage III represents peak conditions, indicating a prograde staurolite-consuming reaction across a KFMASH field, leading eventually to a locally found andalusite–biotite–muscovite hornfels. The lowest pressure stages are recorded by cordierite–biotite in Al-poor pelites. Garnet-bearing MnKFMASH assemblages in Al-poorer pelites record conditions similar to assemblages II and III. The replacement of andalusite by kyanite in assemblage I is attributed to downdragging of andalusite-bearing rocks into a synform as testified by the strained andalusite porphyroblasts affected by a subvertical crenulation cleavage. Prograde metamorphism in the eastern contact of the belt is due to heat transferred to the belt from the ascending high grade antiform across the Vivero fault. 相似文献
4.
Determining whether a reaction can be written between a set of minerals within error is an example of the more general problem of determining whether a set of compositions are coplanar within error. Generally if the compositions are of minerals, ‘within error’ should allow the minerals to maintain stoichiometry. The problem is addressed via the addition of a ‘bogus’ composition to the set, and calculating the reaction coefficients for a reaction between the compositions in this augmented set. A reaction can be written if a confidence interval on the reaction coefficient of ‘bogus’ includes zero. The reaction coefficients can be solved for directly when the problem is posed in terms of least squares with equality constraints. The confidence interval is determined with a bootstrap method, allowing the result to depend on the scatter of the data around the solution of the least squares problem, not on the data uncertainties 相似文献
5.
In the southeastern Reynolds Range, central Australia, a low- P granulite facies metamorphism affected two sedimentary sequences: the Lander Rock Beds and the Reynolds Range Group. In the context of the whole of the Reynolds Range and the adjacent Anmatjira Range, this metamorphism is M3 in a sequence M1–4 that occurred over a period of 250 Ma. In particular, M1 affected the Lander Rock Beds prior to the deposition of the Reynolds Group. M3 has an areally restricted, high-grade area in the southeastern Reynolds Range, affecting both the Reynolds Range Group and the underlying Lander Rock Beds. The effects of M3 are characterized by spinel + quartz-bearing peak metamorphic assemblages in metapelites, which imply peak conditions of ≥750°C and 4.5 ± 1 kbar, and involved isobaric cooling or compression with cooling. It is concluded that one of a series of thermal perturbations caused by thinning of mantle lithosphere contemporaneous with crustal thickening was responsible for M3. In the southeastern Reynolds Range, evidence of both the unconformity between the two rock groups and previous metamorphism/deformation has been completely erased by recrystallization during M3–D3. 相似文献
6.
Abstract In metapelitic schists of the north-eastern Weekeroo Inliers, Olary Block, Willyama Supergroup, South Australia, syn-S1 and syn-S2 assemblages involving staurolite, garnet, biotite and another mineral, most probably cordierite, were overgrown by large syn-S3 andalusite porphyroblasts, owing to isobaric heating from metamorphic conditions that existed during the development of S2. Conditions during the development of S3 probably just reached the andalusite—sillimanite transition. During the development of S4, at somewhat lower temperatures than those that accompanied the development of S3, the following reaction occurred:
staurolite + chlorite + muscovite ± biotite + andalusite + quartz + H2 O.
The amount of retrogression is controlled primarily by the amount of H2 O added by infiltration. As the syn-S3 matrix assemblage was stable during the development of S4, but the andalusite porphyroblasts were no longer stable with the matrix when H2 O was added, the retrogression is focused in and around the porphyroblasts. With enough H2 O available, and if quartz was consumed before biotite in a porphyroblast, then the following reaction occurred:
staurolite + chlorite + muscovite + corundum ± biotite + andalusite + H2 O.
This reaction allowed corundum inclusions in the andalusite to grow, regardless of the presence of quartz in the matrix assemblage. 相似文献
staurolite + chlorite + muscovite ± biotite + andalusite + quartz + H
The amount of retrogression is controlled primarily by the amount of H
staurolite + chlorite + muscovite + corundum ± biotite + andalusite + H
This reaction allowed corundum inclusions in the andalusite to grow, regardless of the presence of quartz in the matrix assemblage. 相似文献
7.
Calculated phase equilibria for low- and medium-pressure metapelites in the KFMASH and KMnFMASH systems 总被引：14，自引：1，他引：14
Petrogenetic grids in the KFMASH and KMnFMASH model systems calculated with the software thermocalc 3.1 are presented for the P–T range 0.5–12 kbar and 450–900 °C, for assemblages involving garnet, muscovite, chloritoid, biotite, chlorite, staurolite, cordierite, spinel, orthopyroxene, K‐feldspar, Al2SiO5 phases, quartz, water and melt. Based on calculated compatibility diagrams and P–T and T–MMn [Mn/(Mg + Fe + Mn)] pseudosections for different metapelitic bulk compositions, the principal conclusions are that the addition of Mn to the KFMASH system: (i) enhances the stability of garnet, and, to a lesser extent, aluminosilicates; (ii) reduces the stability of staurolite, cordierite and, to a lesser extent, chlorite; and (iii) extends the medium pressure stability of muscovite and the low‐P stability field of K‐feldspar. The influence of Mn on individual mineral stabilities is strongly related to rock composition, in particular, to the relative contents of Al2O3 and K2O. For metapelites of a range of compositions and MMn values, P–T pseudosections in the KFMASH system, in most cases, do not adequately predict the mineral assemblages observed in natural assemblages under medium and low‐pressure conditions. In contrast, the P–T pseudosections in the KMnFMASH system generally provide more satisfactory results, suggesting that MnO is one of the non‐KFMASH components that should not be neglected in documenting the phase equilibria of medium‐ and low‐P metapelites. 相似文献
8.
Successive overprinting granulite facies metamorphic events in the Anmatjira Range, central Australia 总被引：4，自引：0，他引：4
The Anmatjira Range and adjacent Reynolds Range, central Australia, comprise early Proterozoic metasediments and othogneisses that were affected by three, and possibly four, temporally distinct metamorphic events, M1–4, and deformation events, D1–4, in the period 1820–1590 Ma. The north-western portion of the range, around Mt Stafford, preserves the effects of ±1820 Ma M1-D1, and shows a spectacular lateral transition from muscovite + quartz-bearing schists to interlayered andalusite-bearing migmatites and two-pyroxene granofelses that reflect extremely low-pressure granulite facies conditions, over a distance of less than 10 km. Orthopyroxene + cordierite + garnet + K-feldspar + quartz-bearing gneisses occur at the highest grade, implying peak conditions of ±750°C and 2.5 ± 0.6 kbar. An anticlockwise P–T path for M1 is inferred from syn- to late-D1 sillimanite overprinting andalusite, petrogenetic grid considerations and quantitative estimates of metamorphic conditions for inferred overprinting assemblages. The effects of M1 have been variably overprinted to the south-east by a c. 1760 Ma M2–D2 event. Much of the central Anmatjira Range, around Ingellina Gap, comprises orthogneiss, deformed during D2, and metapelites that have M1 andalusite and K-feldspar overprinted by M2 sillimanite and muscovite. The south-eastern portion of the range, around Mt Weldon, comprises metasediments and orthogneisses that were completely recrystallized during M2–D2, with metapelitic gneisses characterized by spinel + sillimanite + K-feldspar + quartz-bearing assemblages that suggest peak M2 conditions of >750°C and 5.5 ± 1 kbar. Overprinting parageneses in metapelitic gneisses imply that D2 occurred during essentially isobaric cooling. A third granulite facies event, M3, affected rocks in the Reynolds Range, immediately to the south of the Anmatjira Range, at c. 1730 Ma. A possible fourth event, M4, with a minimum age of c. 1590 My affected both Ranges, but resulted in only minor overprinting of M1–3 assemblages. The superimposed effects of M1–4, mapped for the entire Anmatjira–Reynolds Range area, indicate that only minor or no dislocation of the regional geology occurred during any of the metamorphic and accompanying folding, events. Although the immediate cause of each of the metamorphic events involved advection, the ultimate causes were external to the metasediments and most probably external to the crust. 相似文献
9.
The stability of osumilite in metapelitic granulites 总被引：4，自引：1，他引：4
Abstract A petrogenetic grid and related diagrams derived from KFMASH-system experiments demonstrate that osumilite is stable in relatively magnesian bulk rock compositions ( X Mg > 0.6) at temperatures in excess of 875° C and pressures less than 11 kbar. The experiments, involving the dehydration melting of biotite in synthetic metapelites, were conducted in the range 850–1000° C. Both the mineral assemblages and phase compositions reported from well-documented natural examples of osumilite-bearing rocks are reproduced by the experiments at P-T conditions similar to those previously estimated for these occurrences. Peak metamorphic P-T conditions can be reliably inferred from distinctive osumilite-bearing assemblages identified in the phase diagrams, thereby avoiding the problems of diffusional re-equilibration that often prohibits conventional geothermobarometry from recovering peak conditions. Integration of the experimental data with recent independent experiments, after correcting the latter for an underestimated friction correction, allows extension of the petrogenetic grid to higher temperatures. The extended grid is applied to assess and refine the metamorphic history of the Napier Complex, East Antarctica: the high- P stability limit for osumilite in the Napier Complex is 9–10 kbar, the prograde P-T-t path is not necessarily anticlockwise and isobaric cooling in the Scott and Tula mountains occurred, respectively, at pressures greater and less than reactions in the range 8–9 kbar. The stability range for osumilite predicted by the KFMASH-system petrogenetic grid overlaps many more metamorphic terranes than osumilite is found in. Whilst osumilite is not distinctive in thin section and is prone to retrogression, it is possible that carbon dioxide present in the natural system stabilizes cordierite at the expense of osumilite. 相似文献
10.
Metasedimentary gneisses show a rapid change in grade in a 10 km wide low- P /high- T regional aureole at Mt Stafford in the Arunta Block, central Australia. Migmatite occurs in all but the lowermost of five metamorphic zones, which grade from greenschist (Zone 1) through amphibolite (Zones 2–3) to granulite facies (Zones 4–5). The sequence of partial melting reactions inferred for metapelitic rocks is dependant upon protolith, temperature and fluid conditions. The metapelite solidus in Zone 2 reflects vapour-present melting at P ≈3 kbar and T ≈640 °C, melting having initially been controlled by the congruent breakdown of the assemblage Crd–Kfs–Bt–Qtz. At slightly higher temperature, andalusite in leucosome formed via the reaction Kfs+Qtz+Bt+H2 O→And+melt; And+melt having been stabilized by the presence of boron. Sillimanite coaxially replaces andalusite in the high-grade portion of Zone 2. In Zone 3, large aluminosilicate aggregates in leucosome are armoured by Spl–Crd±Grt symplectites. Garnet partially pseudomorphs biotite, cordierite or spinel in high-grade portions of Zone 3. Zone 4 Grt–Crd–Opx-bearing metapsammite assemblages and garnet-bearing leucosome reflect T ≈800 °C and P =2.2±0.9 kbar. In the model KFMASH system the principal vapour-absent melting step reflected significant modal changes related to the breakdown of the As–Bt tie-line and the establishment of the Spl–Crd tie-line; the bulk rock geochemistry of migmatite samples straddle the Spl–Crd tie-line. The aluminous bulk-rock composition of the common bedded migmatite restricted its potential to witness garnet-forming and orthopyroxene-forming reactions, minor textural and modal changes in and above Zone 3 reflecting biotite destablization in biotite-poor assemblages. 相似文献