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In this study, hydrogeologic and hydrochemical information from the Mersin-Erdemli groundwater system were integrated and
used to determine the main factors and mechanisms controlling the chemistry of groundwaters in the area and anthropogenic
factors presently affecting them. The PHREEQC geochemical modeling demonstrated that relatively few phases are required to
derive water chemistry in the area. In a broad sense, the reactions responsible for the hydrochemical evolution in the area
fall into four categories: (1) silicate weathering reactions; (2) dissolution of salts; (3) precipitation of calcite, amorphous
silica and kaolinite; (4) ion exchange. As determined by multivariate statistical analysis, anthropogenic factors show seasonality
in the area where most contaminated waters related to fertilizer and fungicide applications that occur during early summer
season. 相似文献
2.
Quality and durability assessments of the armourstones for two rubble mound breakwaters (Mersin,Turkey) 总被引：1，自引：0，他引：1
Due to economic reasons, natural stones (armourstones) of various sizes and qualities are very frequently used for the constructions
of the breakwaters to protect coastal engineering structures from wave actions. Deterioration of the armourstones with time
in the form of abrasion and disintegration may end up with the damage of the structures. Therefore, it is necessary to investigate
the long-term performance and quality of the armourstones, which should be sound and durable. Mersin and Kumkuyu harbours
were constructed using four different limestones obtained from two quarries. The limestones have different characters and
site performances. In this study, the material and mass properties of the limestones taken from the quarries with known site
performances as armourstones are investigated. The site performances and durability of the limestones are compared with the
field measurements and laboratory works. Thus, the information obtained is used to assess long-term durability of the armourstones.
The long-term performance of the Degirmencayi and Tirtar upper level limestones are observed to be good whereas it is rather
poor for the Tirtar middle and lower level limestones. Comparison between the predicted and observed durabilities of the armourstones
indicated that CIRIA/CUR, RDId, RERS, and wet to dry strength ratio give better results based on their field performances. However, the prediction of the
durability of the limestones is poor in case RDIs, average pore diameter, and saturation coefficient are used. 相似文献
3.
Muhsin Eren 《Chemie der Erde / Geochemistry》2011,(1):31-37
In the Mersin area, Quaternary calcretes are widespread, and occurred in a variety of forms, as namely powdery, nodular, tubular, fracture-infill, laminar crust, hard laminated crust (hardpan), pisolithic crust. They are predominantly calcite, and small amount of palygorskite associated with them as a minor component. Calcite δ18O and δ13C values of the calcretes vary from −4.31 to −6.82 and from −6.03 to −9.65‰ PDB, respectively. These values are consistent with values of pedogenic calcretes reported in literature from worldwide sites. The oxygen isotope values indicate formation under the influence of meteoric water at estimated temperatures from 25 to 32 °C. The carbon isotope values are typical for pedogenic calcretes, reflecting development under the C3-dominated vegetation cover and semiarid or seasonally arid climatic conditions. 相似文献
4.
Spatial/temporal variabilities of rainwater constituents are examined based on soluble/insoluble trace elements, pH and electrical conductivity measurements in rainfall sampled during December 2003–May 2005 at two urban and two suburban sites in Mersin, an industrialized city of 850,000 inhabitants on the southern coast of Turkey. In the analyses, backward air mass trajectories for rainy days were used in addition to factor analyses, enrichment factors, phase distributions and correlations between trace elements. The pH varied from 4.8 to 8.5 with an average value of 6.2, reflecting a mainly alkaline regime. Mean concentrations of trace elements collected from urban and suburban sites are spatially variable. Based on the overall data, total concentrations of trace elements were ordered as Ca > Na > Fe > Al > Mg > K > Zn > Mn > Sr > Pb > Ni > Cr > Ba > Cu > Co > Cd. Mainly terrigeneous (Ca, Fe, Al) and, to a lesser extent, sea salt particles (Na, Mg) were shown to be the major source of trace elements. Excluding major cations, the solubilities of trace elements were found to be ordered as Sr > Zn > Ba > Mn > Cu > Ni > Cr > Fe > Al, confirming the lower solubility of crustal elements. Cd, Co and Pb were excluded from the above evaluation because of the low numbers of soluble samples allowing quantitative measurements. The solubilities of Al, Fe, Mn and particularly of Ni were found to be considerably lower than those reported for various sites around the world, most likely due to the effect of pH. During the entire sampling period, a total of 28 dust transport episodes associated with 31 red rain events were identified. Extremely high mean concentration ratios of Al (8.2), Fe (14.4) and Mn (13.1) were observed in red rain, compared to normal rain. The degree of this enhancement displayed a decrease from crustal to anthropogenic origin elements and the lowest enhancements were found for anthropogenic origin elements of Zn and Cd (both having a ratio of 1.1). Aerosol dust was found to be the main source of almost all analyzed elements in Mersin precipitation, regardless that they are crustal or anthropic derived elements. The magnitude of crustal source contribution to trace element budget of precipitation was at its highest levels for crustal originated elements, most probably due to much higher scavenging ratios of crustal elements compared to anthropogenic ones. 相似文献
5.
High-resolution shallow seismic-reflection profiles obtained from the western Mersin Bay have revealed the existence of the two distinct depositional sequences (C and B) lying on a narrow and relatively steeply-sloping continental shelf which mainly receives its sediments from the ephemeral rivers. The upper Holocene sedimentary sequence (C) is characterized by stratified (simple to complex) to chaotic reflection configurations produced by the development of a prograding wedge of terrigenous sediment. Particular occurrences of slope- and front-fill facies and the lack of a sharp boundary, which has, however, been observed on the western shelf of this bay, between the Early Holocene and latest Pleistocene deposits are related to possible movement of underlying deposits due to local gravity mass movements or synsedimentary tectonics due to adjustment of the underlying evaporites in adjacent basin. The maximum thickness of the topmost sequence C is associated with the Tarsus–Seyhan delta, which lies to the northeast of the area and is prograding along the shelf. Other variations in thickness (5–40 m) of this topmost sequence are related to the variable sediment discharge along the coast, and the distance from the coast. It is at a maximum (40 m) in the nearshore area just west of the Lamas river mouth and at a minimum (5–15 m) in the offshore area.
The lower depositional pre-Holocene sequence (B) is characterized by continuous to wavy reflection configurations and how some cyclicity, suggesting coarse, heterogeneous sediments deposited under high energy conditions (fan-deltas) of Plio-Pleistocene age.
The combined interpretation of seismic reflection profiles with the available bore-hole data reveals the existence of a widespread Miocene acoustic basement (A) off the Susanoğlu–Tırtar coasts and Karapınar–Gilindirez rivers mouths. Unusual features in some profiles suggest the escape of coastal freshwater into the accumulating sediment. 相似文献
6.
Mustafa Gurhan Yalcin 《Environmental Geology》2009,58(1):119-129
Geochemical works were conducted on anthropogenically effective lithologic unit exposing along the Susanoglu coast in Mersin,
Turkey. For this purpose, beach sand sediments from 33 stations were collected and heavy metal and oxide concentrations were
analyzed. To determine the source of heavy metals (natural and anthropogenic), simple and multivariate statistical analyses
were applied. According to factor analysis, three factors were determined. The first factor consists of SiO2, Al2O3, Na2O, K2O, TiO2, Cr, Ni, Cu and Mo and total variance is explained with 27.502% and expressed as “natural process factor”. These elements (Cr, Ni, Cu, Mo) are closely associated with geogenic materials and came from same sources of ultrabasic
rocks (ophiolite). The second factor consists of CaO, MgO, TiO2, MnO, Ni, Pb, Zn and W and total variance is explained with 21.505% and expressed as “anthropogenic factor”. These elements (Pb, Zn, Cd, V, W) are anthropogenic and are mainly due to the effluent or industrial input/activities and
came from different sources of pollution in the study area. The third factor consists of Pb, Cd and Sb and total variance
is explained with 9.748% and expressed as “intermediate factor”. The factor analysis and the cluster analysis are in support of each other. Cr, Ni, Co, Cd, Hg and Mo concentrations are
greater than Turkish acceptable values and they show toxic effect. Al, Cu, Pb, Cd and Mo concentrations in beach sand deposits
in the Susanoglu coast are found as 1.44, 1.26, 1.21, 1.02 and 1.04 mg/kg and higher than those in Kızkalesi beach sands.
However, all other heavy metal contents are determined in low concentrations. 相似文献
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