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1.
Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria 总被引：1，自引：0，他引：1
Laura J. Liermann Robin L. Guynn Ariel Anbar Susan L. Brantley 《Chemical Geology》2005,220(3-4):285-302
Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N2-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered. 相似文献
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Hematite is a thermodynamically stable iron oxide under the aerobic conditions present in most natural surface soils and sediments. Most studies to date have focused on the capacity of hematite to adsorb trace metals and metalloids, but structural incorporation of trace metals within hematite is less recognized. This study assessed the incorporation of molybdenum within the structure of hematite during the phase transformation of 2-line ferrihydrite under alkaline conditions (pH ∼10). Extended X-ray absorption fine structure analyses show molybdenum incorporated into hematite, with two Mo-O shells having a coordination number (CN) of 3 and average bond distances of 1.78 ± 0.01 and 2.08 ± 0.02 Å, respectively, as well as two Mo-Fe shells with a CN of 3 and average bond distances of 3.10 ± 0.02 Å and 3.44 ± 0.02 Å, respectively. This observation suggests the tetrahedrally-coordinated Mo in the molybdate that adsorbs onto the 2-line ferrihydrite changes to an octahedrally-coordinated Mo within the hematite with Mo possibly substituting for Fe in the hematite structure. Our findings suggest that molybdenum partitioning (low concentrations) to iron oxides in the environment can occur due to structural incorporation as well as adsorption. 相似文献
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天山-兴蒙钼矿带是中亚成矿域的重要组成部分,该成矿带主要呈近东西向分布;本文通过对天山-兴蒙钼矿带4个典型矿床Re-Os同位素精确定年,结合前人区域动力学背景的研究,揭示天山-兴蒙造山带钼矿床的成矿作用主要与岩浆侵入形成的花岗岩热液作用有关,并识别出兴蒙造山带3期岩浆活动、钼成矿作用和构造热事件;Re-Os定年结果揭示出晚古生代铜-钼矿床与俯冲-增生作用有关,三叠纪钼的成矿形成于西伯利亚板块与塔里木-华北克拉通碰撞背景下,而侏罗纪-早白垩世的钼成矿作用与古太平洋板块西向俯冲作用有关。 相似文献
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K. Christanis A. Georgakopoulos J. L. Fernndez-Turiel A. Bouzinos 《International Journal of Coal Geology》1998,36(3-4)
Six peat samples obtained from the Holocene and the Weichselian of the Philippi peat deposit, eastern Macedonia, Greece, were analyzed for 48 trace elements by Inductively Coupled Plasma–Mass Spectrometry (ICP–MS). The ash contents of these samples were also determined. Most of the trace elements are associated with the minerals in the peat, while Ge, Mo, Pb, Se, Ta, Tl, U, and W display a greater affinity with the organic matter. Compared with crustal averages (Clarke concentrations), the Philippi peat is enriched in some elements (Ag, As, Au, Cd, Mo, Se, Te, U, and W) because of the respective mineralizations in the area. The Philippi peat is also enriched in Cr, Cu, Mo, Pb, Sc, Sn, T, V, Y, and Zn in comparison with typical fen peats, as well as in As, Cr, Mo, Se, and U in comparison with typical coals. Climatic and hydrogeological conditions strongly influenced the peat-forming environment resulting in a differentiation between Holocene and Weichselian peat. Generally, the Holocene peat contains lower concentrations of trace elements in the northern and southern part of the fen, than the Weichselian one. The opposite trend is observed in the fen area close to the western basin margins. 相似文献
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A new method for the quantification of different redox-species of molybdenum (V and VI) in seawater 总被引：1，自引：0，他引：1
A new method for the direct determination of reduced and oxidized Mo species (Mo (V) and Mo (VI)) in seawater was developed and used for the first time. The method includes the complexation of Mo (V) with tartrate, solid phase extraction of the Mo (V)–tartrate complex by a XAD 7HP resin, followed by elution with acidic acetone. In this study, the eluted Mo (V) was quantified by graphite furnace atomic absorption spectrometry. The detection limit of this protocol was on the order of 0.2 nM. The analytical precision was 10% of ~ 10 nM. This method was successfully applied to the determination of Mo (V) and Mo (VI) in surface and bottom waters at the head of Peconic River Estuary. Total Mo (Mo (V) + Mo (VI)) ranged from 100–120 nM in most bottom saline waters, and 2.5–15 nM for surface fresher waters. Concentrations of Mo (V) in these environments ranged from 0 nM to ~ 15 nM, accounting for 0%–15% of the total dissolved Mo pool. The time series experiments showed that the Mo speciation changed within 1 h after the water collection, and therefore it is strongly suggested that speciation analysis be carried out within the first 15 min. However, since these are the first Mo speciation data in concentration ranges typical of normal marine and coastal waters, additional research may be required to optimize the methodology and further explore Mo cycling mechanisms. 相似文献
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杏山北钼矿床为胶东半岛一典型矽卡岩型钼矿床,位于著名牟平乳山金成矿带和蓬莱栖霞金成矿带之间,区域上位于胶东辽东钼成矿带,具有较好的成矿地质条件。通过对比胶东地区其他典型钼矿床地质特征,认为胶东半岛钼矿床存在两期成矿时代;矽卡岩型矿床主要受近EW向断裂构造控制,斑岩型矿床主要受近EW向与NE向断裂复合构造控制。通过物探异常预测,认为杏山北钼矿床深部是寻找矽卡岩型和斑岩型铜钼矿床的有利部位。 相似文献
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邢家山大型钼钨矿床位于胶东栖霞-蓬莱-福山金及多金属成矿区东部,矿床主要赋存于晚侏罗世二长花岗岩外接触带的变质地层中,倒转向斜分布区是钼钨成矿有利部位。幸福山岩体为成矿母岩,粉子山群的碳酸盐岩既易交代成矿亦形成了屏蔽层,NW向张扭性断裂导矿,层间裂隙、节理和矿物间隙沉淀成矿。钼钨矿化作用与矽卡岩化、钾化、硅化密切相关,矿床工业类型属矽卡岩型-斑岩型,成因类型属于岩浆期后热液矿床,矿石建造属钨钼建造,该成果对在胶东地区寻找同类型钼矿床具有重要意义。 相似文献
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东秦岭东段新发现的沙坡岭细脉浸染型钼矿地质特征、Re-Os同位素年龄及其地质意义 总被引：7，自引：0，他引：7
豫西洛宁沙坡岭钼矿床位于华北克拉通南缘东秦岭钼矿带东段,是新近发现的赋存于太古宙太华群变质岩中的细脉浸染型钼矿床。本文对其地质特征进行了研究,并初步测定了1个辉钼矿样品的Re－Os同位素年龄,获得模式年龄为126.8±1.7Ma,表明沙坡岭钼矿形成于燕山期,接近金堆城、雷门沟钼矿的形成时代,Re同位素含量显示其地幔来源的特征。沙坡岭钼矿形成机制错综复杂,有待进一步研究,特别是深部钻孔工程验证工作,对于验证深部是否隐伏着与成矿相关的斑岩体、储量更大的斑岩型钼矿有着重要作用,找矿潜力巨大。 相似文献
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