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1.
The source and hydrochemical makeup of a stream reflects the connectivity between rainfall, groundwater, the stream, and is reflected to water quantity and quality of the catchment. However, in a semi-arid, thick, loess covered catchment, temporal variation of stream source and event associated behaviours are lesser known. Thus, the isotopic and chemical hydrographs in a widely distributed, deep loess, semi-arid catchment of the northern Chinese Loess Plateau were characterized to determine the source and hydrochemical behaviours of the stream during intra-rainfall events. Rainfall and streamflow were sampled during six hydrologic events coupled with measurements of stream baseflow and groundwater. The deuterium isotope (2H), major ions (Cl, SO42−, NO3, Ca2+, K+, Mg2+, and Na+) were evaluated in water samples obtained during rainfall events. Temporal variation of 2H and Cl measured in the groundwater and stream baseflow prior to rainfall was similar; however, the isotope compositions of the streamflow fluctuated significantly and responded quickly to rainfall events, likely due to an infiltration excess, overland dominated surface runoff during torrential rainfall events. Time source separation using 2H demonstrated greater than 72% on average, the stream composition was event water during torrential rainfall events, with the proportion increasing with rainfall intensity. Solutes concentrations in the stream had loglinear relationships with stream discharge, with an outling anomaly with an example of an intra-rainfall event on Oct. 24, 2015. Stream Cl behaved nonconservative during rainfall events, temporal variation of Cl indicated a flush and washout at the onset of small rainfall events, a dilution but still high concentration pattern in high discharge and old water dominated in regression flow period. This study indicates rainfall intensity affects runoff responses in a semi-arid catchment, and the stored water in the thick, loess covered areas was less connected with stream runoff. Solute transport may threaten water quality in the area, requiring further analysis of the performance of the eco-restoration project.  相似文献   
2.
In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ18O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ18O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ18O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ18O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ18O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.  相似文献   
3.
俞志尧 《天文学进展》2002,20(3):256-264
自从在活动星系核NGC4945的视线方向上发现第一个河外H2O超脉泽源以来,迄今为止已发现了19个河外H2O超脉泽源,对与活动星系核成协和河外H2O超脉泽源及分子谱线的观测和研究是探测和研究活动星系核核区中央源,拱核气体和尘埃环性质的非常有效的工具,主要评述对河外H2O超脉泽源及与其相关分子谱线的搜索,观测和理论研究现状。  相似文献   
4.
U–Pb age, trace element and Hf isotope compositions of zircon were analysed for a metasedimentary rock and two amphibolites from the Kongling terrane in the northern part of the Yangtze Craton. The zircon shows distinct morphological and chemical characteristics. Most zircon in an amphibolite shows oscillatory zoning, high Th/U and 176Lu/177Hf ratios, high formation temperature, high trace element contents, clear negative Eu anomaly, as well as HREE-enriched patterns, suggesting that it is igneous. The zircon yields a weighted mean 207Pb/206Pb age of 2857 ± 8 Ma, representing the age of the magmatic protolith. The zircon in the other two samples is metamorphic. It has low Th/U ratios, low trace element concentrations, variable HREE contents (33.8 ≥ LuN≥2213; 14.7 ≤ LuN/SmN ≤ 354) and 176Lu/177Hf ratios (0.000030–0.001168). The data indicate that the zircon formed in the presence of garnet and under upper amphibolite facies conditions. The metamorphic zircon yields a weighted mean 207Pb/206Pb age of 2010 ± 13 Ma. These results combined with previously obtained Palaeoproterozoic metamorphic ages suggest a c. 2.0 Ga Palaeoproterozoic collisional event in the Yangtze Craton, which may result from the assembly of the supercontinent Columbia. The zircon in two samples yields weighted mean two-stage Hf model ( T DM2) ages of 3217 ± 110 and 2943 ± 50 Ma, respectively, indicating that their protoliths were mainly derived from Archean crust.  相似文献   
5.
In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K2O, Ca/(Ca + Na)rock and FeOtot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H2O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB.  相似文献   
6.
Measurements of 18O concentrations in precipitation, soil solution, spring and runoff are used to determine water transit time in the small granitic Strengbach catchment (0·8 km2; 883–1146 m above sea level) located in the Vosges Mountains of northeastern France. Water transit times were calculated by applying the exponential, exponential piston and dispersion models of the FlowPC program to isotopic input (rainfall) and output (spring and stream water) data sets during the period 1989–95. The input function of the model was modified compared with the former version of the model and estimated by a deterministic approach based on a simplified hydrological balance. The fit between observed and calculated output data showed marked improvements compared with results obtained using the initial version of the model. An exponential piston version of the model applied to spring water indicates a 38·5 month mean transit time, which suggests that the volume in the aquifer, expressed in water depth, is 2·4 m. A considerable thickness (>45 m) of fractured bedrock may be involved for such a volume of water to be stored in the aquifer. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
7.
Based on the δ13C and δ18O fluctuation of lacustrine carbonate, CaCO3 content and sporo-pollen data, a palaeoclimatic history of Bosten Lake during the Holocene has been outlined, several stages of climatic changes are divided, and the following result es are obtained: (1) Palaeoclimatic changes revealed by carbonate isotope around Bosten Lake are basically identical with that revealed by other geological records in Xinjiang. Environmental changes presented apparent Westlies Style model: during cold period, relative humidity increased, δ18O, δ13C and CaCO3 appeared low; but in warm periods, the dry regime aggravated. (2) The temperature reflected by δ18O exist evident features being increase in the late period during the Holocene. Together with the δ13C, pollen and CaCO3 analyses, several cold and warm phases which are of broad regional significance can be identified. The warm peaks occurred at about 11.0 ka B.P., 9.4 ka B.P., 7.5 ka B.P., 5.0 ka B.P., 3.0 ka B.P. and 2.0 ka B.P.; the cold peaks at 11.5 ka B.P., 10.5 ka B.P., 8.8 ka B.P., 5.5 ka B.P., 3.3 ka B.P., 2.2 ka B.P. and 1.5 ka B.P.. (3) Several climatic events with the nature of “abrupt climatic changes” are revealed in the periods of 11.0 ka B.P. −10.5 ka B.P., 9.4 ka B.P. −8.8 ka B.P., 5.5 ka B.P. −5.0 ka B.P. and 2.0 ka B.P. −1.5 ka B.P.. (4) The results show that carbonate isotopic record of lacustrine sediment in arid area is very sensitive to climatic changes, and may be play a very important role in understanding the features and mechanism of palaeoclimatic changes.  相似文献   
8.
Numerical simulations of the evolving activity of comet Hale-Bopp are presented, assuming a porous, spherical nucleus, 20 km in radius, made of dust and gas-laden amorphous ice. The main effects included are: crystallization of amorphous ice and release of occluded gas, condensation, sublimation and flow of gases through the pores, changing pore sizes, and flow of dust grains. The model parameters, such as initial pore size and porosity, emissivity, dust grain size, are varied in order to match the observed activity. In all cases, a sharp rise in the activity of the nucleus occurs at a large heliocentric distance pre-perihelion, marked by a few orders of magnitude increase in the CO and the CO2 fluxes and in the rate of dust emission. This is due to the onset of crystallization, advancing down to a few meters below the surface, accompanied by release of the trapped gases. A period of sustained, but variable, activity ensues. The emission of water molecules is found to surpass that of CO at a heliocentric distance of 3 AU. Thereafter the activity is largely determined by the behaviour of the dust. If a dust mantle is allowed to build up, the water production rate does not increase dramatically towards perihelion; if most of the dust is ejected, the surface activity increases rapidly, producing a very bright comet. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
9.
The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
10.
通过对中国东部金成矿区域地质特征的分析,根据氢氧同位素及流体包裹体数据特征,表明中国东部金矿床成矿流体主要来自大气降水,其次为变质作用过程释放的水和岩浆分异水;成矿金属组分主要来自太古宙变质岩系。  相似文献   
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