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1.
The 1.27 Ga old Ivigtut (Ivittuut) intrusion in South Greenland is world-famous for its hydrothermal cryolite deposit [Na3AlF6] situated within a strongly metasomatised A-type granite stock. This detailed fluid inclusion study characterises the fluid present during the formation of the cryolite deposit and thermodynamic modelling allows to constrain its formation conditions.Microthermometry revealed three different types of inclusions: (1) pure CO2, (2) aqueous-carbonic and (3) saline-aqueous inclusions. Melting temperatures range between − 23 and − 15 °C for type 2 and from − 15 to − 10 °C for type 3 inclusions. Most inclusions homogenise between 110 and 150 °C into the liquid.Stable isotope compositions of CO2 and H2O were measured from crushed inclusions in quartz, cryolite, fluorite and siderite. The δ13C values of about − 5‰ PDB are typical of mantle-derived magmas. The differences between δ18O of CO2 (+ 21 to + 42‰ VSMOW) and δ18O of H2O (− 1 to − 21.7‰ VSMOW) suggest low-temperature isotope exchange. δD (H2O) ranges from − 19 to − 144‰ VSMOW. The isotopic composition of inclusion water closely follows the meteoric water line and is comparable to Canadian Shield brines. Ion chromatography revealed the fluid's predominance in Na, Cl and F. Cl/Br ratios range between 56 and 110 and may imply intensive fluid–rock interaction with the host granite.Isochores deduced from microthermometry in conjunction with estimates for the solidification of the Ivigtut granite suggest a formation pressure of approximately 1–1.5 kbar for the fluid inclusions. Formation temperatures of different types of fluid inclusions vary between 100 and 400 °C. Thermodynamic modelling of phase assemblages and the extraordinary high concentration in F (and Na) may indicate that the cryolite body and its associated fluid inclusions could have formed during the continuous transition from a volatile-rich melt to a solute-rich fluid. 相似文献
2.
The igneous rocks of the Katzenbuckel, Southwest Germany, represent a unique and unusual alkaline to peralkaline association within the European Volcanic Province. The magmatic activity can be subdivided into two main phases. Phase I comprises the main rock bodies of phonolite and nepheline syenite, which were later intruded by different peralkaline dyke rocks (tinguaites and alkali feldspar syenite dykes) of phase II. The dyke assemblage was accompanied by magnetite and apatite veins and was followed by a late-stage pneumatolytic activity causing autometasomatic alterations.
As is typical for alkaline to peralkaline igneous rocks, early mafic minerals of phase I rocks comprise olivine, augite and Fe–Ti oxides, which are substituted in the course of fractionation by Na-amphibole and Na-pyroxene. For the early magmatic stage, calculated temperatures range between 880 and 780 °C with low silica activities (0.4 to 0.6) but high relative oxygen fugacities between 0.5 and 1.9 log units above the FMQ buffer. Even higher oxygen fugacities (above the HM buffer) are indicated for the autometasomatic alteration, which occurred at temperatures between 585 and 780 °C and resulted in the formation of pseudobrookite and hematite.
The unusually high oxygen fugacities (even during the early magmatic stage) are recorded by the major element compositions of the mafic minerals (forsterite content in olivine between 68 and 78 mol%, up to 6.2 wt.% ZrO2 and 8.5 wt.% TiO2 in clinopyroxene), the unusual mineral assemblages (pseudobrookite, freudenbergite) and by the enrichment of Fe3+ in the felsic minerals (up to 2.8 wt.% Fe2O3 in alkali feldspar and up to 2.6 wt.% Fe2O3 in nepheline). These observations point to a metasomatically enriched and highly oxidized lithospheric mantle as a major source for the Katzenbuckel melts. 相似文献
3.
Application of the QUILF thermobarometer to the peralkaline trachytes and pantellerites of the Eburru volcanic complex, East African Rift, Kenya 总被引：1，自引：0，他引：1
Minghua Ren Peter A. Omenda Elizabeth Y. Anthony John C. White Ray Macdonald D.K. Bailey 《Lithos》2006,91(1-4):109-124
The Quaternary Eburru volcanic complex in the south-central Kenya Rift consists of pantelleritic trachytes and pantellerites. The phenocryst assemblage in the trachytes is sanidine + fayalite + ferrohedenbergite + aenigmatite ± quartz ± ilmenite ± magnetite ± pyrrhotite ± pyrite. In the pantellerites, the assemblage is sanidine + quartz + ferrohedenbergite + fayalite + aenigmatite + ferrorichterite + pyrrhotite ± apatite, although fayalite, ferrohedenbergite and ilmenite are absent from more evolved rocks (e.g. with SiO2 > 71%). QUILF temperature calculations for the trachytes range from 709 to 793 °C and for the pantellerites 668–708 °C, the latter temperatures being among the lowest recorded for peralkaline silicic magmas. The QUILF thermobarometer demonstrates that the Eburru magmas crystallized at relatively low oxidation states (ΔFMQ + 0.5 to − 1.6) for both trachytes and pantellerites. The trachytes and pantellerites evolved along separate liquid lines of descent, the trachytes possibly deriving from a more mafic parent by fractional crystallization and the pantellerites from extreme fractionation of comenditic magmas. 相似文献
4.
John Charles White S. Christian Benker Minghua Ren Kevin M. Urbanczyk Donald W. Corrick 《Lithos》2006,91(1-4):74-94
The Pine Canyon caldera is a small (6–7 km diameter) ash-flow caldera that erupted peralkaline quartz trachyte, rhyolite, and high-silica rhyolite lavas and ash-flow tuffs about 33–32 Ma. The Pine Canyon caldera is located in Big Bend National Park, Texas, USA, in the southern part of the Trans-Pecos Magmatic Province (TPMP). The eruptive products of the Pine Canyon caldera are assigned to the South Rim Formation, which represents the silicic end member of a bimodal suite (with a “Daly Gap” between 57 and 62 wt.% SiO2); the mafic end member consists primarily of alkali basalt to mugearite lavas of the 34–30 Ma Bee Mountain Basalt. Approximately 60–70% crystallization of plagioclase, clinopyroxene, olivine, magnetite, and apatite from alkali basalt coupled with assimilation of shale wall rock (Ma/Mc = 0.3–0.4) produced the quartz trachyte magma. Variation within the quartz trachyte–rhyolite suite was the result of 70% fractional crystallization of an assemblage dominated by alkali feldspar with subordinate clinopyroxene, fayalite, ilmenite, and apatite. High-silica rhyolite is not cogenetic with the quartz trachyte–rhyolite suite, and can be best explained as the result of 5% partial melting of a mafic granulite in the deep crust under the fluxing influence of fluorine. Variation within the high-silica rhyolite is most likely due to fractional crystallization of alkali feldspar, quartz, magnetite, biotite, and monazite. Lavas and tuffs of the South Rim Formation form A-type rhyolite suites, and are broadly similar to rock series described in anorogenic settings both in terms of petrology and petrogenesis. The Pine Canyon caldera is interpreted to have developed in a post-orogenic tectonic setting, or an early stage of continental rifting, and represents the earliest evidence for continental extension in the TPMP. 相似文献
5.
Within the 1.16 Ga old Ilímaussaq intrusion, up to 700 m large autoliths occur in one stratigraphic unit of the layered floor series of agpaitic nepheline syenites (kakortokites). These autoliths consist of two different rock types: augite syenite and naujaite (agpaitic nepheline syenite). All three rock types show a number of alteration features related to the entrapment of the autoliths in the kakortokite magma caused by the interaction with a fluid phase.
In the kakortokites, the oxidation of primary arfvedsonite to aegirine and fluorite is restricted to the close proximity to the autoliths. Close to the surrounding kakortokite, the primary mafic phases of the augite syenites (augite, fayalite, Fe–Ti oxides) are completely replaced by arfvedsonite, aenigmatite, biotite, aegirine and fluorite. The decomposition of primary hastingsite to spectacular aegirine–augite–nepheline–aenigmatite symplectites can be observed up to several meters inside the autoliths. Additionally, fluorite formed at grain boundaries of primary nepheline. In the naujaite autoliths, primary arfvedsonite is replaced by aegirine–biotite intergrowths and abundant aenigmatite is occasionally replaced by Ti-rich aegirine and Fe–Ti oxides.
The mineral reactions in the autoliths are used to decipher details of the late to post-magmatic processes in a peralkaline syenitic intrusion. Mineral equilibria record an evolution governed by falling temperature (620 to ca. 500 °C) and increasing relative oxygen fugacity from FMQ + 1 to above FMQ + 4. Quantification of the observed mineral reactions reveals the infiltration of the autoliths with an oxidizing fluid phase rich in Na and F and minor addition of K. Volatiles (H and F) and in some cases also Fe, Ti and Ca (± Mg) released from primary autolith phases were mainly just relocated within the autoliths. 相似文献
6.
The East Kunlun Orogenic Belt(EKOB),which is in the northern part of the Greater Tibetan Plateau,contains voluminous Late Triassic intermediate-felsic volcanic rocks.In the east end of the EKOB,we identified highly differentiated peralkaline-like Xiangride rhyolites(～209 Ma)that differ from the wide-spread andesitic-rhyolitic Elashan volcanics(～232-225 Ma)in terms of their field occurrences and min-eral assemblages.The older,more common calc-alkaline felsic Elashan volcanics may have originated from partial melting of the underthrust Paleo-Tethys oceanic crust under amphibolite facies conditions associated with continental collision.The felsic Elashan volcanics and syn-collisional granitoids of the EKOB are different products of the same magmatic event related to continental collision.The Xiangride rhyolites are characterized by elevated abundances of high field strength elements,especially the very high Nb and Ta contents,the very low Ba,Sr,Eu,P,and Ti contents;and the variably high 87Sr/86Sr ratios(up to 0.96),exhibiting remarkable similarities to the characteristic peralkaline rhyolites.The primitive magmas parental to the Xiangride rhyolites were most likely alkali basaltic magmas that underwent pro-tracted fractional crystallization with continental crust contamination.The rock associations from the early granitoids and calc-alkaline volcanic rocks to the late alkaline basaltic dikes and peralkaline-like rhyolites in the Triassic provide important information about the tectonic evolution of the EKOB from syn-collisional to post-collisional.We infer that the transition from collisional compression to post-collisional extension occurred at about 220 Ma. 相似文献
7.
The Katherina ring complex (KRC) in the central part of south Sinai, Egypt, is a typical ring complex of late Neoproterozoic age (605–580 Ma). It was developed during the final tectono-magmatic stage of the north Arabian–Nubian Shield (ANS) during evolution of the Pan-African crust. The KRC includes Katherina volcanics, subvolcanic bodies, ring dykes and Katherina granitic pluton. The Katherina volcanics represent the earliest stage of the KRC, which was subsequently followed by emplacement of the subvolcanic bodies and ring dykes. The Katherina granitic pluton depicts as the latest evolution stage of the KRC that intruded all the early formed rock units in the concerned area. The Katherina volcanics are essentially composed of rhyolites, ignimbrite, volcanic breccia and tuffs. Mineralogically, the peralkaline rhyolites contain sodic amphiboles and aegirine. The rhyolite whole rock chemistry has acmite-normative character. The subvolcanic bodies of the KRC are represented by peralkaline microgranite and porphyritic quartz syenite. The ring dykes are semicircular in shape and consist mainly of quartz syenite, quartz trachyte and trachybasalt rock types. The Katherina subvolcanic rocks, volcanic rocks as well as the ring dykes are alkaline or/and peralkaline in nature. The alkaline granitic pluton forms the inner core of the KRC, including the high mountainous areas of G. Abbas Pasha, G. Bab, G. Katherina and G. Musa. These mountains are made up of alkaline syenogranite and alkali feldspar granite. The mantle signature recorded in the KRC indicates a juvenile ANS crust partial melting process for the generation of this system. The evolution of the KRC rocks is mainly dominated by crystal fractionation and crustal contamination. Mineral geothermometry points to the high temperature character of the KRC, up to 700–1100 °C. 相似文献
8.
At Sams Creek, a gold-bearing, peralkaline granite porphyry dyke, which has a 7 km strike length and is up to 60 m in thickness, intrudes camptonite lamprophyre dykes and lower greenschist facies metapelites and quartzites of the Late Ordovician Wangapeka formation. The lamprophyre dykes occur as thin (< 3 m) slivers along the contacts of the granite dyke. δ18Omagma values (+5 to +8‰, VSMOW) of the A-type granite suggest derivation from a primitive source, with an insignificant mature crustal contribution. Hydrothermal gold–sulphide mineralisation is confined to the granite and adjacent lamprophyre; metapelite country rocks have only weak hydrothermal alteration. Three stages of hydrothermal alteration have been identified in the granite: Stage I alteration (high fO2) consisting of magnetite–siderite±biotite; Stage II consisting of thin quartz–pyrite veinlets; and Stage III (low fO2) consisting of sulphides, quartz and siderite veins, and pervasive silicification. The lamprophyre is altered to an ankerite–chlorite–sericite assemblage. Stage III sulphide veins are composed of arsenopyrite + pyrite ± galena ± sphalerite ± gold ± chalcopyrite ± pyrrhotite ± rutile ± graphite. Three phases of deformation have affected the area, and the mineralised veins and the granite and lamprophyre dykes have been deformed by two phases of folding, the youngest of which is Early Cretaceous. Locally preserved early-formed fluid inclusions are either carbonic, showing two- or three-phases at room temperature (liquid CO2-CH4 + liquid H2O ± CO2 vapour) or two-phase liquid-rich aqueous inclusions, some of which contain clathrates. Salinities of the aqueous inclusions are in the range of 1.4 to 7.6 wt% NaCl equiv. Final homogenisation temperatures (Th) of the carbonic inclusions indicate minimum trapping temperatures of 320 to 355°C, which are not too different from vein formation temperatures of 340–380°C estimated from quartz–albite stable isotope thermometry. δ18O values of Stage II and III vein quartz range from +12 and +17‰ and have a bimodal distribution (+14.5 and +16‰) with Stage II vein quartz accounting for the lower values. Siderite in Stage III veins have δ18O (+12 to +16‰) and δ13C values (−5‰, relative to VPDB), unlike those from Wangapeka Formation metasediments (δ13Cbulk carbon values of −24 to −19‰) and underlying Arthur Marble marine carbonates (δ18O = +25‰ and δ13C = 0‰). Calculated δ18Owater (+8 to +11‰, at 340°C) and
(−5‰) values from vein quartz and siderite are consistent with a magmatic hydrothermal source, but a metamorphic hydrothermal origin cannot be excluded. δ34S values of sulphides range from +5 to +10‰ (relative to CDT) and also have a bimodal distribution (modes at +6 and +9‰, correlated with Stage II and Stage III mineralisation, respectively). The δ34S values of pyrite from the Arthur Marble marine carbonates (range from +3 to +13‰) and Wangapeka Formation (range from −4 to +9.5‰) indicate that they are potential sources of sulphur for sulphides in the Sams Creek veins. Another possible source of the sulphur is the lithospheric mantle which has positive values up to +14‰. Ages of the granite, lamprophyre, alteration/mineralisation, and deformation in the region are not well constrained, which makes it difficult to identify sources of mineralisation with respect to timing. Our mineralogical and stable isotope data does not exclude a metamorphic source, but we consider that the source of the mineralisation can best be explained by a magmatic hydrothermal source. Assuming that the hydrothermal fluids were sourced from crystallisation of the Sams Creek granite or an underlying magma chamber, then the Sams Creek gold deposit appears to be a hybrid between those described as reduced granite Au–Bi deposits and alkaline intrusive-hosted Au–Mo–Cu deposits. 相似文献
9.
The diffusion of water in a peralkaline and a peraluminous rhyolitic melt was investigated at temperatures of 714–1,493 K
and pressures of 100 and 500 MPa. At temperatures below 923 K dehydration experiments were performed on glasses containing
about 2 wt% H2O
t
in cold seal pressure vessels. At high temperatures diffusion couples of water-poor (<0.5 wt% H2O
t
) and water-rich (~2 wt% H2O
t
) melts were run in an internally heated gas pressure vessel. Argon was the pressure medium in both cases. Concentration profiles
of hydrous species (OH groups and H2O molecules) were measured along the diffusion direction using near-infrared (NIR) microspectroscopy. The bulk water diffusivity
() was derived from profiles of total water () using a modified Boltzmann-Matano method as well as using fittings assuming a functional relationship between and Both methods consistently indicate that is proportional to in this range of water contents for both bulk compositions, in agreement with previous work on metaluminous rhyolite. The
water diffusivity in the peraluminous melts agrees very well with data for metaluminous rhyolites implying that an excess
of Al2O3 with respect to alkalis does not affect water diffusion. On the other hand, water diffusion is faster by roughly a factor
of two in the peralkaline melt compared to the metaluminous melt. The following expression for the water diffusivity in the
peralkaline rhyolite as a function of temperature and pressure was obtained by least-squares fitting:
where is the water diffusivity at 1 wt% H2O
t
in m2/s, T is the temperature in K and P is the pressure in MPa. The above equation reproduces the experimental data (14 runs in total) with a standard fit error
of 0.15 log units. It can be employed to model degassing of peralkaline melts at water contents up to 2 wt%. 相似文献
10.
In this contribution we report the results of an experimental study that investigated equilibrium and fractional crystallization of hydrous, transitional alkaline basalt at low oxygen fugacity, under lower to middle crustal conditions to constrain the generation of subaluminous and peralkaline differentiation products that typically occur in rift systems. The experiments reveal that liquids produced by equilibrium crystallization in the range 0.7–1 GPa cannot cross the subaluminous/peralkaline compositional divide. In contrast, fractional crystallization experiments under isobaric and polybaric conditions approach closer the naturally observed trend from subaluminous to evolved peralkaline products suggesting that polybaric differentiation starting at elevated pressures can indeed lead to the transition from subaluminous to peralkaline derivative liquids. The presence of water in the parental magmas of silicic derivative products is of prime importance for the fractionation equilibria as well as for the mobility of such magmas toward shallow crustal levels.
We suggest that peralkaline magmas in rift environments are indicative for differentiation under relatively low oxygen fugacity conditions in an extensional environment characterized by a high degree of crustal fracturing that allows rapid upward migration of mafic parental magmas and formation of shallow magma reservoirs. Crystallization–differentiation of parental, hydrous transitional alkaline basalt in such reservoirs is controlled by low pressure phase equilibria that typically evolve through early saturation of anorthite-rich plagioclase and suppressed amphibole crystallization resulting in ‘low-alumina’, peralkaline derivative liquids. 相似文献