None of the existing models for calc-alkaline “Late Granite” (Siluro–Devonian) genesis in the metamorphic Caledonian orogenic belt of Ireland and Scotland fully explains their spatial, age or chemical character. A consistent model must involve the closure of Iapetus Ocean, where slab breakoff is a natural consequence of attempted subduction of continental crust. Expected outcome is a long linear belt of high-K, calc-alkaline magmas, some with characteristic trace element signatures, specifically high Ba, Sr and Zr. Other features include the critical magmatic association of coeval appinite and granite, rapid uplift, erosion and the low-grade regional metamorphism in the Southern Uplands. The linear heat pulse on breakoff is spatially, intensity and time limited producing small volume melts emplaced as separated plutons, over a short time span. Magmatism in the Caledonian metamorphic belt is accurately accounted for by slab breakoff on collision of Baltica with the Scoto–Greenland margin during the Scandian orogeny, following Iapetus Ocean closure. The two chemically, isotopically and areally distinctive suites in the metamorphic belt in Scotland, viz. the Argyll and Cairngorm Suites, can be modelled by reference to the Donegal granites where sequential partial melting of new, lamprophyric underplated crust, then shallower old crust, as heat conduction moved up through the crust on slab breakoff, produced magmas characteristic of the two suites. 相似文献
The Kundal area of Malani Igneous Suite consists of volcano-plutonic rocks. Basalt flows and gabbro intrusives are associated
with rhyolite. Both the basic rocks consist of similar mineralogy of plagioclase, clinopyroxene as essential and Fe-Ti oxides
as accessories. Basalt displays sub-ophitic and glomeroporphyritic textures whereas gabbro exhibits sub-ophitic, porphyritic
and intergrannular textures. They show comparable chemistry and are enriched in Fe, Ti and incompatible elements as compared
to MORB/CFB. Samples are enriched in LREE and slightly depleted HREE patterns with least significant positive Eu anomalies.
Petrographical study and petrogenetic modeling of [Mg]-[Fe], trace and REE suggest cogenetic origin of these basic rocks and
they probably derived from Fe-enriched source with higher Fe/Mg ratio than primitive mantle source. Thus, it is concluded
that the basic volcano-plutonic rocks of Kundal area are the result of a low to moderate degree (< 30%) partial melting of
source similar to picrite/komatiitic composition. Within plate, anorogenic setting for the basic rocks of Kundal area is suggested,
which is in conformity with the similar setting for Malani Igneous Suite. 相似文献
The Uintjiesberg kimberlite diatreme occurs within the Proterozoic Namaqua–Natal Belt, South Africa, approximately 60 km to the southwest of the Kaapvaal craton boundary. It is a group I, calcite kimberlite that has an emplacement age of 100 Ma. Major and trace element data, in combination with petrography, are used to evaluate its petrogenesis and the nature of its source region. Macrocryst phases are predominantly olivine with lesser phlogopite, with very rare garnet and Cr-rich clinopyroxene. Geochemical variation amongst the macrocrystic samples (Mg# 0.85–0.87, SiO2=27.0–29.3%, MgO=26.1–30.5%, CaO=10.9–13.5%) is shown to result from 10% to 40% entrainment and partial assimilation of peridotite xenoliths, whereas that shown by the aphanitic samples (Mg# 0.80–0.83, SiO2=19.1–23.0%, MgO=17.9–23.9%, CaO=16.5–23.7%) is consistent with 7–25% crystal fractionation of olivine and minor phlogopite. Changing trajectories on chemical variation diagrams allow postulation of a primary magma composition with 25% SiO2, 26% MgO, 2.3% Al2O3, 5%H2O, 8.6% CO2 and Mg#=0.85.
Forward melting models, assuming 0.5% melting, indicate derivation of the primary Uintjiesberg kimberlite magma from a source enriched in light rare earth elements (LREE) by 10× chondrite and heavy REE (HREE) by 0.8–2× chondrite, the latter being dependent on the proportion of residual garnet. Significant negative Rb, K, Sr, Hf and Ti anomalies present in the inferred primary magma composition are superimposed on otherwise generally smooth primitive mantle-normalized trace element patterns, and are inferred to be a characteristic of the primary magma composition. The further requirement for a source with chondritic or lower HREE abundances, residual olivine with high Fo content (Fo94) suggests derivation from a mantle previously depleted in mafic melt but subsequently enriched in highly incompatible elements prior to kimberlite genesis. These requirements are interpreted in the context of melting of continental lithospheric mantle previously enriched by metasomatic fluids derived from a sublithospheric (plume?) source. 相似文献
The 1998 eruption of Volcán Cerro Azul in the Galápagos Islands produced two intra-caldera vents and a flank vent that erupted more than 1.0×108 m3 of lava. Lava compositions changed notably during the 5-week eruption, and contemporaneous eruptions in the caldera and on the flank produced different compositions. Lavas erupted from the flank vent range from 6.3 to 14.1% MgO, nearly the entire range of MgO contents previously reported from the volcano. On-site monitoring of eruptive activity is linked with petrogenetic processes such that geochemical variations are evaluated in a temporal context. Lavas from the 1998 eruption record two petrogenetic stages characterized by progressively more mafic lavas as the eruption proceeded. Crystal compositions, whole rock major and trace element compositions, and isotope ratios indicate that early lavas are the product of mixing between 1998 magma and remnant magma of the 1979 eruption. Intra-caldera lavas and later lavas have no 1979 signature, but were produced by the 1998 magma incorporating olivine and clinopyroxene xenocrysts. Thus, early magma petrogenesis is characterized by mixing with the 1979 magma, followed by the magma progressively entraining wehrlite cumulate mush.Editorial Responsibility: M.R. Carroll 相似文献