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1.
A large, euhedral crystal of fluorapatite (ca. 19.5 × 20.0 mm) from the Panasqueira tin-tungsten deposit (Portugal) was investigated in terms of the distribution of trace elements by using several microanalytical techniques. The studied material represents almost pure fluorapatite with minor amounts of other cations (mainly Sr, Mn, REE and Fe), OH and Cl. Particular interest was given to the distribution of rare earth elements with respect to the crystallographic orientation. A broad range of analytical techniques were used, including optical microscopy coupled with cathodoluminescence imaging, electron probe microanalysis (EPMA), laser ablation – inductively coupled plasma mass spectrometry (LA-ICPMS), Raman microspectroscopy, and simultaneous thermal analysis coupled with mass spectrometry. The investigated crystal consists of the main crystal with a distinct core and rim (Ap2core and Ap2rim, respectively), which grew on a previous, euhedral crystal (Ap1). The fluorapatite demonstrates various types of zoning: regular oscillatory, irregular, and internal sectoring, which is also reflected in trace elements concentrations. The rim Ap2rim has lower concentrations of Mn, Sr and Fe, and significantly higher concentrations of REE compared to the core Ap2core and older crystal Ap1. Furthermore, the rim Ap2rim is strongly depleted in Th, U and Pb. The entire crystal shows elevated Eu contents, expressed as a strong positive anomaly in chondrite-normalized REE patterns. With regards to the volatiles, F concentrations are constant in Ap1, Ap2core and Ap2rim, whereas Cl is below the EPMA detection limit. The Ap2rim was the only part of the investigated material containing OH and CO3, which were observed in the Raman spectra. Furthermore, part of the crystal Ap2core is extensively altered, likely due to fluid-induced metasomatic processes. LA-ICPMS U-Pb dating yielded highly discordant dates due to common Pb content. A lower intercept age of 297 ± 13 Ma (MSWD = 0.13) indicates the age of the fluorapatite crystallization. The overall analytical data constrain growth and post-growth processes, including crystallization of Ap1 and Ap2core, which both have typical hydrothermal Sn-W deposit characteristics, whereas Ap2rim is related to a carbonate stage of the mineralization in the Panasqueira deposit.  相似文献   
2.
The Breves deposit in the Carajás Copper-Gold Belt, Brazil, a member of the Cu-Au-(W-Bi-Sn) group of deposits, contains about 50 Mt of 1.22% Cu, 0.75 g/t Au, 2.4 g/t Ag, 1,200 g/t W, 70 g/t Sn, 175 g/t Mo and 75 g/t Bi. It is hosted by sandstones and siltstones of the Águas Claras Formation (minimum age of 2,681±5 Ma) in the roof zone of a complex, highly altered granite intrusion. The mineralisation is disseminated in a greisenized zone, resulting from alteration of probable monzogranites and syenogranites. The ore-bearing greisen contains abundant xenomorphic quartz in association with Fe-chlorite and muscovite. The gangue assemblage also includes fluorite, tourmaline, and minor amounts of monazite, xenotime, chlorapatite, thorite, zircon, calcite, siderite and bastnäesite. Copper mineralisation is dominated by chalcopyrite associated with pyrite, arsenopyrite, pyrrhotite and molybdenite. Gold particles, in equilibrium with native bismuth, are common as inclusions in chalcopyrite. The greisen contains sub-economic concentrations of tungsten and niobium that are related to the presence of ferberite, qitianlingite and Nb-rutile. SHRIMP II zircon dating of the host granites gives 207Pb/206Pb ages of 1,878±8 and 1,880±9 Ma for two phases, and a combined age of 1,879±6 Ma. SHRIMP II dating of monazite and xenotime grains in late- to post-mineralisation veins gives a combined 207Pb/206Pb age of 1,872±7 Ma, indistinguishable from the ages of the granites. This provides a genetic connection between the Breves deposit and the ca. 1.88 Ga A-type granite magmatism that typifies the Carajás Belt as part of a much larger, intracratonic magmatic province that extends over much of the Amazonian Craton. The recognition of this association has exploration implications, not only for the geophysical signature of the granite roof zones, but also for likely geochemical dispersion around the deposits of this type.Editorial handling: G. Beaudoin  相似文献   
3.
Low cost adsorbents were prepared from dried plants for the removal of heavy metals, nitrate, and phosphate ions from industrial wastewaters. The efficiency of these adsorbents was investigated using batch adsorption technique at room temperature. The dried plant particles were characterized by N2 at 77 K adsorption, scanning electron microscopy, energy dispersive X‐ray spectroscopy, Fourier transform infrared spectroscopy, and phytochemical screening. The adsorption experiments showed that the microparticles of the dried plants presented a good adsorption of heavy metals, phosphate, and nitrate ions from real wastewaters. This adsorption increased with increasing contact time. The equilibrium time was found to be 30 min for heavy metals and nitrate ions and 240 min for phosphate ions. After the adsorption process, the Pb(II) concentrations, as well as those of Cd(II), Cu(II), and Zn(II) were below the European drinking water norms concentrations. The percentage removal of heavy metals, nitrates, and phosphates from industrial wastewaters by dried plants was ～94% for Cd2+, ～92% for Cu2+, ～99% for Pb2+, ～97% for Zn2+, ～100% for ${\rm NO}_{{\rm 3}}^{{-} } $ and ～77% for ${\rm PO}_{{\rm 4}}^{3{-} } $ ions. It is proved that dried plants can be one alternative source for low cost absorbents to remove heavy metals, nitrate, and phosphate ions from municipal and industrial wastewaters.  相似文献   
4.
Ground investigations for the A303 Stonehenge Tunnels revealed a unique and complex Chalk geology including the presence of the thickest (>20 m thick), and previously unknown phosphatic chalks in England, partly filling fault controlled erosional channels. The use of natural gamma-ray borehole logs to determine the presence and thickness of the phosphatic deposits is of particular value and combined with the lithostratigraphy, macrofossil and nannofossil biostratigraphy from cores has, for the first time, accurately constrained the Coniacian to Santonian age and the lenticular geometry of such deposits. Four phosphatic chalk events between 88.5–86.5 Ma are recognised associated with synsedimentary faulting. We suggest a causal link between tectonics, subsidence and channel-formation, phosphatisation events, pulses of oceanic upwelling on a frequency of about 0.5 million years to mantle-controlled plate tectonic episodes. The implications of this geology for construction of the A303 and the archaeology of the area are discussed.  相似文献   
5.
江西宜春黄玉-锂云母花岗岩是著名的稀有金属花岗岩,P2O5含量较高（平均0.56%）.该花岗岩全岩Be含量一般超过100×10^-6,最高可达720×10^-6,属于铍矿化花岗岩.本文利用电子探针技术对宜春铍矿化花岗岩中的铍磷酸盐及其共生矿物进行了系统研究.研究发现羟磷铍钙石是该花岗岩中的最重要铍矿物（BeO=15%～16%）,偶尔亦可见磷钠铍石,它们主要呈晶间副矿物出现在岩体的中部.与铍矿物共生的矿物仍主要为磷酸盐矿物,如氟磷灰石、磷铝锂石、磷铝钠石,表明铍矿化作用与熔体中磷的聚集作用有显著关系.研究认为,宜春黄玉-锂云母花岗岩中铍以磷酸盐矿物形式结晶,而不是硅酸盐矿物,其主要原因可能为该花岗岩的结晶晚期磷的活度远远高于硅的活度,因此,P优先作为成网离子与铍结合形成铍磷酸盐矿物.  相似文献   
6.
The Oum Er-Rabia Basin provides important water resources from a multi-layer aquifer system of which the Turonian limestone aquifer constitutes the main potential resource. The same basin is also known by its wealth in phosphates and comprises the Ouled Abdoun Series, the largest Moroccan phosphate occurrence. The present work attempts to characterize the interaction of natural resources with their impacts on water and phosphates quality. Hydrogeochemical data on waters of the Turonian and the Eocene aquifers, as well as their petrographical analyses, by optical and electronic microscopes and by the X-ray diffraction method on weathered and non-weathered rocks of relative aquifers, have shown that water-rock interaction has a large influence on the quality of water and phosphate resources in the Oum Er-Rabia Basin.  相似文献   
7.
Though the Maastrichtian Phosphates of Morocco have yielded very rich marine vertebrate assemblages, plesiosaurs remain very scarce in these strata. The only hitherto recognized taxon was Plesiosaurus mauritanicus Arambourg, 1952, regarded here as a nomem dubium. Here we describe a new genus and species of elasmosaurid plesiosaur, Zarafasaura oceanis, which represents the first valid elasmosaurid plesiosaur described from the latest Cretaceous of Africa, and the second one from this continent. A phylogenetic analysis of plesiosauroids indicates that Zarafasaura oceanis has close affinities with elasmosaurids from the Late Cretaceous of North America and Japan. Among its distinctive suite of characters, the general shape and organisation of its squamosal and palate are unique among elasmosaurids. This new taxon completes our understanding of Late Cretaceous plesiosaur palaeobiodiversity and palaeobiogeography, and shows that Maastrichtian plesiosaurs were characterized by a quite high degree of endemism. They were also highly diversified and distributed worldwide, which supports the hypothesis of a catastrophic extinction of plesiosaurs at the K/T boundary.  相似文献   
8.
Brian Jones   《Sedimentary Geology》2009,219(1-4):302-317
Calcitic speleothems from a cave located on the north central coast of Grand Cayman commonly include corrosion surfaces that developed when calcite precipitation ceased and corrosion mediated by condensates became the operative process. Dissolution features associated with these surfaces, including etched crystal surfaces, microcavities, and solution-widened boundaries between crystals, are commonly occupied by microbes and microbial mats that have been replaced by calcium phosphate and/or coated with calcium phosphate. No mineralized microbes were found in the calcite crystals that form the speleothems. The morphology of the mineralized hyphae (eight morphotypes) and spores (nine morphotypes) are indicative of actinomycetes, a group of microbes that are ideally adapted to life in oligotrophic cave environs. Superb preservation of the delicate hyphae, aerial hyphae, and delicate ornamentation on the hyphae and spores indicate that the microbes underwent rapid mineralized while close to their original life positions. Although these actinomycetes were extremely susceptible to replacement by calcium phosphate, there is no evidence that they directly or indirectly controlled precipitation. Nevertheless, the association between the P-rich precipitates and microbes shows that the use of phosphorus as a proxy for seasonal climate changes in paleoclimate analyses must be treated with caution.  相似文献   
9.
 Northland, New Zealand has been affected by natural hot water spring systems depositing elevated concentrations of mercury and arsenic over the past 5 million years. Due to the different erosion levels of these hot water systems, four principal types of mercury and arsenic occurrences are found: active hot springs; layered surface deposits (sinters) deposited by hot springs; highly fractured rock zones formed immediately beneath hot springs; and chemically altered and mineralized rock from the deeper roots of hot spring systems. Mercury occurs principally as cinnabar and as a minor impurity (<1 wt%) in phosphate minerals and iron sulfides, particularly marcasite. Mercury is irregularly distributed through limonitic cements formed during oxidation. Arsenic occurs as a minor impurity (<1 wt%) in phosphate minerals and iron sulfides, particularly marcasite. Arsenic is also variably dispersed through limonite, but not necessarily with mercury. Decomposition of marcasite constitutes the most significant source of mercury and arsenic pollution from the studied sites. Release of mercury and arsenic into the environment from marcasite, phosphates and limonite is enhanced by acidification of the sites (down to pH of 2), caused by oxidation of iron sulfides. Mercury and arsenic concentrations of up to 100 parts per billion should be expected in waters near the deposits; these concentrations are in excess of recommended drinking water levels. Received: 9 April 1999 · Accepted: 2 August 1999  相似文献   
10.
In Greece, several occurrences of phosphates have been located in Mesozoic and Cenozoic sedimentary rocks. The aim of the present paper is to describe the mineralogy, geochemistry and the origin of the phosphates deposited in marine and lacustrine basins of Neogene age in Greece. Phosphates of marine origin formed in an outer shelf-upper slope environment (Palliki Peninsula, Kefalonia Island) as well as in a hemipelagic environment (Heraklion, Crete Island). In both the deposits, the phosphate minerals belong to the apatite group. In Kefalonia Island, phosphatic material accumulations occur in the field as scattered or accumulated vertebrate bones, fish teeth and other biogenic components, hosted in a sandy limestone of Upper Tortonian age. On a microscopic scale, in the groundmass of the limestone, phosphate minerals are present as fillings and secondarily as replacements of foraminiferal and other calcareous microfossil tests. In Crete Island, burrowed cobbles and phosphatic concretions up to 10 cm in diameter have been detected east of Heraklion town. The phosphatic material is hosted in a sandy marlstone that is interbedded with diatomaceous rocks of Middle Pliocene age. Phosphates of lacustrine origin have been formed in the NW–SE-oriented Upper Miocene basins of Florina–Ptolemais and Elassona–Sarantaporo, located, respectively, in western Macedonia and Thessaly, Greece. The phosphate minerals are mainly represented by Ca/Fe phosphates such as anapaite and mitridatite and secondarily by Ca phosphates of the apatite group that are hosted in a thick succession of clayey diatomite rock. They usually form lenticular layers, asymmetric lenses, nodular and botryoidal aggregates, and faecal pellet replacements.

The major and trace element content of a representative set of rocks was studied. Their geochemistry was found to be controlled by the presence of detrital minerals, the host rock mineralogies, and the types of phosphate minerals present. The relatively high amounts of uranium, arsenic and barium detected in some of the phosphate rocks studied are mainly related with organic matter and are comparable to those detected in other phosphate deposits worldwide.

In the deposits studied, phosphogenesis was mainly promoted by the decay of organic substances derived from diatoms, fishes and other vertebrates, leaves and trunks, and faecal pellets in a highly reducing environment on or just below the sea or lake bottom, and secondarily by the feeding of the basin with phosphate-bearing nutrients that originated in the land.  相似文献   

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