Possible chemical structures and biological precursors of different vitrinites in coal measure in Northwest China     

Dayong Liu  Ping'an Peng   《International Journal of Coal Geology》2008,75(4):204-212

Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state ¹³C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in ¹³C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in ¹³C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and ¹³C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.  相似文献   

Problems of soil and groundwater pollution in the disposal of “marble” slurries in NW Sicily     

G. Rizzo  F. D’Agostino  L. Ercoli 《Environmental Geology》2008,55(5):929-935

This work deals with disposal of slurries generated during the cutting and polishing processes of slabs of decorative sedimentary carbonate rocks in the north western Sicily. At present, they are used as fillers of dismantled quarries near the sawmills and, as a final step of reclamation, are covered with earth layers. In spite of such inexpensive solution, there is lack of knowledge about the composition of the waste. In order to assess if there is any threat for the environment and to suggest indications for alternative solutions, such as recycling or inactivation processes, the slurries were analysed by XR diffraction, simultaneous thermal analysis, ICP/MS, ionic chromatography, FTIR, UV-Vis, COD and TOC measurements, grain size analysis. Results indicate that the slurries can threaten the groundwater, because of the high chemical oxygen demand; furthermore they can modify the mechanism of groundwater recharge, because of their grain size distribution. Some laboratory tests show that, even in very aggressive conditions, the solid pollutants persist in the waste and slowly release into water the products of their degradation. The slurry therefore should be subjected to inactivation treatment before disposal or, alternatively, recycled as secondary raw material for a suitable process.  相似文献   

GIS支持的城市固体废弃物规划管理信息系统构建     

李劲  王华 《测绘工程》2008,17(1):60-63

研究了基于组件式GIS平台MapX的城市固体废弃物规划管理信息系统的设计与实现;讨论了系统框架与系统功能设计、数据库设计和系统实现的关键技术。以昆明市为例,构建了基于MapX的城市固体废弃物规划管理信息系统。该系统能够实现城市固体废弃物各类数据的采集、表达和输出,提供与城市固体废弃物管理模型无缝集成的接口,可利用地图、文字、表格等多种手段为城市固体废弃物规划管理提供辅助决策。  相似文献   

江苏危机矿山深部及外围潜力资源找矿          下载免费PDF全文

苏安金  苏阳 《江苏地质》2008,32(3):235-238

介绍了危机矿山的定义.对江苏省主要固体矿产矿山的危机程度进行了综合分析.叙述了能源矿产、金属矿产和其他非金属矿产等矿山所属的危机程度.指出了危机矿山存在的主要问题,即矿产资源保证程度低;资源潜力依据充分,但找矿难度大.就江苏危机矿山深部及外围潜力资源找矿工作,提出了一些建议.  相似文献   

On the tidal variation of the geopotential     

José M. Ferrándiz  Juan Getino 《Celestial Mechanics and Dynamical Astronomy》1993,57(1-2):279-292

In this paper analytical expressions are derived for the temporal variations ofJ ₂ andJ ₂₂ due to the tides of the solid Earth, taking into account only the deformation of the mantle, and employing a procedure already used by the authors in their Hamiltonian theory of the Earth's rotation, which obtain the necessary parameters in a direct way by integration of those provided by a selected model of Earth interior.Numerical tables giving the periodic variation of coefficients are given, as well as a new prediction for UT1. For J ₂ and J ₂₂ the amplitudes reach such a magnitude that both two variations should not be ignored in studies involving the analysis of highly precise satellite tracking data. Moreover, the possibility of improving our knowledge of the value of those harmonic coefficients in only a more exact digit appears as to be strongly dependent on the limitations in the theoretical modeling of the variations of the inertia tensor due to solid tides.  相似文献   

中国科学院固体地球科学知识创新工程现状与发展态势     

周少平  张金东  范蔚茗 《地球科学进展》2002,17(5):776-781

回顾了中国科学院国家知识创新试点工程实施以来特别是启动阶段3年里固体地球科学知识创新工程试点各项工作的进展情况，包括项目与经费、创新成果、人才吸引、科研竞争力提升、院地合作推进等方面，分析和总结了中国科学院固体地球科学知识创新工程现状，并展望了固体地球科学知识创新工程若干重要发展态势。  相似文献   

Structural relaxation in the MnCO3–CaCO3 solid solution: a Mn K-edge EXAFS study     

Y. J. Lee  R. J. Reeder  R. W. Wenskus  E. J. Elzinga 《Physics and Chemistry of Minerals》2002,29(9):585-594

Mn K-edge EXAFS spectroscopy of solid-solution samples encompassing the complete MnCO₃–CaCO₃ series shows that first-shell Mn–O distances deviate little from the 2.19-Å distance observed in pure MnCO₃. Very slight lengthening is observed only in the limiting case of dilute Mn(II) calcite solid solutions, where the Mn–O distance is 2.21 Å. The observed nearly complete structural relaxation and the composition independence of the Mn–O distance are consistent with the Pauling model behavior of solid solutions, and agree with previous studies showing a high degree of relaxation around hetero-sized substituents in the calcite structure. Strain occurs through bond bending, which is facilitated by the exclusively corner-sharing topology of calcite. Observed distances from Mn to more distant neighbors show significant variation across the solid-solution series that resembles Vegard's law-type behavior but reflects averaging. The high degree of relaxation suggests modest enthalpies of mixing in the solution, consistent with calorimetric studies.  相似文献   

江西瑞昌1995年ML4.9级地震前后九江地震台倾斜固体潮汐变化分析     

赵爱平  吴敏 《华南地震》2002,22(4):79-84

通过月整点值数据文件和滑动值数据文件这两种数据处理形式。对九江台地倾斜资料进行调和分析计算。分析了M2潮汐因子与瑞昌ML4.9级地震的关系。认为存在震前短临异常或震后异常，并与趋势异常得到相互印证。  相似文献   

LiCl-NiCl2熔盐体系相图          下载免费PDF全文

张宏力  方建慧  阎立诚  陈念贻 《盐湖研究》2003,11(1):7-10

用原子参数 模式识别方法研究AX BX2 型卤化物熔盐体系形成固溶体的规律性 ,同时预报了LiCl NiCl2 熔盐体系能形成以LiCl为基的广泛固溶体。采用热分析法和X 射线衍射分析等实验测定了LiCl NiCl2熔盐体系相图 ;结果与计算预报相符。  相似文献   

A Simplified Analytical Procedure for the Determination of Organically Bound Halogens in Salt‐containing Water Samples     

Helko Borsdorf  Petra Fiedler  Dorit Wilke  Holger Weiß 《洁净——土壤、空气、水》2003,31(1):19-24

A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established.  相似文献