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《Comptes Rendus Geoscience》2018,350(6):267-278
This study uses field observations and new U–Pb ages of detrital zircon grains from three samples to question the stratigraphic position of the Firgoun and Niamey siliciclastic sediments, presumed to be Neoproterozoic in age. Sharing several lithological similarities with the Late Cryogenian “Triad” of the Taoudenni, Gourma, and Volta basins, the uppermost siliciclastic sediments of the Firgoun and Niamey areas were likely also deposited during this period. This is corroborated by matrix-supported diamictites with faceted or striated pebbles as well as by structures resembling cryoturbation processes. However, the detrital zircon U–Pb age record that we present here for the lowermost deposits of Firgoun and Niamey provides mainly Paleoproterozoic ages, and very few Archean ages, altogether in a range from 1822 ± 9 to 3392 ± 9 Ma. Therefore, the new data only show that the Firgoun and Niamey sediments were deposited before about 1800 Ma. Nevertheless, the U–Th–Pb zircon age data allows examining the possible provenance of the sediments. We show that the latter was likely in the westerly close vicinity of the studied areas. The Archean zircons are likely inherited, and possibly originating from a more westerly source. The nearby source of the Niamey and Firgoun sediments suggests that a high topographic relief was still existing in the south-central part of the West African Craton in the Mid Neoproterozoic.  相似文献   
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Stable isotope data (δ18O, δ13C) were obtained for magnesite (MgCO3) from Holocene salt lake deposits of the Taoudenni–Agorgott basin, Mali, in which it is the only carbonate mineral present. The deposits have a high glauberite content (Na2Ca(SO4)2), representing a type of continental evaporite formation that is commonly magnesite‐bearing. Samples from seven different levels in a 5 m long sequence were analysed. δ18OV‐PDB values are between +3.17 and +5.91‰, which is lower than might be expected for evaporitic environments, recording reduced 18O enrichment at high salinity. δ13CV‐PDB values are between −1.32‰ and −4.79‰, showing an influence of carbon derived from the decomposition of organic matter rather than from exchange with atmospheric CO2. Covariance between δ18O and δ13C is strong for the lower part of the sequence, recording coupled 18O and 13C enrichment as commonly observed for closed basins. Covariance is lacking for the upper part of the sequence, with only periodic massive magnesite deposition in a more shallow lake. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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