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Amphiboles were synthesized from bulk compositions prepared along the join Ca1.8Mg5.2Si8O22(OH)2–Ca1.8Mg3Ga4Si6O22(OH)2 hydrothermally at 750–850 °C and 1.0–1.8 GPa, and along the join Ca2Mg5Si8O22F2–Ca2Mg3Ga4Si6O22F2, anhydrously at 1000 °C and 0.7 GPa to document how closely the tschermak-type substitution is obeyed in these analogues
of aluminous amphiboles. Electron-microprobe analyses and Rietveld X-ray diffraction structure refinements were performed
to determine cation site occupancies. The extent of Ga substitution was found to be limited in both joins, but with the fluorine
series having about twice the Ga content (0.6 atoms per formula unit, apfu) of the hydroxyl-series amphiboles (0.3 apfu).
The tschermak-type substitution was followed very closely in the hydroxyl series with essentially equal partitioning of Ga
between tetrahedral and octahedral sites. The fluorine-series amphiboles deviated significantly from the tschermak-type substitution
and, instead, appeared to follow a substitution that is close to a Ca-pargasite substitution of the type: [6]Ga3++2[4]Ga3++1/2[A] Ca2+ = [6]Mg2++2[4]Si4++1/2[A]□. Infrared spectroscopy revealed an inverse correlation between the intensity of the OH-stretching bands and the Ga content
for the hydroxyl- and fluorine-series amphiboles. The direct correlation between the Ga and F content and inverse relationship between the Ga and
OH content may be a general phenomenon present in other minerals and suggests, for example, that high F contents in titanite
are controlled by the Al content of the host rock and that there may be similar direct Al–F correlations in tschermakitic
amphiboles. Evidence for the possibility that Al (Ga) might substitute onto only a subset of the tetrahedral sites in tschermakitic
amphiboles was sought but not observed in this study.
Received: 5 March 2001 / Accepted: 31 July 2001 相似文献
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攀西中元古结晶片岩系遭受了前进区域变质作用。盐边和米易的砂屑岩和泥质岩分别可划出:绿泥石、黑云母、铁铝榴石、十字石和夕线石带以及绿泥石、黑云母-石榴子石、红柱石和夕线石带。在中、低级泥砂质岩石中,白云母的Na/(Na+K)比值随变质级增高。白云母、绿泥石和黑云母中的契尔马克替换范围大体上随变质级增高而降低。白云母和绿泥石之间契尔马克替换交换反应的分配系数,大致是白云母的绿鳞石含量的函数,并随变质温度升高而降低,在夕线石带,该分配系数变得很小。黑云母和白云母契尔马克替换交换反应的分配系数有类似的趋势。 相似文献
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Progressive sequence of reactions of the Ryoke metamorphism in the Yanai district, southwest Japan: the formation of cordierite 总被引：2，自引：0，他引：2
T. IKEDA 《Journal of Metamorphic Geology》1998,16(1):39-52
The compositions of biotite and muscovite were examined in terms of the paragenesis and the metamorphic grade in low- to medium-grade pelitic rocks of the Ryoke metamorphism in the Yanai district, southwest Japan. The biotite and muscovite that coexist with K-feldspar have a higher K component in an A'KF diagram than those in rocks lacking K-feldspar. This fact reflects an increase in the K2 O content in muscovite, but in biotite it reflects an increase of not only the K2 O content but also of the octahedral vacancy.
At higher metamorphic grade beyond the cordierite isograd, where cordierite coexists with neither chlorite nor K-feldspar, the biotite shows an increase in illite, K Aliv □xii−1 Si−1, and Tschermak components, Alvi Aliv R+−1 Si−1, where □xii and R+ denote the interlayer vacancy and (Fe+Mg+Mn), respectively. A reaction to define the cordierite isograd is proposed by treating this chemical change as being responsible for the first appearance of cordierite, i.e. K,Al-poor biotite+phengitic muscovite=K,Al-rich biotite+cordierite+quartz+water .By treating this as a key reaction in medium-grade metamorphism, a set of reaction in a progressive metamorphism is established for the Ryoke metamorphism, a typical low-pressure type metamorphism. Some textures in one of the high-grade areas, the K-feldspar-cordierite zone, suggest that a further two prograde reactions have taken place, i.e. andalusite+biotite+quartz=cordierite+K-feldspar+water
and andalusite=sillimanite.quartz=cordierite+K-feldspar+water
This implies that this zone probably has a P–T path involving isobaric heating. 相似文献
At higher metamorphic grade beyond the cordierite isograd, where cordierite coexists with neither chlorite nor K-feldspar, the biotite shows an increase in illite, K Aliv □xii−1 Si−1, and Tschermak components, Alvi Aliv R+−1 Si−1, where □xii and R+ denote the interlayer vacancy and (Fe+Mg+Mn), respectively. A reaction to define the cordierite isograd is proposed by treating this chemical change as being responsible for the first appearance of cordierite, i.e. K,Al-poor biotite+phengitic muscovite=K,Al-rich biotite+cordierite+quartz+water .By treating this as a key reaction in medium-grade metamorphism, a set of reaction in a progressive metamorphism is established for the Ryoke metamorphism, a typical low-pressure type metamorphism. Some textures in one of the high-grade areas, the K-feldspar-cordierite zone, suggest that a further two prograde reactions have taken place, i.e. andalusite+biotite+quartz=cordierite+K-feldspar+water
and andalusite=sillimanite.quartz=cordierite+K-feldspar+water
This implies that this zone probably has a P–T path involving isobaric heating. 相似文献
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