The magmatic to hydrothermal transition and its bearing on ore-forming systems   总被引：1，自引：0，他引：1  

Werner E. Halter  James D. Webster 《Chemical Geology》2004,210(1-4):1-6

The exsolution of volatile phases from silicate magmas controls physical and chemical magma properties and influences large-scale geologic phenomena and processes having major societal and economic implications including the release of climate-altering gases to the atmosphere, the explosivity of volcanic eruptions, hydrothermal alteration, and the generation of magmatic–hydrothermal mineralization. These volatile phases exsolve from a wide variety of magmas and cover a very broad spectrum of compositions.

The transition from the orthomagmatic to the hydrothermal stages has important bearing on these fundamentally important geologic phenomena, and this report summarizes the published results of a dozen scientific investigations on the magmatic–hydrothermal transition as applied to volcanic eruption and magmatic–hydrothermal mineralization. These studies involve a variety of analytical and experimental methodologies, and many focus on fluid and melt inclusions from mineralized magmatic systems. A primary goal of each study is to better understand the role of magmatic volatiles and the importance of the magmatic–hydrothermal transition on these geologic processes.  相似文献   

流动注射分光光度法同时测定水中挥发酚及氰化物     

陈素兰章勇  盛冬梅 《江苏地质》2005,29(3):162-164

在单针进样器的基础上，增加一个三通流路同时进样，在线消解-流动注射分光光度法测定水中挥发酚及氰化物。实验结果表明，挥发酚浓度在0mg/L～0．2mg／L、氰化物浓度在0mg/L～0．5mg／L范围内具有良好的线性关系。通过在线气体扩散分离技术，提高了分析速度，每小时可完成12个～15个样品的分析。方法的相对标准偏差〈5％，回收率在90．4％～108．5％之间。  相似文献   

Zur Bildung von Artefakten und deren Vermeidung bei der Bestimmung leichtflüchtiger Halogenkohlenwasserstoffe in Wasser mittels Headspace-Gaschromatographie unter den Bedingungen der DIN 38407 Teil 5 (DEV-F5). Teil II: Überhöhte Trihalogenmethanbefunde in gechlortem Schwimmbeckenwasser     

J. Koch  P. Vlker 《洁净——土壤、空气、水》1996,24(4):179-184

Formation of Artefacts and its Suppression during the Determination of Volatile Halogenated Hydrocarbons in Water by Means of Headspace Gas Chromatography under the Standard Conditions of DIN 38407-F5. Part II: Increased Trihalomethane Formation in Chlorinated Swimming-pool Water A comparison of two analytical standard procedures for the determination of trihalomethanes (THM) in water (headspace gas chromatography and pentane extraction/gas chromatography) yielded strongly differing results. Under the conditions recommended by the German Standard Method DIN 38407-F5 (60…80°C for at least 60 min) degradation of thermo-labile chlorination products occurs resulting in elevated THM concentrations. The reactions involved are partly pH-dependant, and these can be suppressed by sample acidification. The degradation of trihalogen acetic acids, however, can only be influenced by minimizing the equilibration time and temperature. Other intermediate chlorination products (haloacetonitriles) are also degraded to THM after preceding hydrolysis to the corresponding carboxylic acids. Comparative results obtained with a purge and trap method at ambient temperature, i.e. without thermal stress during the enrichtment step, are lower than with static headspace GC but still high in comparison to the pentane extraction method. Presumably volatile THM-precursors are also trapped and subsequently decomposed upon thermal desorption from the trap. As the static headspace GC is the most rational method of LHKW determination available, the recommended experimental sample handling conditions should be modified in a way that deterioration reactions are reduced as far as possible.  相似文献   

The Kuwae (Vanuatu) eruption of<Emphasis Type="SmallCaps"> AD</Emphasis> 1452: potential magnitude and volatile release     

J. B. Witter  S. Self 《Bulletin of Volcanology》2007,69(3):301-318

Sometime during AD 1452, according to new evidence, a large-magnitude, initially phreatomagmatic eruption, destroyed the island of Kuwae (16.83°S, 168.54°E), located in the present-day Republic of Vanuatu. It created a 12×6-km submarine caldera composed of two adjacent basins. Based on estimates of caldera volume, between 30 and 60 km³ DRE of dacite magma was ejected as pyroclastic flow and fall deposits during this event. Annual layers of ice dating from the period AD 1450–1460 contain acidity peaks representing fallout of sulfuric acid onto both the Greenland and Antarctic ice caps. These acidity peaks have been attributed by others to the sedimentation of H₂SO₄ aerosols that originated from sulfur degassing during the Kuwae eruption. Improved dating techniques and new data from nineteen ice cores reveal a single acidity peak attributed to Kuwae lasting from 1453 to 1457. In this study, we present new electron microprobe analyses of the S, Cl, and F contents of matrix glasses and glass inclusions in phenocrysts from tephra ejected during the Kuwae eruption. We establish that the Kuwae event did indeed yield a large release of sulfur gases. From our glass inclusion data and analysis, we calculate that the total atmospheric aerosol loading from the 1452 Kuwae eruption was ≫100 Tg H₂SO₄. Much of the volatile mass released during the eruption was probably contained in a separate, volatile-rich, fluid phase within the pre-eruptive Kuwae magma body. Comparing the volatile release of the Kuwae eruption with other large-magnitude eruptions, places Kuwae as the greatest sulfuric acid aerosol producer in the last seven centuries, larger even than sulfur emissions from the eruption of Tambora (Indonesia) in 1815, and possibly Laki (Iceland) in 1783. The severe and unusual climatic effects reported in the mid- to late-1450s were likely caused by the Kuwae eruption.  相似文献   

火山喷发形式与挥发分含量   总被引：1，自引：0，他引：1  

贾祖冰  夏群科  田真真 《岩石学报》2014,30(12):3701-3708

火山喷发是由地球深部物质发生部分熔融产生的岩浆上涌至地表所形成的一种地质现象,是地球内部能量释放的主要途径之一。有些火山喷发极为猛烈,产生的大量火山灰能够在长达几个月的时间内影响当地气候环境,甚至可以在一瞬间掩埋整座城市;而有些火山喷发时只有大量的熔岩从火山口中静静地溢出,人们甚至可以在不远处进行观赏。火山喷发具有何种程度的破坏力取决于其喷发形式,而挥发分含量是影响喷发形式的重要因素之一。本文简述了几种常见的喷发形式及其相互之间可能存在的转化关系,着重论述了挥发分含量在其中所起到的作用,同时介绍了几种可能的去气模型及常见的测量岩浆挥发分含量的方法。其中使用单斜辉石斑晶来反演大陆玄武岩原始岩浆水含量的方法预计会在未来的研究中得到普及。  相似文献   

Near-infrared spectral monitoring of Triton with IRTF/SpeX I: establishing a baseline for rotational variability     

W.M. Grundy  L.A. Young 《Icarus》2004,172(2):455-465

We present eight new 0.8 to 2.4 μm spectral observations of Neptune's satellite Triton, obtained at IRTF/SpeX during 2002 July 15-22 UT. Our objective was to determine how Triton's near-infrared spectrum varies as Triton rotates, and to establish an accurate baseline for comparison with past and future observations. The most striking spectral change detected was in Triton's nitrogen ice absorption band at 2.15 μm; its strength varies by about a factor of two as Triton rotates. Maximum N₂ absorption approximately coincides with Triton's Neptune-facing hemisphere, which is also the longitude where the polar cap extends nearest Triton's equator. More subtle rotational variations are reported for Triton's CH₄ and H₂O ice absorption bands. Unlike the other ices, Triton's CO₂ ice absorption bands remain nearly constant as Triton rotates. Triton's H₂O ice is shown to be crystalline, rather than amorphous. Triton's N₂ ice is confirmed to be the warmer, hexagonal, β N₂ phase, and its CH₄ is confirmed to be highly diluted in N₂ ice.  相似文献   

挥发份对高硅岩浆演化趋势的制约:以东南沿海白垩纪晚期花岗岩类岩石为例SCIEI北大核心CSCD     

陈璟元  杨进辉  张吉衡  周夏冰  杨志国 《岩石学报》2022,38(5):1460-1480

东南沿海分布大面积的白垩纪晚期侵入岩。这些岩石可分为两期:其中115~100Ma以钙碱性系列岩石为主,岩石组合为辉长岩-闪长岩-花岗闪长岩-二长花岗岩-碱性长石花岗岩;而100~86Ma的岩石为碱性系列,岩石组合为石英二长斑岩-正长斑岩-碱性长石花岗岩。115~100Ma的辉长岩以角闪辉长岩为主,具有极高的CaO、MgO和Al_(2)O_(3)含量,具有极低的SiO_(2)(42.9%~53.8%)、全碱(K_(2)O+Na_(2)O:0.86%~5.28%)、Ba、Nb、Th、Rb和Zr含量,也具有极低的FeO^(T)/MgO、La/Yb和Zr/Hf比值,较高的Eu/Eu^(*)、Sr/Y比值和Sr含量,为基性-超基性堆晶岩。与辉长岩同期的闪长岩和细粒暗色包体具有较高的SiO_(2)(50.34%~63.68%),较低的CaO、P_(2)O_(5)、MgO、Al_(2)O_(3)含量,相对低的Eu/Eu^(*)和Sr/Y比值,变化较大的La/Yb和Zr/Hf比值,代表了从基性岩浆储库中抽取的富硅熔体。115~100Ma的花岗闪长岩和二长花岗岩类岩石为准铝质岩石,SiO_(2)含量变化较大(61.7%~75.3%),具有较低的FeO^(T)/MgO、Ga/Al比值和Nb、Zr及Nb+Zr+Ce+Y元素含量,显示出典型I型花岗岩的特征。这些花岗岩具有相对高的La/Yb、Eu/Eu^(*)和Zr/Hf比值和高的Sr、Ba和Zr含量。结合岩相学特征,这些花岗岩为堆晶花岗岩。而115~100Ma的碱性长石花岗岩具有极高的SiO_(2)含量(大于75%),低的Eu/Eu^(*)、La/Yb、Zr/Hf和Sr/Y比值,具有低的Ba、Sr和Zr含量和高的Rb、Nb、Y和Th含量和Rb/Sr比值,表明这些花岗岩是由富硅岩浆储库中抽离的高硅熔体侵入地壳形成。100~86Ma期间形成的二长斑岩和正长斑岩具有极高的全碱含量,可以达到8%~12%,其SiO_(2)主要集中在60%~70%,具有极高的Zr、Sr和Ba含量和Eu/Eu^(*)、La/Yb和Sr/Y比值,显示出堆晶花岗岩的特征。而100~86Ma期间形成的大部分碱性长石花岗岩具有极高的SiO_(2)含量(大于75%),并显示出A型花岗岩的特征,具有高的Rb/Sr比值和高的Rb、Y和Th和低的Ba、Sr含量和低的Zr/Hf、La/Yb、Eu/Eu^(*)和Sr/Y比值,表明它们是由富硅岩浆储库抽离的高硅熔体侵入浅部地壳形成。东南沿海高硅花岗岩的形成和穿地壳岩浆系统密切相关,高硅花岗岩是由浅部地壳内晶体-熔体分异产生的熔体侵入地壳所形成,而高硅花岗岩的地球化学特征与岩浆储库的水及挥发份含量密切相关。115~100Ma期间,从富水的岩浆储库抽离的熔体形成具有低高场强元素含量和低Rb/Sr比值的高硅花岗岩,这一过程与古太平洋板块俯冲有关;100~86Ma期间,从富挥发份的岩浆储库抽离的熔体形成碱性特征、富含高场强元素和具有高的Rb/Sr比值的高硅花岗岩,这一过程和古太平洋板块回撤软流圈上涌有关。  相似文献   

阿尔泰可可托海伟晶岩中弧形石英白云母层的成因及意义   总被引：1，自引：0，他引：1  

田野  秦克章  周起凤  唐冬梅  王春龙 《岩石学报》2015,31(8):2353-2365

石英白云母层时常紧贴伟晶岩侵入体的边界出现且平行边界延伸。但是在新疆阿尔泰可可托海伟晶岩型稀有金属矿区伟晶岩体中石英白云母层出现了三种不同类型的弧形起伏,这些弧形形态仅用矿物的定向生长是难以解释的。弧形石英白云母层具有统一的"背地性"指向(弧形凸起顶端一律朝上)并且越靠近伟晶岩侵入体的顶部弧形凸起越明显,在侵入体侧部边界的石英白云母层不存在弧形凸起形态。这些形态特点与浮力作用下形成的形态具有可比性,暗示浮力与弧形石英白云母层间存在密切的成因联系。石英白云母层与石英钠长石层的间隔出现指示伟晶岩浆中挥发分含量的周期性增加。挥发分含量的周期性增加导致了挥发分不断加入未固结的剩余岩浆中并向伟晶岩体顶部上升,逐步在伟晶岩侵入体的顶部形成了弧形石英白云母层。弧形石英白云母层的大量出现不仅说明伟晶岩侵入体规模较大,也暗示存在有利的挥发分保存环境,对伟晶岩型稀有金属矿产的形成和稀有金属找矿预测起到非常重要的作用。  相似文献   

Untersuchungen zur adsorptiven Abtrennung von leichtflüchtigen chlorierten Kohlenwasserstoffen (LCKW) aus huminstoffhaltigen Wässern mit neuartigen Adsorberpolymeren und Aktivkohlen. Teil II:: Dynamik der Adsorption     

A. Kowaszik  K. Pichowski 《洁净——土壤、空气、水》1999,27(6):437-445

Investigations of the Adsorptive Separation of Volatile Chlorinated Hydrocarbons (VCHC) from Water with Humic Substance by Novel Polymeric Adsorbents and Activated Carbons. Part II: Dynamics of Adsorption In this publication, the dynamics of adsorption of different volatile chlorinated hydrocarbons (VCHC) (1,2-dichloroethane, 1,1,1-trichloroethane, trichloroethene) and a humic substance from water as well as of these VCHC from water with humic substance onto novel polymeric ad-[QJ][HR] sorbents (WOFATIT EP 63, DOWEX XUS 43493, MACRONET MN 100 and MN 200) was studied in comparison to activated carbons (NORIT ROW 0.8 SUPRA, PRECOLITH BKK 3, HYDRAFFIN CG). The obtained breakthrough curves and the following predicted characteristic values reveal that the polymeric adsorbents do not remove or remove the humic substance only with low adsorption capacity in contrast to the activated carbons. At the adsorption of the VCHC from water with humic substance it was determined that the influence of the humic substance on the adsorption capacity is substantially less on polymeric adsorbents than on activated carbons.  相似文献   

Plasma‐Based Indoor Air Cleaning Technologies: The State of the Art‐Review          下载免费PDF全文

Mitra Bahri  Fariborz Haghighat 《洁净——土壤、空气、水》2014,42(12):1667-1680

  相似文献