排序方式: 共有17条查询结果,搜索用时 15 毫秒
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研究pH和Ca(Ⅱ)对砷酸根在海水与NaCl介质中对水合氧化物和粘土矿物上交换吸附的影响:(1)在酸性条件下和海水及NaCl介质中,砷酸根在针铁矿上的交换率E(%)—pH曲线呈平顶峰型、在δ-MnO呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子/配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。(2)在碱性条件下的海水介质中,砷酸根与水合氧化物和粘土矿物的E(%)—pH曲线都呈V型,这是因为生成了具有一定结构的液—固界面三元络合物之故。(3)在NaCl介质中,Ca加入起促进作用,再次证明液—固界面三元络合物生成机理与V型曲线的内在关系 相似文献
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广西德保矿区产出的结晶为双锥状的臭葱石的主要化学成分为Fe2O3 34.5%,As2O5 47.75%;而呈葡萄状的臭葱石含Fe2O3 26.67%,As2O5 44.28%, 它们的FeAs≈1,与理想分子式FeAsO4*2H2O接近.根据该矿物(德保)的粉晶X射线分析数据用最小二乘法计算的晶胞参数为a0=10.28(A),b0=10.00(A),c0=8.90(A).Z=8,为斜方晶系,空间群为Pcab.红外吸收光谱分析显示有波数为3505、3420、3000、820、720、490、470、435、415(cm-1)等吸收带.差热分析显示有256℃、945℃和980℃三个明显的吸热谷,还显示有520℃、725℃两个小的放热峰. 相似文献
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Donald G. Fraser 《中国科学D辑(英文版)》2005,48(12):2155-2165
DOI: 10.1360/03yd0553 Arsenic, a toxic element, is ubiquitous in the earth’s crust and may lead to health risks for humans. This may come about as a result of oxidative weathering and dissolution of As-containing minerals, use of ar-senical pesticides, excess use of some fertilizers and from mine drainage, smelter wastes and agricultural drainage water from certain arid regions. The dis-solved inorganic arsenic is transported in surface or2156 Science in China Ser. D Earth Sciences groun… 相似文献
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砷铅铁矾一般产出于含砷硫化物矿床氧化带铁帽中,常见与之共生的矿物有臭葱石、砷铅石、砷铅铁石、乳砷铅铜石等砷酸盐类矿物。该矿物呈菱面体晶体,常呈假立方体状、粒状和球粒状。暗黄绿色。Hm=3.5,Hv=375kg/mm^2,Dm=4。广西平桂矿区产出的砷铅铁矾的化学成份W(B)/%为:PbO31.18,Fe2O3 31.38,As2O5 18.87,SO3 10.84,H2O 8,据此计算的矿物分子式为:Pb0.99Fe2.80(AsO4)1.17(SO4)0.96(OH)6.24。广西德保矿区产出的含铜较高的铜砷铅铁矾(?)的平均化学成份.W(B)/%为:PbO 31.72,Fe2O3 29.21,CuO 7.96,As2O5 14.84,SO3 9.88,H2O 8,据此计算的矿物分子式为:Pb0.99Fe2.61Cu0.69(AsO4)0.89(SO4)0.86o(OH)7.20砷铅铁矾(德保)的粉晶X射线分析主要衍射强线有:5.90(9),3.65(5),3.07(10),2.29(8),1.976(6)。晶胞参数为:a0=0.732nm,c0=1.702nm,Z=3。三方晶系,空间群为R3m。红外吸收光谱分析显示有波数/cm^-1为3475,3402,3212,1639,993,919,825,763,549,535.428等吸收带。差热分析显示有460C,770C和910C3个明显的吸热谷。 相似文献
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1986年,在广西德保铜锡矿床氧化带铁帽中发现有砷铝铁石,针柱状晶呈晶簇状产出。鲜红色至褐红色,硬度HM=3.5,DX=5.34,折光率大于2。五个颗粒电子探针分析平均化学成分(%)为Fe2O320.77.PbO38.29,As2O5;36.64.CaO0.24.Al2O30.43,SiO20.30,H2O+末分析(以2.85%计)计算出分子式:Pb1.11Fe1.69Al0.05Ca0.03[(AsO4)2.07(SiO4)0.03]2.10(OH)2.05,粉晶X射线分析主要衍射线(nm)有:0.324(10)(202),0.295(8)(15),0.305(7)(40),0256(7)(242),0.458(6)(211),0.418(5)(131),0.356(5)(311),0.273(5)(251),斜方晶系.计算出晶胞参数a=1.2281nm,b=1.6657nm,c=0.7663nm,Z=8。红外吸收光谱分析显示有波数为3448,3405,1638,1082,864,808,758,459(cm-1)等吸收带。 相似文献
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胶州湾中砷(Ⅴ)还原初步研究 总被引:2,自引:0,他引:2
研究胶州湾沉积物对砷(Ⅴ)的还原作用。结果表明:1.随泥水比增大,还原率升高,泥水比为且:1000时,沉积物对砷(Ⅴ)的还原率为16%;2.未煮沸的泥-水提取液还原率高于煮沸杀菌泥-水提取液。指示:沉积物有机质在微生物作用下,对砷(Ⅴ)有一定的还原作用。此外,根据胶州湾的调查结果及实验室藻类培养模拟实验结果,分析了胶州湾砷(Ⅲ)产生原因。指出:主要是由于藻类和沉积物、水体有机物的还原作用,两者的还原能力相当,但在不同季节所起的作用不同。 相似文献
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Xiaofen Yang Hongmei Wang Linfeng Gong Hima Hassane Zhengbo Jiang 《Frontiers of Earth Science》2009,3(2):221-225
Fe2+ oxidation by Acidithiobacillus ferrooxidans in pure and mixed cultures was investigated in batch cultures in the presence of arsenate. The pH value was periodically
monitored and Fe2+ content was analyzed by the 1,10-phenanthroline method. ICP-AES was employed for the analysis of As(V) concentration in the
solution phase. Precipitates were collected and analyzed by X-ray diffraction. Slight enhancement of iron bio-oxidation was
observed in mixed cultures with the two greatest As(V) concentrations (1.0 and 5.0 mg/L As), which were enriched from sediment
samples in an abandoned copper mine site. As(V) concentrations decreased with time, indicating either the co-precipitation
with or the adsorption by jarosite, the major sink of solid phase. Our data suggest that biogenically synthesized jarosite
may play an important role in the attenuation of soluble arsenate in natural aquatic environments. 相似文献