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针对低频Rayleigh表面波,设计了部分埋入式工字形截面周期波屏障。利用有限元方法计算了结构的频散曲线,分析了带隙的形成机理,讨论了屏障埋入土体深度和截面参数对带隙的影响,在此基础上设计了具有低频超宽衰减域的梯度及分段梯度波屏障并计算了其传输谱。结果表明:周期波屏障存在较宽带隙,板埋入深度和端部尺寸是影响带隙的关键参数,通过参数调节可实现不同频段Rayleigh波的调控。工字形变截面波屏障比等截面具有更优越的隔震性能且节省材料。梯度及分段梯度波屏障显著拓宽了衰减域的频率范围,对1.5~20 Hz范围内的Rayleigh表面波实现了全覆盖,用小尺寸控制了大波长。 相似文献
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Abstract: Natural sphalerite as a natural cost-effective photocatalyst was characterized and its visible light photocatalytic activity was investigated in terms of substituting ions, impurity phases and surface defects. The substitutions of metal ions for Zn2+ alter the band structure and result in the visible light response. The coexistence of impurity semiconductors and nanosized particles in natural sphalerite samples help to prolong the lifetime of electron-hole pairs. The cleavage planes and fracture surfaces improve the photocatalytic activity of natural sphalerite by providing more active sites than perfect faces. Both the negative charge defects from the non-isoelectronic substitutions and surface elements with variable chemical valence suppressed the recombination of electron-hole pairs by their possible role of capturing photogenerated holes. 相似文献
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Photocatalytic Reduction of Cr^Ⅵ by Natural Sphalerite Suspensions under Visible Light Irradiation 总被引：4，自引：0，他引：4
LI Yan LU Anhuai WANG Changqiu 《《地质学报》英文版》2006,80(2):267-272
The photocatalytic reductive capability of a natural semiconducting mineral, sphalerite has been studied for the first time. The sphalerite from the Huangshaping deposit of Hunan Province performed great photoreductive capability that 91.95% of the Cr^6＋ was reduced under 9 h visible light irradiation, higher than the 70.58% under 9.5 h UV light irradiation. The highly reductive ability results from its super negative potential of electrons in the conduction band. Furthermore, Fe substitution for Zn introduces donor states, and the oxidation process of Fe^2＋ to Fe^3＋ makes it an effective hole-scavenger. Cd and Cu substitute for Zn also reduce the bandgap and help broaden the absorbing edge towards the visible light. These substituting metal ions in natural sphalerite make it a hyper-active photocatalyst and very attractive for solar energy utilization. 相似文献
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LI Yan LU Anhuai WANG Changqiu School of Earth Space Sciences Peking University Beijing 《《地质学报》英文版》2006,80(2)
The photocatalytic reductive capability of a natural semiconducting mineral, sphalerite has been studied for the first time. The sphalerite from the Huangshaping deposit of Hunan Province performed great photoreductive capability that 91.95% of the Cr6+ was reduced under 9 h visible light irradiation, higher than the 70.58% under 9.5 h UV light irradiation. The highly reductive ability results from its super negative potential of electrons in the conduction band. Furthermore, Fe substitution for Zn introduces donor states, and the oxidation process of Fe2+ to Fe3+ makes it an effective hole-scavenger. Cd and Cu substitute for Zn also reduce the bandgap and help broaden the absorbing edge towards the visible light. These substituting metal ions in natural sphalerite make it a hyper-active photocatalyst and very attractive for solar energy utilization. 相似文献
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