新矿物长城矿—铱的硫铋化物          下载免费PDF全文

於祖相 《地质学报》1997,71(4):336-339

长城矿产在铬铁矿体及临近矿体的铂砂矿中。呈块状聚集体或细脉状,分布在硫铱矿的边缘并交代它。不透明,金属光泽,钢灰色,条痕黑色。莫氏硬度H_M=3.7,显微硬度VHN_(20)=165kg/mm~2。均质性,无解理。计算密度D_(calc.)=11.96g/cm~3。7个电子探针分析的平均化学成分(％):S 7.2,Cu 0.3,Te 0.4,Ir 41.2,Pt 2.8,Bi 47.2,总量99.1。简化的化学式为IrBiS。5条最强X射线粉晶衍射线(hkl,d,I)为:210,2.75(70);211,2.51(60);311,1.860(100);440,1.090(50);600,1.027(50)。X射线粉晶衍射图谱与马营矿相似。进行对比后,长城矿可以指标化为等轴晶系、空间群P2_13。由X射线粉晶衍射线求得α=0.6164(4)nm,V=0.2342nm~3,Z=4。  相似文献   

Changchengite—A New Iridium Bismuthide-Sulphide from the Yanshan Mountains     

Yu ZuxiangInstitute of Geology  Chinese Academy of Geological Sciences  Baiwanzhuang  Beijing 《《地质学报》英文版》1997,71(4):486-490

Changchengite occurs in chromite orebodies in dunite and in platinum placer deposits in chromite orebodies nearby. The mineral occurs as massive aggregates or veinlets on margins of iridisite (IrS2) and replaces it. Opaque. Lustre metallic. Colour steel-black. Streak black. Hm = 3.7. VHN20= 165 kg/ mm2. Isotropic. Cleavage none. Density 11.96 g/ cm3. Seven electron microprobe analyses give the following mean chemical results (wt. %): S 7.2, Cu 0.3, Te 0.4, Ir 41.2, Pt 2.8 and Bi 47.3 with total 99.1. The simplified formula is IrBiS. The strongest X-ray powder diffraction lines (hkl, d, I) are 210, 2.75 (70); 211, 2.51 (60); 311, 1.860 (100); 440. 1.090 (50) and 600, 1.027 (50). The X-ray powder diffraction pattern is similar to that of mayingite. After the diffraction data are indexed the mineral is determined to be cubic. The space group is P213 with a = 0.6164(4) nm, V = 0.2342 nm3 and Z = 4.  相似文献