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沉积物物源组成的定量判识方法及其在冲绳海槽的应用   总被引:15,自引:3,他引:12  
用多元成分数据统计分析中的端元估计算法,处理混合源沉积物地球化学数据定量判识沉积物物源端元的化学成分和比例。将该方法应用于已知端元的人工数据,端元的化学成分和含量的估计值与已知值非常接近。实验结果说明,这种成分数据分析算法是定量判识沉积物物源端元的有效方法。  相似文献   
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对山东半岛泥质楔柱状样进行沉积物粒度分析,并在210Pb测年基础上结合黄河年输沙量、悬浮泥沙粒径、河口位置及沿岸流强弱替代指标等数据研究近百年来黄河改道及输沙量变化对远端沉积区沉积特征的影响。研究结果显示,研究区沉积物粒度的变化是黄河入海泥沙特征和沿岸流等水动力作用共同影响的结果。1884–1939年及1947–1999年,研究区沉积物粒度特征的变化主要受到沿岸流强弱的影响;1939–1947年及1999–2012年,受1938–1947年花园口决堤以及20世纪90年代末以来黄河年输沙量持续偏低致使源区泥沙不足的影响,沉积物粒度相对粗化,与沿岸流强度的相关性减弱。与黄河入海泥沙近端沉积区不同,研究区粒度特征对黄河尾闾改道事件不敏感,且对花园口决堤及年输沙量低于临界值的响应有一定程度的延迟,这与该区沉积物经历了再悬浮过程及中间复杂的物质混合有关。黄河改道及输沙量变化仍然是远端沉积区沉积特征演化不可忽视的因素。  相似文献   
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Spectral mixture analysis (SMA) is an image-processing technique used for the analysis of airborne hyperspectral remote-sensing data which consist of a large number of spectral bands, typically over 100. In this paper the possibilities are examined of using SMA for the analysis of Landsat Thematic Mapper satellite data with only six bands in the visible to shortwave-infrared wavelength. We use data from a semi-arid area in the Sanmatenga province of Burkina Faso, an area known to experience land-degradation problems. In SMA, we assume that pixels in an image consist of one or more homogeneous (uniform in character) or pure surfaces, the so called end-members. The end-members were derived from the image data on the basis of specific image characteristics. Field data was collected to describe the characteristics of these end-members in terms of land cover, soil and degradation phenomena. The end-members derived from the image analysis, although statistically pure in terms of image spectral characteristics, prove to be mixtures at a field scale. This lack of purity is explained by the nature of semi-arid areas which is more heterogeneous than that of most other areas. The SMA yielded cover percentages for the end-members from which an unsupervised classification was made. Comparison of the classification with the results of SMA shows that the latter provides information on the amount and spatial distribution of land characteristics such as land degradation.  相似文献   
4.
An end-member analysis was performed using algorithms ofExtended cabfac qmodel on 21 sample distributions of vitrinite reflectance (VR) by depth from the Inigok well in the National Petroleum Reserve of Alaska (NPRA). Eight end members, which account for 99% of the variance, adequately recreate the VR distributions. These eight end members contain stratigraphic information based on systematically increasing or decreasing mixing proportions with depth. Paleoheat flux determined from end members, or from orthogonally filtered sets of end members, is not significantly different from paleoheat flux determined from arithmetic mean values of VR, indicating that the arithmetic mean provides an adequate representation of each VR distribution analyzed in this well. Additionally, use of filtering devices to assess the degree of trustworthiness of signal in VR distributions enables an assessment to be made of the degree of stability of paleoheat flux variation estimates.  相似文献   
5.
系统介绍“分离沉积物端元的最优斜交成分因子算法”,此算法包括主成分分析、因子得分成分化和最优斜交变换三部分.此算法可获得成分化的非负的斜交因子得分,弥补了Q型因子分析仅能用于样品间的相互关系及样品的分类研究,而不能胜任海底沉积物端元物质分离工作之不足.方法适合于沉积物物源端元定量分离工作.将此方法应用于冲绳海槽海底表层样,成功地分离出长江陆源物质.此方法同样适合于诸如岩石、水体、土壤污染等混合过程的端元定量分离工作.  相似文献   
6.
峨眉山大陆溢流玄武岩(ECFB)的西南部以丽江、大理和攀枝花三角区为中心的苦橄岩分布区,面积约5×10 4 km2 ,为峨眉地幔柱的轴部区。Sr、Nd、Pb同位素和痕量元素研究表明,大部分火山岩样品落在洋岛火山岩成分范围内,并存在类似FOZO、HIMU和EM - 的三个端元。这说明它们是在地幔柱轴部,由地幔岩和榴辉岩(古玄武质洋壳)组成的源区产生的岩浆形成的。岩浆源区再循环玄武质洋壳的存在可能是该区超大型钒钛磁铁矿床形成的根本原因。少部分分布在洋岛火山岩成分范围之外的样品,一部分属于地幔柱岩浆与地壳混染产物,另一部分低Ti岩石可能与岩石圈反应有关。地幔端元的地球化学特征如下:FOZO端元以白林山苦橄玄武岩(YB-0 1)为代表,低87Sr/86 Sr(0 .70 36 ) ,高1 43Nd/1 44 Nd(0 .5 12 7) ,中等2 0 6 Pb/2 0 7Pb(18.5 6 93) ;Nb/U =36 .6 7,Th/Nb =0 .0 82 ,L a/Nb=0 .91,Zr/Nb=6 .2 3。HIMU端元以丽江苦橄岩(JL - 2 9)为代表,高2 0 6 Pb/2 0 4 Pb(2 0 .6 4 12 )和2 0 7Pb/2 0 4 Pb(15 .74 89) ,低87Sr/86 Sr(0 .70 4 8)。EM - 端元包括两部分:1以二滩苦橄岩-玄武岩(R- 1、3、5、8)为代表,高87Sr/86 Sr(0 .70 73) ,低1 43Nd/1 44 Nd(0 .5 12 3) ,低2 0 6 Pb/2 0 4 Pb(17.996 8)和2 0 8Pb/2 0 4 Pb(37.94 5 0 )  相似文献   
7.
Dissolved load of the Loire River: chemical and isotopic characterization   总被引:5,自引:0,他引:5  
The Loire River, with one of the largest watersheds in France, has been monitored just outside the city of Orleans since 1994. Physico-chemical parameters and major and trace elements were measured between 2-day and 1-week intervals according to the river flow. The sampling site represents 34% of the total Loire watershed with 76% silicate rocks and 24% carbonate rocks.

Elements are transported mainly in the dissolved phase with the ratio of total dissolved salts (TDS) to suspended matter (SM) ranging between 1.6 and 17.4. Chemical weathering of rocks and soils are thus the dominant mechanisms in the Loire waters composition. The highest TDS/SM ratios are due to dissolved anthropogenic inputs. The database shows no link between NO3 content and river flow. The Na+, K+, Mg2+, SO42−, and Cl concentrations are seen to decrease with increasing discharge, in agreement with a mixing process involving at least two components: the first component (during low flow) is concentrated and may be related with input from the groundwater and sewage station water, the second component (during high flow) is more dilute and is in agreement with bedrock weathering and rainwater inputs. A geochemical behaviour pattern is also observed for HCO3 and Ca2+ species, their concentrations increase with increasing discharge up to 300 m3/s, after which, they decrease with increasing discharge. The Sr isotopic composition of the dissolved load is controlled by at least five components — a series of natural components represented by (a) waters draining the silicate and carbonate bedrock, (b) groundwater, and (c) rainwaters, and two kinds of anthropogenic components.

The aim of this study is to describe the mixing model in order to estimate the contribution of each component. Finally, specific export rates in the upper Loire watershed were evaluated close to 12 t year−1 km−2 for the silicate rate and 47 t year−1 km−2 for the carbonate rate.  相似文献   

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