Stable isotope study of carbonate-cemented rocks from the Pobitite Kamani area,north-eastern Bulgaria     

R. W. Botz  V. Georgiev  P. Stoffers  Kh. Khrischev  V. Kostadinov 《International Journal of Earth Sciences》1993,82(4):663-666

The Precipitation of carbonate cements in the Pobitite Kamani area (Lower Eocene) began during early diagenesis of sediments. There is evidence, however, that calcite is still forming today.The negative ¹³C values to –29.2 suggest that the carbonate formed during degradation of ¹²C-enriched organic matter (perhaps partly from oxidation of methane). The ¹⁸O values of –0.9 to –1.6 reflect the marine origin of the early diagenetic carbonate cements. Most of the carbonates, however, formed during late diagenesis (at approximately 1300 m burial depth) and/or recently (after uplift) from percolating groundwaters. These carbonates have an isotopic composition characteristic of carbonates which precipitated from meteoric waters under normal sedimentary temperatures in isotopic equilibrium with ¹²C-enriched soil carbon dioxide.  相似文献   

Primary Ore Mineral Assemblage and Fluid Inclusion Study of the Batu Hijau Porphyry Cu-Au Deposit, Sumbawa, Indonesia   总被引：3，自引：0，他引：3  

Akira Imai  Satoshi Ohno 《Resource Geology》2005,55(3):239-248

Abstract. The Batu Hijau porphyry Cu‐Au deposit, Sumbawa Island, Indonesia, is associated with a tonalitic intrusive complex. The temperature‐pressure condition of mineralization at the Batu Hijau deposit is discussed on the basis of fluid inclusion microthermometry. Then, the initial Cu‐Fe sulfide mineral assemblage is discussed. Bornite and chalcopyrite are major copper ore minerals associated with quartz veinlets. The quartz veinlets have been classified into ‘A’ veinlets associated with bornite, digenite, chalcocite and chalcopyrite, ‘B’ veinlets having chalcopyrite bornite along vuggy center‐line, rare ‘C’ chalcopyrite‐quartz veinlets, and late ‘D’ veinlets consisting of massive pyrite and quartz (Clode et al., 1999). Copper and gold mineralization is associated with abundant ‘A’ quartz veinlets. Abundant fluid inclusions are found in veinlet quartz consisting mainly of gas‐rich inclusions and polyphase inclusions throughout the veinlet types. The hydrothermal activity occurred in temperature‐pressure conditions of aqueous fluid immiscibility into hypersaline brine and dilute vapor. The halite dissolution (Tm[halite]) and liquid‐vapor homogenization (Th) temperatures of the polyphase inclusions in veinlet quartz range from 270 to 472d?C and from 280 to 454d?C, respectively. The estimated salinity ranges from 36 to 47 wt% (NaCl equiv.). The apparent pressures lower than 300 bars are estimated to have been along the liquid‐vapor‐halite curve for the fluid inclusions having the Th lower than the Tm that trapped the brine saturated with halite, or at slightly higher pressure relative to liquid‐vapor‐halite curve for the fluid inclusions having the Th higher than the Tm that trapped the brine unsaturated with halite. The actual temperature and pressure during the hydrothermal activity at the Batu Hijau deposit are estimated to have been around 300d?C and 50 bars. At such temperature‐pressure conditions, the principal and initial Cu‐Fe sulfide mineral assemblages are thought to be chalcopyrite + bornite solid solution (bnss) for the chalcopyrite‐bearing assemblage, and chalcocite‐digenite solid solution and bnss for the chalcopyrite‐free assemblage.  相似文献   

柴达木盆地一里坪盐湖成盐卤水成分变化及其意义——来自LA- ICP- MS分析石盐流体包裹体组成的证据   总被引：1，自引：0，他引：1  

胡宇飞  汪明泉  赵艳军  焦鹏程 《地质学报》2021,95(7):2109-2120

一里坪盐湖是柴达木盆地一个以富锂卤水为主的干盐湖,蕴藏有丰富的卤水钾锂资源,目前对成矿过程中卤水的成分及其演变规律方面的研究较少.论文选取一里坪盐湖中部钻孔HC2105岩芯的石盐为主要对象,利用激光剥蚀-电感耦合等离子质谱法开展了单个石盐原生流体包裹体成分分析,探讨恢复了一里坪盐湖地区晚更新世以来成盐期的古卤水成分.结果表明,一里坪盐湖下层石盐古卤水Li、B、K等离子浓度均高于上层石盐,这说明晚更新世成矿条件更好.古卤水中Li、B、K和Mg等离子具有正相关性,再结合对Ca离子浓度变化的研究,说明一里坪盐湖的主要物质来源为那棱郭勒河,深部卤水对其物质来源贡献较小;石盐流体包裹体中各离子浓度的演变规律与钻孔沉积韵律以及古气候变化三者基本可以拟合,从而证实盐湖卤水成分变化受到古气候变化的影响,干冷期可能更有利于富锂卤水矿的形成.  相似文献   

东濮凹陷文留油田盐岩地震反射特征及相关油藏类型   总被引：1，自引：1，他引：0  

孙思敏  梁德富  黄述旺 《地质力学学报》2007,13(4):348-354

利用地震资料, 结合地质、钻井资料, 对东濮凹陷文留地区盐岩的物理性质、地震反射特征、几何形态、与盐岩相关油气藏的类型进行了研究。发现盐岩具有密度恒定特性(低密度)和速度稳定特性(高速度), 基本不随深度变化。盐岩与砂泥岩体之间有较强的波阻抗差, 因而其界面反射特征明显。但盐岩的流动特性造成盐岩体有多种赋存状态, 它们的地震反射特征各不相同, 这是盐岩解释的主要困难。利用地震资料识别归纳出盐层(体)解释判定模式, 认为本区盐岩主要有3种赋存状态:原生板状盐岩、后生变形盐岩和次生盐墙。盐岩流动变形及相变形成了3类油气藏:盐上堑式背斜油气藏、盐侧向封堵油气藏和盐下盐背斜油气藏。   相似文献   

Sedimentology and early diagenesis of the Broadford Beds (Lower Jurassic), Skye,north-west Scotland     

Alison Searl 《Geological Journal》1992,27(3):243-270

The Broadford Beds comprise a basal carbonate-dominated unit overlain by dark muddy sandstones and an upper cross-bedded sandstone unit. The limestones include coralliferous and oolitic lithologies and the sandstones include pisolitic berthierine ironstones and abundant phosphate nodules. The Broadford Beds have a maximum thickness of 140 m and can be subdivided into 17 parasequences, each initiated by an approximately 20 m rise in relative sea level. Marine flooding surfaces are most readily recognized in the lower parts of the succession, where diagenetic data can be utilized to locate emergence surfaces. There is no diagenetic evidence of early emergence in the upper parts of the sequence, but a variety of sedimentological data can be used to identify parasequence boundaries. Deposition of the Broadford Beds occurred largely around the shores of a number of islands in the northern Hebridean area. These islands partly isolated the Skye–Applecross area from a deeper marine basin to the west, and this may have enhanced the formation of authigenic phosphates and iron silicates. It is possible to use the regional variability of parasequence thicknesses to investigate the role of active local tectonism in governing differential subsidence and sediment supply.  相似文献   

Mechanism of carbonate cementation and its influence on reservoir in Pinghu Formation of Xihu Sag     

Haiqiang Bai  Xiaojun Xie  Gongcheng Zhang  Ying Chen  Ziyu Liu  Lianqiao Xiong  Jianrong Hao  Xin Li 《海洋学报(英文版)》2023,42(3):65-75

Carbonate cements are the most abundant authigenic mineral and impact on physical properties greatly in sandstone reservoir. In this paper, Pinghu Formation of Xihu Sag was taken as a target. Characteristics,distribution and formation of carbonate cements were investigated via optical microscopy, cathodoluminescence(CL), electron probe and in-situ carbon-oxygen isotope. The results showed that carbonate cements varied in types and shapes. Calcite/dolomite mainly present as poikilotopic cements, ...  相似文献   

略谈我国核废物岩盐处置的前景   总被引：7，自引：0，他引：7  

杨吉根 《华东地质学院学报》1989,12(2):55-62

  相似文献   

不同晶形石盐沉积生长特征及对包裹体温度的影响     

冯阵东  吴伟  周永  刘惟庆  魏国营  贾天让 《地质学报》2022,96(4):1469-1477

石盐晶体生长过程中捕获流体包裹体，利用冷冻测温法得到的均一温度信息与古水温存在良好的相关性。在部分地区，利用包裹体最大均一温度评价古气候时，温度数据与孢粉学反映的气候特征存在冲突，不同晶形的石盐沉积特征，及其晶体条纹内包裹体温度代表的地质含义需进一步探讨。笔者在分析经典测温数据的基础上，观察常温蒸发实验中漏斗晶和人字晶的形成及生长过程，分析了不同温度段均一温度与气温、水温之间的关系。结合现代气象记录数据，分析了最大均一温度评价气候时存在的局限性。研究认为：漏斗晶晶核形成与卤水表面，包裹体温度受温度和气压共同影响，漏斗晶在卤水底部绕核生长，漏斗晶外围包裹体温度对应水底温度，沉入水下后漏斗晶生长缓慢，包裹体最大温度可能代表年度最高温度，以此为指标评价气候得出的结论过于炎热；人字晶是多个漏斗晶之间的桥接部分，大部分形成于卤水蒸发将近结束之时，人字形条纹内包裹体温度受气温和地表温度共同影响，地表温度远大于气温是造成包裹体最高温度过高的主要原因。  相似文献   

内陆盐湖石盐流体包裹体均—温度指示意义的现代过程研究   总被引：5，自引：1，他引：5  

刘兴起 倪培董海良  王天刚 《岩石学报》2007,23(1):113-116

Halite precipitation with water and air temperature was observed in detail, and homogenization temperature of fluid inclusions in halite formed in ancient and modem Chaka Salt Lake was studied. Halite precipitates mainly in August every year and largely precipitates between 13 and 15pm at one day when water temperatures reach 20℃ but can seldom reach 30℃. Homogenization temperatures of fluid inclusions in halite formed in Chaka Salt Lake range from 14℃ to 38℃ with an average of 23.7℃. The number of inclusions appears an obvious peak value at homogenization temperatures between 18 - 25℃, which probably represent the water temperature in which halite mainly precipitates when water temperatures reach 20℃. Therefore, homogenization temperatures of fluid inclusions in halite formed in Chaka Salt Lake can wall reflect the water temperature.  相似文献   

Pleistocene climatic change in Southern Australia and its effect on speleothem deposition in some Nullarbor caves     

Albert Coede  Russell S. Harmon  Tim C. Atkinson  Peter J. Rowe 《第四纪科学杂志》1990,5(1):29-38

Activity ratios of ²³⁴U/²³⁸U, ²³⁰Th/²³⁴U, and ²³⁰Th/²³²Th have been determined for calcite, gypsum and halite speleothems from caves of the Nullarbor Plain, mostly in the area N and NW of Mundrabilla Station, for the purpose of U-series dating. All calcite speleothems contain adequate amounts of uranium for dating, but some show an excess of ²³⁰Th. Stratigraphic relationships indicate that there were at least three phases of calcium carbonate deposition in the Nullarbor caves. The calcite samples, with one possible exception, have ages in excess of ca. 400000 yrs BP. This suggests that no significant amounts of calcium carbonate deposition have taken place during the last 400ka. At present, active deposition of speleothems is restricted almost entirely to gypsum and halite. The only gypsum speleothem dated was found to have a finite age of ca. 185 ka. Six dates on a small halite speleothem containing insect and arachnid remains indicate that it formed rapidly during Holocene time.  相似文献