Preliminary investigation of mercury in bone tissues of skua and penguin in Antarctica using AFS and Synchrotron Radiation X-ray Fluorescence （SR-XRF）   总被引：1，自引：0，他引：1  

谢周清程邦波  孙立广黄宇营 何伟 《极地研究(英文版)》2005,16(1):33-40

Mercury （Hg） was investigated in bone tissues of skua （ Catharacta maccormick） and penguin （Pygoscelis adeliae） collected in the maritime Antarctic using atomic fluorescence spectrometry （AFS） and synchrotron radiation X-ray fluorescence （SR-XRF） method. The total levels of mercury in bone tissues of penguin and skua are much lower than those in other organs （e. g. , kidney, liver）. The toxic effects of mercury in bone tissues of seabirds in polar region are not known. We have used SR- XRF method to map the distribution of trace levels of mercury in bones. The levels of mercury are found to be enriched somewhere near the periosteal surface and/or endosteal surface. The distribution of mercury shows strongly correlation with that of some essential elements and probably poses negative effect on the bone metabolism inferring from the relationship of mercury with the other elements. These studies represent a first step toward understanding the toxic effects of mercury on bone of polar animals by suggesting the possible microscopic investigation.  相似文献   

Metamorphic phase relations in orthopyroxene-bearing granitoids: implication for high-pressure metamorphism and prograde melting in the continental crust     

S. K. BHOWMIK  L. SAHA  S. DASGUPTA  M. FUKUOKA 《Journal of Metamorphic Geology》2009,27(4):295-315

In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K₂O, Ca/(Ca + Na)_rock and FeO_tot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H₂O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB.  相似文献   

定水头注水引起的含水层水平运动和应变   总被引：2，自引：2，他引：0  

王庆良  冉兴龙 《大地测量与地球动力学》2001,21(4):26-32

基于含水层固体颗粒与孔隙水不可压缩的假设 ,本文导出了单井注水情况下泰斯承压含水层水平运动速度与水头之间的基本关系式。然后利用注水井壁处的应力、应变边界条件 ,进一步导出了单井定水头注水引起的泰斯承压含水层水平运动速度、位移和应变解析表达式。该水平位移与应变由两部分组成 :一部分为由注水压力本身引起的经典弹性力学解项 ,它仅随半径而变化 ,与注水时间无关 ;另一部分为由地下水头变化引起的水动力学位移和应变解项。其中 ,含水层水动力学水平位移随时间加长呈指数增长特征 ,水动力学径向应变则表现为近井处拉张、远井处挤压的分区特征 ,且近井拉张区随时间加长逐渐向外扩展。单井注水含水层水动力学水平位移、应变解的导出 ,完善和发展了单孔内压经典弹性平面力学问题解  相似文献   

微型氢化物发生装置在冷原子吸收分光光度法测汞中的应用     

赵延庆 《岩矿测试》2008,27(1):69-70

采用微型氢化物发生装置-冷原子吸收分光光度法测定了焊锡料及纽扣电池中的汞。在酸性介质中,用硼氢化钾将汞离子还原为汞原子,用载气将汞蒸气导入石英管,原子吸收分光光度计在波长253.7 nm处进行测定。选择了实验条件,对共存离子的干扰等进行了考察。方法的检出限为0.34 ng/mL,11次测定的相对标准偏差(RSD)小于6%,加标回收率为94.4%~104.7%。  相似文献   

汞对三角褐指藻生长影响的研究——汞与浮游植物相互作用(Ⅰ)     

吕小乔  孙秉一  史致丽 《中国海洋大学学报(自然科学版)》1990,(4)

采用连续培养技术研究汞对三角褐指藻生长的影响。当长时间接触含HgCl_2(范围5～25μg/dm~3)的培养介质中,得到结果表明,藻的生长速率随汞浓度增加而降低,细胞所排泄的有机物增加,对细胞中Chl-a的含量有一定程度影响,并抑制对硝酸盐和磷酸盐的吸收。在最初的2—4天中,汞对生物化学过程影响最大。  相似文献   

氮磷营养盐与有机汞联合作用对微氏海链藻生长的影响   总被引：1，自引：1，他引：1  

李顺兴  郑凤英  洪华生  王大志  黄立漳 《海洋科学》2005,29(10):36-39

探讨在高营养盐（氮、磷、硅分别为浮游植物生长的营养盐阚值≥40、50、9倍）条件下，氮浓度及氮磷摩尔比值[n（N）／n（P）]变化、汞（甲基汞和乙基汞）对微氏海链藻（Thalassiosira weissflogii）生长的影响。结果表明，高营养盐区海链藻的生长遵循营养盐限制的唯一因子论；氮浓度和氮磷比提高促进生长，当n（N）／n（P）=64则呈抑制效应；生长初期，甲基汞和乙基汞均产生毒性抑制作用，生长中后期，适量甲基汞（浓度≤1．0μg／L）、乙基汞（浓度≤0．5μg／L）却呈兴奋效应，促进生长；汞形态不同，剂量-效应关系不同。氮和有机汞是海链藻生长的刺激因子。适度有机汞污染与氮富营养化对微氏海链藻的生长产生协同效应。  相似文献   

汞元素的石油地质意义     

李广之  袁子艳  庄原  江浩 《物探与化探》2008,32(2):143-146,185

油气中都含有汞元素组分,汞的物理化学性质决定其可以从油气藏中向上垂向运移,根据采样介质类型及样品预处理的手段不同,地表中汞的分析方法可分为壤气、热释汞及土壤总汞分析方法。壤气汞、热释汞及土壤总汞指标都有着很好的示油气意义,同时也有着示断裂带的地质意义。  相似文献   

高温高压岩石流变仪的围压标定方法     

党嘉祥  周永胜  何昌荣  闫小兵 《地学前缘》2008,15(3):287-291

高温高压岩石流变仪围压标定的主要方法为氯化盐类的部分熔融法和矿物相变法。利用氯化盐类进行压力标定时,不仅可以利用单一盐类,也可以使用多种盐类的混合物;常用的压力标定矿物相变及其适用温压范围如下:石英-柯石英,500~1200℃、2.5~3.2GPa;钠长石-硬玉+石英,600~1200℃、1.6~3.2GPa;铁橄榄石+石英-铁辉石,600~1200℃、1~1.7GPa;磷镁石-Mg3(PO4)2-Ⅱ,565~825℃、0.6~0.9GPa;方解石-文石,600~1200℃、0.5~2.5GPa。不同的标定方法具有不同的特征,文中将进行详细介绍。  相似文献   

Integration of local–global upscaling and grid adaptivity for simulation of subsurface flow in heterogeneous formations     

M. Gerritsen  J. V. Lambers 《Computational Geosciences》2008,12(2):193-208

We propose a methodology, called multilevel local–global (MLLG) upscaling, for generating accurate upscaled models of permeabilities or transmissibilities for flow simulation on adapted grids in heterogeneous subsurface formations. The method generates an initial adapted grid based on the given fine-scale reservoir heterogeneity and potential flow paths. It then applies local–global (LG) upscaling for permeability or transmissibility [7], along with adaptivity, in an iterative manner. In each iteration of MLLG, the grid can be adapted where needed to reduce flow solver and upscaling errors. The adaptivity is controlled with a flow-based indicator. The iterative process is continued until consistency between the global solve on the adapted grid and the local solves is obtained. While each application of LG upscaling is also an iterative process, this inner iteration generally takes only one or two iterations to converge. Furthermore, the number of outer iterations is bounded above, and hence, the computational costs of this approach are low. We design a new flow-based weighting of transmissibility values in LG upscaling that significantly improves the accuracy of LG and MLLG over traditional local transmissibility calculations. For highly heterogeneous (e.g., channelized) systems, the integration of grid adaptivity and LG upscaling is shown to consistently provide more accurate coarse-scale models for global flow, relative to reference fine-scale results, than do existing upscaling techniques applied to uniform grids of similar densities. Another attractive property of the integration of upscaling and adaptivity is that process dependency is strongly reduced, that is, the approach computes accurate global flow results also for flows driven by boundary conditions different from the generic boundary conditions used to compute the upscaled parameters. The method is demonstrated on Cartesian cell-based anisotropic refinement (CCAR) grids, but it can be applied to other adaptation strategies for structured grids and extended to unstructured grids.  相似文献   

大别山榴辉岩一片麻岩杂岩的成因   总被引：2，自引：1，他引：1  

刘晓春 《地球化学》1994,(4)

大别山榴辉岩由辉长岩、大陆拉斑玄武岩和少量泥灰质经高压变质作用形成。大别地块可划分出四个形成条件不同的榴辉岩区,它们代表一种构造－岩石组合体。片麻岩杂岩中各种高压变质岩类的发现证明它们与榴辉岩一起经历了原地高压变质过程。二者变质作用Ｐ－Ｔ参数的差异归因于抬升过程中退变质反应速度的不同。不同地区榴辉岩退变质组合及Ｐ－Ｔ条件与围岩的一致性表明,大别杂岩现今所展示的“递增”变质带是由榴辉岩相退变质作用形成的。高压榴辉岩－片麻岩杂岩的产生是印支期扬子与华北两个大陆板块碰撞的结果。  相似文献