绿片岩-低角闪岩相变质条件下磁铁铁矿与黄铁矿间的Fe同位素分馏   总被引：3，自引：0，他引：3  

李志红  朱祥坤  唐索寒  李延河 《岩石矿物学杂志》2008,27(4):292-297

对辽宁省鞍山一本溪地区经历了绿片岩一低角闪岩相变质的新太古代条带状铁建造中磁铁矿和黄铁矿矿物对的Fe同位素分析结果显示:相对于标准IRMM-014,所有样品的磁铁矿和黄铁矿均显示Fe的重同位素富集;且黄铁矿的Fe同位素比值均大于磁铁矿的Fe同位素比值(ε57Fe黄铁矿ε57Fe磁铁矿),两种矿物的Fe同位素比值之差为△57Fe黄铁矿-磁铁矿=2.23～5.13.黄铁矿富集铁的重同位素表明矿物的Fe同位素组成并不代表其原始沉积的特征,而是在区域变质作用过程中Fe同位素发生了交换的结果.由同位素平衡判别图解可知,在绿片岩一低角闪岩相变质作用中,磁铁矿-黄铁矿间的Fe同位素基本达到了平衡,且在平衡条件下黄铁矿比磁铁矿更富集Fe的重同位素,二者之间的Fe同位素平衡分馏系数α黄铁矿-磁铁矿≈1.000 4‰±0.06‰(2σ).这一研究成果是对变质作用过程中Fe同位素的地球化学行为认识的重要进展.  相似文献   

河南省南召县梅子垛铁矿矿床成矿地质特征及矿石加工技术性能     

赖群生  江和中  樊中玲  杨士辉  李自民 《华南地质与矿产》2008,(2):15-19

2005～2007年,在河南省南召县白土岗-南河店-带发现数十个风化花岗闪长岩型超贫磁铁矿床。矿体的形态、产状、规模与花岗闪长岩体基本一致,矿石类型、成分简单,磁性铁品位2．79～13．28％,平均9．02％,矿石易采易选,在当前经济技术条件下,开采该类矿床具较好经济效益。笔者以梅子垛铁矿为例分析说明该类矿床成矿地质特征及矿石加工技术性能。  相似文献   

磁铁石英岩型铁矿岩芯光谱编录研究     

胥燕辉  田庆久 《国土资源遥感》2005,16(3):70-73

 对河北省昌黎县闫庄铁矿床的磁铁石英岩型铁矿石261件样品进行了光谱反射率测量，并与其铁含量进行了相关关系研究，目 的是对钻孔岩芯编录的新方法即高光谱岩芯编录在此类矿床中的可行性进行分析。研究结果表明，铁矿石反射率较低，一般为5%~20% ，铁离子的吸收峰主要表现在400~1 100 nm范围内，铁矿石中铁含量与850~900 nm的反射率均值呈现显著指数负相关关系，为高光谱 岩芯编录在此类矿床中的可行性提供了理论依据和技术途径。  相似文献   

安徽双河含柯石英硬玉石英岩中流体包裹体的研究   总被引：14，自引：1，他引：14       下载免费PDF全文

韩郁菁  张泽明 《地球科学》1997,22(3):322-326

在安徽双河含柯石英石玉石英岩中已识别出５类流体懈裹体，其中早期退变质阶段捕获的包裹体是均一温度低、含盐度较高的水溶包裹体，晚期捕获提均一温度较高、含盐底低的水溶流体包裹体，更晚期的是三相富含ＣＯ２包裹体及均一温度高的气－液两相富Ｃ炮裹体，为限定硬玉石英岩的隆升轨迹提供重要依据，在单相气体包裹体和三相富含Ｃ炮裹体中的气相成分为ＣＯ２和Ｎ２，氮可能来自外部或玉石英岩的原岩。  相似文献   

Characteristics and genesis of maghemite in Chinese loess and paleosols: Mechanism for magnetic susceptibility enhancement in paleosols   总被引：4，自引：0，他引：4  

Tianhu Chen  Huifang Xu  Qiaoqin Xie  Jun Chen  Junfeng Ji  Huayu Lu 《Earth and Planetary Science Letters》2005,240(3-4):790-802

Morphological characteristics and microstructures of magnetic minerals extracted from Chinese loess and paleosols were investigated using powder X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). Our results indicate that maghemite in loess–paleosol sequences was transformed from magnetite through oxidation of magnetite. Maghemite transformed from eolian magnetite during chemical weathering has low-angle grain boundaries among maghemite nano-crystals. Some nano-crystalline maghemites with nanoporous texture resulted from microbe-induced precipitation of magnetite or transformation of poorly crystalline ferric Fe (oxy)hydroxides in presence of Fe-reducing bacteria. Aggregates of euhedral maghemite nano-crystals were transformed from magnetite magnetosomes. Both microbe-induced nanoporous magnetite and microbe-produced magnetite magnetosomes are directly related to microbial activities and pedogenesis of the paleosols. It is proposed that the formation of nano-crystalline maghemite with superparamagnetic property in paleosol results in the enhancement of magnetic susceptibility, although the total amount (weight percent) of magnetic minerals in both paleosol and loess units is similar. Our results also show that nano-crystalline and nanoporous magnetite grains prefer to transform into maghemite in semi-arid soil environments instead of hematite, although hematite is a thermodynamically stable phase. This result also indicates that a decrease in crystal size will increase stability of maghemite. It is also inferred that surface energy of maghemite is lower than that of hematite.  相似文献   

Mineralogical changes during thermal demagnetization of natural continental sandstones     

C. Prezzi  R. Somoza  R. C. Mercader 《Studia Geophysica et Geodaetica》2005,49(2):213-232

We study the mineralogical changes suffered by specimens of natural miocene red and green continental sandstones (from Pozuelos Formation and Tiomayo Formation) cropping out in the Argentine Puna that increase their bulk magnetic susceptibility and change color when thermally treated. We hypothesize that on heating siderite, which is present in small quantities as cement in the studied sandstones, would oxidize and decompose into maghemite and/or magnetite. Subsequent heating to higher temperatures sometimes would bring about the conversion of maghemite and/or magnetite to hematite. Mössbauer spectroscopy proved to be a very valuable tool for the determination of the presence of siderite in small amounts in the studied samples. The present results show that further work is needed in order to fully understand the mineralogical changes suffered by continental sandstones during heating. The characterization of such changes occurred during laboratory routines is relevant, since they can help to better understand natural processes.  相似文献   

A magnetoclimatological investigation of Pampean loess, Argentina   总被引：3，自引：0，他引：3  

J. C. Bidegain  M. E. Evans  A. J. van Velzen 《Geophysical Journal International》2005,160(1):55-62

  相似文献   

Evolution of the Magma Chamber beneath Usu Volcano since 1663: a Natural Laboratory for Observing Changing Phenocryst Compositions and Textures   总被引：2，自引：1，他引：2  

TOMIYA  AKIHIKO; TAKAHASHI  EIICHI 《Journal of Petrology》2005,46(12):2395-2426

We have investigated the evolution of an active silicic magma-feedingsystem beneath Usu volcano, Japan, where eight eruptions havebeen recorded since AD 1663. All magmatic products contain similartypes of plagioclase and orthopyroxene phenocrysts that consistof homogeneous cores with uniform compositions, and a zonedmantle that increases in size with time. The compositions ofplagioclase and orthopyroxene phenocrysts vary gradually andregularly with time, as do the bulk-rock compositions. The textureof these phenocrysts also changes systematically, caused byprogressive crystal growth, dissolution and diffusion. On thebasis of these observations, we conclude that the same magma-feedingsystem has persisted at Usu volcano since AD 1663. Compositionalvariation of magnetite phenocrysts differs from that of plagioclaseand orthopyroxene, because magnetite has large diffusion coefficientsand should represent magmatic conditions immediately beforethe eruption. Most pumices from Usu volcano contain two typesof magnetite phenocryst, each with a different composition andcrystallization temperature, indicating that two magmas mixedbefore each eruption (approximately several days before). Theend-members changed with time: rhyolite + basaltic andesite(1663); dacite ± rhyolite (1769, 1822, 1853); dacite± dacite (1977, 2000). The temperature of the magma apparentlyincreases with time, and the increase can be explained by sequentialtapping from a magma chamber with a thermal and chemical gradientin addition to injection of high-temperature magma. KEY WORDS: continuous existence of magma chamber; dacite; dissolution and diffusion of phenocrysts; magma mixing; magnetite  相似文献   

深海嗜热异化铁还原菌Caloranaerobacter ferrireducens DY22619T对不同铁氧化物的铁还原特性   总被引：1，自引：0，他引：1  

李曦  曾湘  张昭  邵宗泽 《海洋学报》2016,38(8):83-92

异化铁还原微生物在铁元素的地球化学循环中具有重要意义。深海热液活动是大洋铁元素的重要来源,目前深海热液环境中铁代谢相关微生物研究很少。本文对一株分离自深海热液区的嗜热异化铁还原菌新种Caloranaerobacter ferrireducens DY22619T的铁还原特性进行分析,比较了该菌对无定形羟基氧化铁、无定形铁氧化物和针铁矿3种不同铁氧化物的铁还原速率;并利用透射电镜对矿化产物进行矿物形貌、组成元素和晶型的分析。研究发现该菌生长在指数期至稳定期时,铁还原速率最快,其中对无定形羟基氧化铁和无定形铁氧化物的还原速率较高,达2.82 μmol/h和2.15 μmol/h;透射电镜结果表明,该菌可将3种不同胞外铁氧化物均还原矿化形成颗粒状磁铁矿,由针铁矿矿化形成的磁铁矿少但粒径最大,而由无定形铁氧化物形成的磁铁矿晶面不同于另外两种铁氧化物。结果表明,该菌有很强的铁还原和矿化能力,能厌氧呼吸还原三价铁氧化物,但是铁氧化物的性质对该菌胞外铁还原能力和矿化形成的磁铁矿的性质有重要影响。本研究为认识深海热液环境中异化铁还原菌在铁元素的地球化学循环和生物成矿过程提供了参考。  相似文献   

Apatite Composition of Representative Magnetite‐series and Ilmenite‐series Granitoids in Japan          下载免费PDF全文

Shunso Ishihara  Takeru Moriyama 《Resource Geology》2016,66(1):55-62

Apatites of representative magnetite‐series and ilmenite‐series granitoids were studied in the Japanese Islands. Concentrations of the volatile components F, Cl and SO₃ are differently distributed in apatites of these granitoid series. Apatites are always fluoroapatite. They have weakly higher F content in the ilmenite series than in the magnetite series. In contrast, Cl and SO₃, are significantly concentrated in apatites of the magnetite series compared to the ilmenite series. These characteristics reflect the original concentrations of these components in the host granitic magmas. A high fO₂ seems most important for the S‐concentration as sulfate in apatite of the magnetite series. REE and Y are only erratically high in the studied apatites.  相似文献