平凉隐伏岩溶水环境同位素研究     

马致远  马蒂尔·亨德尔 《地球科学与环境学报》2003,25(4):60-66

地下水资源可持续利用的一个急待解决的重要问题,是对地下水补给和更新能力的评价.利用环境同位素技术研究地下水的补给和可更新性是当前较为新颖的方法之一.在西北干旱、半干旱的隐伏岩溶地区,地下水埋藏条件复杂,常规的地质勘探方法所能提供的水文地质信息有限,环境同位素方法在研究地下水的补给及可更新能力方面发挥了优势,可对传统方法进行补充和验证.其结果表明,研究区隐伏岩溶水形成较早,且有大量现代水的混入,平均混入量为54%.说明区内隐伏岩溶水的补给和更新能力较好.环境同位素分析结果还显示,大岔河隐伏岩溶水为一相对独立、半开放的水文地质单元,其补给来源部分为流域内大气降水、地表水的补给,部分为东南部三道沟岩溶地下水的补给;根据环境同位素EPM模型计算,地下水的滞留时间为36 a.地下水储存量为1.314×108 m3; 储水系数为7.29×10-3.这一结果与传统勘探方法的计算结果基本吻合,说明环境同位素方法的实用性.  相似文献   

APPLICATION OF MAP AND FILE INFORMATIONVISUALIZATION SYSTEM TO COMPREHENSIVEDIVISION OF NATURAL DISASTERS- Takingthe ChangjiangValleg as an Example     

HU Bao-qing    JIANG Mei-xin  JUN Su-lan  ZENG Qiao-song 《中国地理科学(英文版)》2001,(4)

In recent years，scholars at home and abroad have method，and that vanous disasters would be analyzed assynthetically studied natural dlsaste‘theoretically and an Integral．SHI Peilun（1991）putforwad a scientificmethodologlcally，as well as its cases analys。s（CND，term—regional disaster system，which Indicates that1987； MA et al，1990； MARBLE，1990； NE et al，the situation of a disaster（calamity loss）results from1999； PATAK et al，1982； SHI，1991；VAN et al，h…  相似文献   

陕西秦巴山区农业自然资源开发利用     

刘胤汉  陆立新 《山地学报》1990,(1)

农业自然资源据其在农业利用过程中的地位可分为两类:一类是生成农业自然资源的环境,另一类为可资直接利用的自然生成物(即狭义的农业自然资源)。陕西秦巴山区自然环境的主要特点是:复合山体高峻庞大,地跨暖温带和北亚热带,垂直分异明显。区内有:森林、草场、野生生物、林特产与农作物等多种农业自然资源。据此,提出了本区农业自然资源的开发利用途径。  相似文献   

Contribution of storms to groundwater recharge in the semi‐arid region of Karnataka,India     

K. Shivanna  U. P. Kulkarni  T. B. Joseph  S. V. Navada 《水文研究》2004,18(3):473-485

This paper describes the application of environmental isotopes and injected tracer techniques in estimating the contribution of storms as well as annual precipitation to groundwater recharge and its circulation, in the semi‐arid region of Bagepalli, Kolar district, Karnataka. Environmental isotopes ²H, ¹⁸O and ³H were used to study the effect of storms on the hydrological system, and an isotope balance was used to compute the contribution of a storm component to the groundwater. Some of the groundwater samples collected during the post‐storm periods were highly depleted in stable isotope content with higher deuterium excess relative to groundwater from the pre‐storm periods. Significant variation in deuterium excess in groundwater from the same area, collected in two different periods, indicates the different origin of air masses. The estimated recharge component of a storm event of 600 mm to the groundwater was found to be in the range of 117–165 mm. There was no significant variation in environmental tritium content of post‐storm and pre‐storm groundwater, indicating the fast circulation of groundwater in the system. After completion of the environmental isotope work, an injected radiotracer ³H technique was applied to estimate the direct recharge of total precipitation to the groundwater. The estimated recharge to the groundwater is 33 mm of the 550 mm annual precipitation during 1992. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

The solubility of iron sulphides in synthetic and natural waters at ambient temperature   总被引：1，自引：1，他引：0  

W. Davison 《Aquatic Sciences - Research Across Boundaries》1991,53(4):309-329

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.  相似文献   

Recharge source and hydrogeochemical evolution of shallow groundwater in a complex alluvial fan system,southwest of North China Plain   总被引：4，自引：0，他引：4  

Fadong Li  Guoying Pan  Changyuan Tang  Qiuying Zhang  Jingjie Yu 《Environmental Geology》2008,55(5):1109-1122

Many cities around the world are developed at alluvial fans. With economic and industrial development and increase in population, quality and quantity of groundwater are often damaged by over-exploitation in these areas. In order to realistically assess these groundwater resources and their sustainability, it is vital to understand the recharge sources and hydrogeochemical evolution of groundwater in alluvial fans. In March 2006, groundwater and surface water were sampled for major element analysis and stable isotope (oxygen-18 and deuterium) compositions in Xinxiang, which is located at a complex alluvial fan system composed of a mountainous area, Taihang Mt. alluvial fan and Yellow River alluvial fan. In the Taihang mountainous area, the groundwater was recharged by precipitation and was characterized by Ca–HCO₃ type water with depleted δ¹⁸O and δD (mean value of −8.8‰ δ¹⁸O). Along the flow path from the mountainous area to Taihang Mt. alluvial fan, the groundwater became geochemically complex (Ca–Na–Mg–HCO₃–Cl–SO₄ type), and heavier δ¹⁸O and δD were observed (around −8‰ δ¹⁸O). Before the surface water with mean δ¹⁸O of −8.7‰ recharged to groundwater, it underwent isotopic enrichment in Taihang Mt. alluvial fan. Chemical mixture and ion exchange are expected to be responsible for the chemical evolution of groundwater in Yellow River alluvial fan. Transferred water from the Yellow River is the main source of the groundwater in the Yellow River alluvial fan in the south of the study area, and stable isotopic compositions of the groundwater (mean value of −8.8‰ δ¹⁸O) were similar to those of transferred water (−8.9‰), increasing from the southern boundary of the study area to the distal end of the fan. The groundwater underwent chemical evolution from Ca–HCO₃, Na–HCO₃, to Na–SO₄. A conceptual model, integrating stiff diagrams, is used to describe the spatial variation of recharge sources, chemical evolution, and groundwater flow paths in the complex alluvial fan aquifer system.  相似文献   

Coupled and complex: Human-environment interaction in the Greater Yellowstone Ecosystem, USA     

David Bennett  David McGinnis 《Geoforum》2008,39(2):833-845

Complexity theory has received considerable attention over the past decade from a wide variety of disciplines. Some who write on this topic suggest that complexity theory will lead to a unifying understanding of complex phenomena; others dismiss it as a passing and disruptive fad. We suggest that for the analysis of coupled natural/human systems, the truth emerges from the middle ground. As an approach focused as much on the connections among system elements as the elements themselves, we argue that complexity theory provides a useful conceptual framework for the study of coupled natural/human systems. It is, if nothing else, a framework that leads us to ask interesting questions about, for example, sustainability, resilience, threshold events, and predictability.In this paper we attempt to demystify the ongoing discussions on complexity theory by linking its evocative and overloaded terminology to real-world processes. We illustrate how a shift in focus from system elements to connections among elements can lead to meaningful insight into human-environment interactions that might otherwise be overlooked. We ground our discussion in ongoing interdisciplinary research surrounding Yellowstone National Park’s northern elk winter range; a tightly coupled natural/human system that has been the center of debate, conflict, and compromise for more than 135 years.  相似文献   

运用3DEEMs及荧光偏振方法研究pH、离子强度及浓度效应对腐殖酸荧光光谱特性的影响   总被引：6，自引：0，他引：6  

梅毅  吴丰昌  王立英  白英臣 《地球化学》2008,37(2):165-173

利用三维荧光激发.发射光谱(3DEEMs)及荧光偏振法研究了3例腐殖酸和1例湖泊溶解有机物(DOM)在不同腐殖酸浓度、离子强度和pH条件下的荧光光谱特性.实验结果表明,随着浓度增大,各腐殖酸样的荧光强度增大,其中垃圾渗滤液腐殖酸和Pahokee泥炭腐殖酸的荧光峰出现红移.随着浓度进一步增大,腐殖酸的荧光偏振值增大,由此推断在此浓度范围内腐殖酸由于分子间的排斥作用使其构型出现伸展.离子强度增大导致腐殖酸及阿哈湖DOM的荧光强度降低.随着氯化钾(KCI)浓度增大,Fluka腐殖酸的荧光峰A蓝移,荧光峰B的荧光偏振值出现减小,推测是由于静电中和作用使其荧光基团发生卷曲造成的.离子强度对其余腐殖酸样和阿哈湖DOM的其他荧光特性没有明显的影响.总的来说,pH值的变化对腐殖酸和湖泊DOM的荧光特征的影响是很明显的.随着pH值增大,腐殖酸和湖泊DOM的荧光强度增强.而pH值减小时,Fluka腐殖酸和Pahokee泥炭腐殖酸的荧光峰(A峰)蓝移,当pH值降到5时,Fhka腐殖酸的荧光峰突然红移到最大,随后又继续蓝移;垃圾渗滤液腐殖酸和阿哈湖DOM的荧光峰位无明显的漂移.所有样品的荧光偏振值都减小(但阿哈湖DOM的A峰变化不大),但在pHi≤5时又增大,这种现象表明随着pH值降低,腐殖酸和湖泊DOM中有机大分子发生卷曲,但在pH≤5时由于羧基的质子化又以平面伸展构型出现在溶液中.  相似文献   

无机盐类对天然矿物低温催化混合酯生烃反应的影响   总被引：2，自引：0，他引：2  

刘会平  张在龙  籍志凯  李波 《沉积学报》2008,26(5):886-890

脂肪酸酯是一类重要的生烃母质。选择了十四烷酸甲酯、十六烷酸甲酯和十八烷酸甲酯的混合酯为模型反应物,以方解石、白云石、伊利石、钙蒙脱石和黄铁矿为催化剂,分别考察了氯化钾、氯化镁、氯化钠、硫酸钠以及混合盐对天然矿物低温催化混合酯生烃反应的影响。结果表明,无机盐类对矿物催化下混合酯的生烃反应均有不同程度的影响,硫酸钠具有反催化作用,其它盐类具有正催化作用。且在各无机盐存在下,不同的矿物表现出不同的催化活性。  相似文献   

从汶川地震看遥感技术在突发自然灾害中的应用     

许亚平 《贵州地质》2008,25(4)

现代遥感技术具有获取信息范围大、速度快,适应性强和信息量大等特点。"5.12"汶川地震后,交通堵塞、通信中断,遥感技术成为信息获取和灾害监测的重要手段。本文以遥感图像特征和遥感解译在汶川地震中的应用为例,阐述了遥感技术在突发自然灾害中的应用。  相似文献