Radiocarbon redating of contaminated samples from a tropical volcano: the Mansion ‘Series’ of St Kitts,West Indies     

D. D. Harkness  M. J. Roobol  A. L. Smith  J. J. Stipp  P. E. Baker 《Bulletin of Volcanology》1994,56(5):326-334

Heavy rainfall and dense vegetation on tropical volcanoes produce abundant carbonized wood in pyroclastic deposits, in addition to easy contamination of this wood by root systems and soluble humic material. Because the physical nature of the charcoal varies, some samples are more prone to contamination. Two independent studies of the same volcano, Mt Liamuiga on St Kitts in the Lesser Antilles, sometimes using samples from the same carbonized tree, yielded a systematic difference in radiocarbon ages. An exchange of samples and a re-investigation of three physically distinct types of charcoal yielded the following results. Rare, hard, dense charcoal, lacking contamination, which had yielded a spurious age of 2860 years bp, was redated at 1845±58 years bp. Common soft, friable charcoal with good cellular structure proved to be susceptible to contamination. A field decontamination technique utilized by one group seems significant as it yields older ages than when only routine laboratory pre-treatment was used, indicating that the latter technique only partly removes the dried and hard residue produced by the decomposition of modern plant rootlets. A previous date of 24870 years bp obtained from powdery charcoal in a horizon beneath the Mansion Series contradicted ages older than 41000 years bp from common friable charcoal in the lower Mansion Series. The soft powdery charcoal was re-investigated using a sample collected a few centimeters from the original, although field decontamination of this sample was not possible, more extensive laboratory treatment yielded an age of ca. 43000 years bp, again proving that routine laboratory pretreatments are inadequate. A revised geochronology for the Mansion Series is described and a cautionary discussion is presented for the benefit of investigators using radiocarbon ages to date volcanic deposits.  相似文献   

Formation of the mid-fifteenth century Kuwae caldera (Vanuatu) by an initial hydroclastic and subsequent ignimbritic eruption     

Claude Robin  Michel Monzier  Jean-Philippe Eissen 《Bulletin of Volcanology》1994,56(3):170-183

In the mid-fifteenth century, one of the largest eruptions of the last 10 000 years occurred in the Central New Hebrides arc, forming the Kuwae caldera (12x6 km). This eruption followed a late maar phase in the pre-caldera edifice, responsible for a series of alternating hydromagmatic deposits and airfall lapilli layers. Tuffs related to caldera formation ( 120 m of deposits on a composite section from the caldera wall) were emitted during two main ignimbritic phases associated with two additional hydromagmatic episodes. The lower hydromagmatic tuffs from the precaldera maar phase are mainly basaltic andesite in composition, but clasts show compositions ranging from 48 to 60% SiO₂. The unwelded and welded ashflow deposits from the ignimbritic phases and the associated intermediate and upper hydromagmatic deposits also show a wide compositional range (60–73% SiO₂), but are dominantly dacitic. This broad compositional range is thought to be due to crystal fractionation. The striking evolution from one eruptive style (hydromagmatic) to the other (magmatic with emission of a large volume of ignimbrites) which occurred either over the tuff series as a whole, or at the beginning of each ignimbritic phase, is the most impressive characteristic of the caldera-forming event. This strongly suggests triggering of the main eruptive phases by magma-water interaction. A three-step model of caldera formation is presented: (1) moderate hydromagmatic (sequences HD 1–4) and magmatic (fallout deposits) activity from a central vent, probably over a period of months or years, affected an area slightly wider than the present caldera. At the end of this stage, intense seismic activity and extrusion of differentiated magma outside the caldera area occurred; (2) unhomogenized dacite was released during a hydromagmatic episode (HD 5). This was immediately followed by two major pyroclastic flows (PFD 1 and 2). The vents spread and intense magma-water interaction at the beginning of this stage decreased rapidly as magma discharge increased. Subsequent collapse of the caldera probably commenced in the southeastern sector of the caldera; (3) dacitic welded tuffs were emplaced during a second main phase (WFD 1–5). At the beginning of this phase, magma-water interaction continued, producing typical hydromagmatic deposits (HD 6). Caldera collapse extended to the northern part of the caldera. Previous C¹⁴ dates and records of explosive volcanism in ice from the south Pole show that the climactic phase of this event occurred in 1452 A.D.  相似文献   

Analogue study of particle segregation in pyroclastic density currents, with implications for the emplacement mechanisms of large ignimbrites   总被引：3，自引：0，他引：3  

C. M. Choux  T. H. Druitt 《Sedimentology》2002,49(5):907-928

Abstract Analogue flume experiments were conducted to investigate the transport and sedimentation behaviour of turbulent pyroclastic density currents. The experimental currents were scaled approximately to the natural environment in three ways: (1) they were fully turbulent; (2) they had a very wide range of particle sizes and associated Rouse numbers (the ratio of particle settling velocity to effective turbulent eddy velocity in the current); and (3) they contained particles of two different densities. Two sets of surge‐type experiments were conducted in a 5 m long, water‐filled lock‐exchange flume at five different volumetric particle concentrations from 0·6% to 23%. In one set (one‐component experiments), the currents contained just dense particles; in the other set (two‐component experiments), they contained both light and dense particles in equal volume proportions. In both sets of experiments, the population of each component had a log‐normal size distribution. In the two‐component experiments, the size range of the light particle population was selected in order to be in hydrodynamic equivalence with that of the dense particles. Dense particles were normally graded, both vertically and downstream, in the deposits from both sets of experiments. The mass loading (normalized to the initial mass of the suspension) and grain size of the dense component in the deposits decreased with distance from the reservoir and were insensitive to initial total particle concentration in the currents. On the other hand, in the two‐component experiments, the light particles were extremely sensitive to concentration. They were deposited in hydrodynamic equivalence with the dense particles from dilute currents, but were segregated efficiently at concentrations higher than a few per cent. With increasing particle concentration, the large, light particles were carried progressively further down the flume because of buoyancy effects. Deposits from the high‐concentration currents exhibited reverse vertical grading of the large, light particles. Efficient segregation of the light component was observed even if the bulk density of the current was less than that of the light particles. In both sets of experiments, marked inflexions in the rate of downstream decline in mass loading and maximum grain size of the dense component can be attributed to the presence of two different particle settling regimes in the flow: (1) particles with Rouse numbers >2·5, which did not respond to the turbulence and settled rapidly; and (2) particles with Rouse numbers <2·5, which followed the turbulent eddies and settled slowly. The results are applied to the transport and sedimentation dynamics of pyroclastic density currents that generate large, widespread ignimbrites. Field data fail to reveal significant departures from aerodynamic equivalence between pumice and lithic clasts in three such ignimbrites: the particulate loads of some large ignimbrites are transported principally in turbulent suspensions of low concentration. In some ignimbrites, the well‐developed inflexions in curves of maximum lithic (ML) size vs. distance can be attributed to the existence of distinct high and low Rouse number particle settling regimes that mark the transition from an overcharged state to one in which the residual particulate load is transported more effectively by turbulence.  相似文献   

Three types of pyroclastic currents and their deposits: examples from the Vulsini Volcanoes, Italy     

Danilo M. Palladino  Silvia Simei 《Journal of Volcanology and Geothermal Research》2002,116(1-2)

This paper deals with ground-hugging, gas–pyroclast currents from explosive volcanic eruptions and their deposits. Key field observations and laboratory determinations are proposed to relate specific deposit types with flow regimes and particle concentration in the transport and depositional systems. Three relevant flow scenarios and corresponding deposit types have been recognized from a survey of pyroclastic successions of the Vulsini Volcanic District (central Italy): (1) dilute, turbulent, pyroclastic currents producing normally or multiply graded beds by direct suspension sedimentation; (2) concentrated bedload regions beneath suspension currents, depositing inversely graded beds by traction carpet sedimentation; (3) self-sustained, high particle concentration, laminar, mass flows developing massive, poorly sorted bodies, with opposite grading of coarse lithic and pumice clasts, overlying fine-grained, inversely graded, basal layers. Main distinguishing criteria include the occurrence and pattern of clast grading, clast–thickness relationships, grain size, ash matrix componentry and pyroclast size–density relationships. Downcurrent and temporal transitions among identified flow scenarios are likely to occur for changing energy conditions and gas–pyroclast ratio both on regional and local scales. The nature and efficiency of magma fragmentation, volatile content, conduit geometry (which determine the characteristics of the erupted mixture and possible lateral blast component at the vent), and the angle of incidence of the column collapse, are suggested as the main factors controlling the generation of one type over the other at flow inception. Dilute, fine-grained, overpressured eruption clouds are thought to favor the formation of low particle concentration turbulent currents. Column collapse over slightly inclined volcano slopes, causing a high degree of compression of the collapsing mixture and of gas expulsion, would favor the generation of high particle concentration pyroclastic currents.  相似文献   

Reconciling pyroclastic flow and surge: the multiphase physics of pyroclastic density currents     

Alain Burgisser  George W. Bergantz 《Earth and Planetary Science Letters》2002,202(2):405-418

Two end-member types of pyroclastic density current are commonly recognized: pyroclastic surges are dilute currents in which particles are carried in turbulent suspension and pyroclastic flows are highly concentrated flows. We provide scaling relations that unify these end-members and derive a segregation mechanism into basal concentrated flow and overriding dilute cloud based on the Stokes number (S_T), the stability factor (Σ_T) and the dense-dilute condition (D_D). We recognize five types of particle behaviors within a fluid eddy as a function of S_T and Σ_T: (1) particles sediment from the eddy, (2) particles are preferentially settled out during the downward motion of the eddy, but can be carried during its upward motion, (3) particles concentrate on the periphery of the eddy, (4) particles settling can be delayed or ‘fast-tracked’ as a function of the eddy spatial distribution, and (5) particles remain homogeneously distributed within the eddy. We extend these concepts to a fully turbulent flow by using a prototype of kinetic energy distribution within a full eddy spectrum and demonstrate that the presence of different particle sizes leads to the density stratification of the current. This stratification may favor particle interactions in the basal part of the flow and D_D determines whether the flow is dense or dilute. Using only intrinsic characteristics of the current, our model explains the discontinuous features between pyroclastic flows and surges while conserving the concept of a continuous spectrum of density currents.  相似文献   

Deep submarine pyroclastic eruptions: theory and predicted landforms and deposits   总被引：1，自引：0，他引：1  

James W. Head  III  Lionel Wilson   《Journal of Volcanology and Geothermal Research》2003,121(3-4):155-193

Submarine pyroclastic eruptions at depths greater than a few hundred meters are generally considered to be rare or absent because the pressure of the overlying water column is sufficient to suppress juvenile gas exsolution so that magmatic disruption and pyroclastic activity do not occur. Consideration of detailed models of the ascent and eruption of magma in a range of sea floor environments shows, however, that significant pyroclastic activity can occur even at depths in excess of 3000 m. In order to document and illustrate the full range of submarine eruption styles, we model several possible scenarios for the ascent and eruption of magma feeding submarine eruptions: (1) no gas exsolution; (2) gas exsolution but no magma disruption; (3) gas exsolution, magma disruption, and hawaiian-style fountaining; (4) volatile content builds up in the magma reservoir leading to hawaiian eruptions resulting from foam collapse; (5) magma volatile content insufficient to cause fragmentation normally but low rise speed results in strombolian activity; and (6) volatile content builds up in the top of a dike leading to vulcanian eruptions. We also examine the role of bulk-interaction steam explosivity and contact-surface steam explosivity as processes contributing to volcaniclastic formation in these environments. We concur with most earlier workers that for magma compositions typical of spreading centers and their vicinities, the most likely circumstance is the quiet effusion of magma with minor gas exsolution, and the production of somewhat vesicular pillow lavas or sheet flows, depending on effusion rate. The amounts by which magma would overshoot the vent in these types of eruptions would be insufficient to cause any magma disruption. The most likely mechanism of production of pyroclastic deposits in this environment is strombolian activity, due to the localized concentration of volatiles in magma that has a low rise rate; magmatic gas collects by bubble coalescence, and ascends in large isolated bubbles which disrupt the magma surface in the vent, producing localized blocks, bombs, and pyroclastic deposits. Another possible mode of occurrence of pyroclastic deposits results from vulcanian eruptions; these deposits, being characterized by the dominance of angular blocks of country rocks deposited in the vicinity of a crater, should be easily distinguishable from strombolian and hawaiian eruptions. However, we stress that a special case of the hawaiian eruption style is likely to occur in the submarine environment if magmatic gas buildup occurs in a magma reservoir by the upward drift of gas bubbles. In this case, a layer of foam will build up at the top of the reservoir in a sufficient concentration to exceed the volatile content necessary for disruption and hawaiian-style activity; the deposits and landforms are predicted to be somewhat different from those of a typical primary magmatic volatile-induced hawaiian eruption. Specifically, typical pyroclast sizes might be smaller; fountain heights may exceed those expected for the purely magmatic hawaiian case; cooling of descending pyroclasts would be more efficient, leading to different types of proximal deposits; and runout distances for density flows would be greater, potentially leading to submarine pyroclastic deposits surrounding vents out to distances of tens of meters to a kilometer. In addition, flows emerging after the evacuation of the foam layer would tend to be very depleted in volatiles, and thus extremely poor in vesicles relative to typical flows associated with hawaiian-style eruptions in the primary magmatic gas case. We examine several cases of reported submarine volcaniclastic deposits found at depths as great as 3000 m and conclude that submarine hawaiian and strombolian eruptions are much more common than previously suspected at mid-ocean ridges. Furthermore, the latter stages of development of volcanic edifices (seamounts) formed in submarine environments are excellent candidates for a wide range of submarine pyroclastic activity due not just to the effects of decreasing water depth, but also to: (1) the presence of a summit magma reservoir, which favors the buildup of magmatic foams (enhancing hawaiian-style activity) and episodic dike emplacement (which favors strombolian-style eruptions); and (2) the common occurrence of alkalic basalts, the CO₂ contents of which favor submarine explosive eruptions at depths greater than tholeiitic basalts. These models and predictions can be tested with future sampling and analysis programs and we provide a checklist of key observations to help distinguish among the eruption styles.  相似文献   

Rainfall induced debris flows in pyroclastic deposits, Campania (southern Italy)   总被引：12，自引：0，他引：12  

Francesco Fiorillo  Raymond C. Wilson   《Engineering Geology》2004,75(3-4):263-289

A combination of empirical and physically based hydrological models has been used to analyze historical data on rainfall and debris-flow occurrence in western Campania, to examine the correlation between rainfall and debris-flow events.

Rainfall data from major storms recorded in recent decades in western Campania were compiled, including daily series from several rain gauges located inside landslide areas, supplemented by hourly rainfall data from some of the principal storms.

A two-phase approach is proposed. During phase 1, soil moisture levels have been modelled as the hydrological balance between precipitation and evapotranspiration, on a daily scale, using the method of Thornthwaite [Geograph. Rev. 38 (1948) 55].

Phase 2 is related to the accumulation of surplus moisture from intense rainfall, leading to the development of positive pore pressures. These interactions take place on an hourly time scale by the “leaky barrel” (LB) model described by Wilson and Wiezoreck [Env. Eng. Geoscience, 1 (1995) 11]. In combination with hourly rainfall records, the LB model has been used to compare hydrological effects of different storms. The critical level of retained rain water has been fixed by the timing of debris-flow activity, related to recorded storm events.

New rainfall intensity–duration thresholds for debris-flow initiation in western Campania are proposed. These thresholds are related to individual rain gauge and assume a previously satisfied field capacity condition. The new thresholds are somewhat higher than those plotted by previous authors, but are thought to be more accurate and thus need less conservatism.  相似文献   

Inviscid behaviour of fines-rich pyroclastic flows inferred from experiments on gas-particle mixtures     

O. Roche  M.A. Gilbertson  R.S.J. Sparks 《Earth and Planetary Science Letters》2005,240(2):401-414

Experiments were carried out on granular flows generated by instantaneous release of gas-fluidised, bidisperse mixtures and propagating into a horizontal channel. The mixture consists of fine (< 100 μm) and coarse (> 100 μm) particles of same density, with corresponding grain size ratios of ∼ 2 to 9. Initial fluidisation of the mixture destroys the interparticle frictional contacts, and the flow behaviour then depends on the initial bed packing and on the timescale required to re-establish strong frictional contacts. At a fines mass fraction (α) below that of optimal packing (∼ 40%), the initial mixtures consist of a continuous network of coarse particles with fines in interstitial voids. Strong frictional contacts between the coarse particles are probably rapidly re-established and the flows steadily decelerate. Some internal friction reduction appears to occur as α and the grain size ratio increases, possibly due to particle rolling and the lower roughness of internal shear surfaces. Segregation only occurs at large grain size ratio due to dynamical sieving with fines concentrated at the flow base. In contrast, at α above that for optimal packing, the initial mixtures consist of coarse particles embedded in a matrix of fines. Flow velocities and run-outs are similar to that of the monodisperse fine end-member, thus showing that the coarse particles are transported passively within the matrix whatever their amount and grain size are. These flows propagate at constant height and velocity as inviscid fluid gravity currents, thus suggesting negligible interparticle friction. We have determined a Froude number of 2.61 ± 0.08 consistent with the dam-break model for fluid flows, and with no significant variation as a function of α, the grain size ratio, and the initial bed expansion. Very little segregation occurs, which suggests low intensity particle interactions during flow propagation and that active fluidisation is not taking place. Strong frictional contacts are only re-established in the final stages of emplacement and stop the flow motion. We infer that fines-rich (i.e. matrix-supported) pyroclastic flows propagate as inviscid fluid gravity currents for most of their emplacement, and this is consistent with some field data.  相似文献   

Recognition features of felsic pyroclastics of Serra do Tombo formation,Minas Gerais,Brazil     

《Journal of South American Earth Sciences》2016

In this contribution we report a study of poorly exposed, rhyodacitic welded-ignimbrite deposit from Minas Gerais. A petrographic study of textures indicate high temperature of emplacement. Key features include eutaxitic texture, flattened and agglutinated lapilli and glass menisci. Most of the feldspar minerals and glass are extensively altered to clay minerals, which pseudomorph the original volcanic textures. Glass menisci and spherules suggest a possible process of liquid immiscibility. Immobile trace element distribution indicates a possible link with other post-Palaeozoic felsic volcanic rocks in Brazil, a magmatism interpreted as due to basaltic underplating and partial melting of a hydrous continental crust. A peculiar feature is a high Light REE/Heavy REE ratio. Depletion in heavy rare earth elements is possibly due to a residual HREE-bearing phase in the source. The geologic context of these rocks suggests a Lower Cretaceous age and a tectonic relationship with a continental rifting event.  相似文献   

二叠系火山碎屑岩气藏天然气地球化学特征及气源分析——以四川盆地成都—简阳地区永探1井为例     

田兴旺  罗冰  孙奕婷  刘冉  李亚  陈延贵  周春林  汪华  李亚丁  王尉  王云龙  杨岱林 《吉林大学学报(地球科学版)》2021,51(2):325-335

2018年12月底,在四川盆地二叠系火山岩发育地区部署的风险探井永探1井测试获得22.5万m³/d的高产工业气流,实现了二叠系火山碎屑岩的重大勘探突破,展现了火山碎屑岩气藏的巨大勘探潜力。本文根据该钻井成果资料,应用分析化验数据,采用不同地区气-气对比方法,开展了成都—简阳地区天然气地球化学特征分析、源-储接触关系解剖及气源综合对比。在此基础上,对二叠系火山碎屑岩气藏天然气成因进行了鉴别,对天然气来源进行了判识。结果表明：永探1井火山岩气藏天然气均为典型的干气,干燥系数达0.997,CH₄质量分数高,平均为99.03%,C₂H₆质量分数低,平均为0.35%,C₃H₈几乎没有,不含H₂S;天然气甲烷、乙烷碳同位素值均较轻,甲烷碳同位素平均值为-32.17‰,乙烷碳同位素平均值为-34.27‰,且岩心及镜下可见大量残余沥青,天然气成因鉴别分析表明永探1井火山岩气藏天然气为原油二次裂解气;通过源-储接触关系解剖以及天然气甲烷、乙烷碳同位素对比分析,表明永探1井火山碎屑岩气藏天然气主要来源于德阳—安岳台内裂陷内发育的巨厚下寒武统筇竹寺组优质烃源岩,部分来源于中二叠统。  相似文献