排序方式： 共有26条查询结果，搜索用时 312 毫秒
1.
Root‐related rhodochrosite and concretionary siderite formation in oxygen‐deficient conditions induced by a ground‐water table rise 
下载免费PDF全文
下载免费PDF全文 Maciej J. Bojanowski Elżbieta Jaroszewicz Adrijan Košir Maciej Łoziński Leszek Marynowski Anna Wysocka Arkadiusz Derkowski 《Sedimentology》2016,63(3):523-551
Sedimentological, mineralogical, stable carbon and oxygen isotope determinations and biomarker analyses were performed on siderite concretions occurring in terrestrial silts to understand their formation and to characterize the sedimentary and diagenetic conditions favouring their growth. High δ13C values (6·4‰ on average) indicate that siderite precipitated in an anoxic environment where bacterial methanogenesis operated. The development of anoxic conditions during shallow burial was induced by a change in sedimentary environment from flood plain to swamp, related to a rise of the ground‐water table. Large amounts of decaying plant debris led to efficient oxygen consumption within the pore‐water in the peat. Oxygen depletion, in combination with a decrease in sedimentation rate, promoted anoxic diagenetic conditions under the swamp and favoured abundant siderite precipitation. This shows how a change in sedimentary conditions can have a profound impact on the early‐diagenetic environment and carbonate authigenesis. The concretions contain numerous rhizoliths; they are cemented with calcium‐rhodochrosite, a feature which has not been reported before. The rhodochrosite cement has negative δ13C values (?16·5‰ on average) and precipitated in suboxic conditions due to microbial degradation of roots coupled to manganese reduction. The exceptional preservation of the epidermis/exodermis and xylem vessels of former root tissues indicates that the rhodochrosite formed shortly after the death of a root in water‐logged sediments. Rhodochrosite precipitated during the initial stages of concretionary growth in suboxic microenvironments within roots, while siderite cementation occurred simultaneously around them in anoxic conditions. These suboxic microenvironments developed because oxygen was transported from the overlying oxygenated soil into sediments saturated with anoxic water via roots acting as permeable conduits. This model explains how separate generations of carbonate cements having different mineralogy and isotopic compositions, which would conventionally be regarded as cements precipitated sequentially in different diagenetic zones during gradual burial, can form simultaneously in shallow burial settings where strong redox gradients exist around vertically oriented permeable root structures. 相似文献
2.
民乐锰矿生物矿物学特征初步研究 总被引：2，自引：0，他引：2
民乐锰矿矿石中发现蓝藻化石六、七种,其中石囊藻细胞(Eontophysalis)和色球藻目(chroocacean)中的矿物质为钙、镁、锰的碳酸盐系列矿物。本文综合了偏光显微镜、生物显微镜、电子显微镜及X射线衍射分析,无机、有机化学分析资料,找到了蓝藻与碳酸锰矿物的密切空间关系和成生联系。引用了关于生物成矿的观点,论述本区生物形成矿物的作用过程和相关的矿物种类。提出菱锰矿形成的生物—生物化学成因的观点。 相似文献
3.
主乌鲁克锰矿床位于西昆仑北缘晚古生代陆缘裂谷恰尔隆弧盆系的北部,含锰层位为下石炭统他龙群细碎屑岩夹碳酸盐岩,锰矿层为黑色泥质碳质页岩夹铁锰质泥晶灰岩。锰矿体严格受地层的控制,呈NWW向展布,延伸较为稳定,规模较大,共见有13条锰矿体,其中有3个矿体较大构成主矿体;锰矿石以原生菱锰矿为主体,氧化矿石不多。该矿床与近年发现的玛尔坎苏地区锰矿床既有相似之处,又有明显不同,矿床类型为在深海-半深海陆缘裂谷环境中形成的与黑色碳质页岩有关的沉积型锰矿床,锰矿的成矿时代为早石炭世。由于下石炭统他龙群是西昆仑地区新发现的含锰层位,具有较大的找矿潜力,应加强矿床外围及深部的找矿工作。 相似文献
4.
Coupling between metallogenesis of the Cryogenian Datangpo-type manganese deposit in South China and major geological events 下载免费PDF全文
下载免费PDF全文 Yu Wen-Chao Du Yuan-Sheng Zhou Qi Wang Ping Qi Liang Xu Yuan Jin Song Pan Wen Yuan Liang-Jun Xie Xiao-Feng Yang Bing-Nan 《古地理学报》1999,22(5):855-871
The exploration of the Cryogenian manganese deposits in the Datangpo Formation of South China has achieved great progress in recent years. It is concern in the long term there are many studies on this manganese deposits due to its particularity in the temporal and spatial distribution and the mineralization background. In this paper,we systematically summarize the previous achievements on the Datangpo-type manganese deposits. Besides,we also review current findings of Neoproterozoic global geotectonics,palaeoclimate evolution,ancient marine chemistry,and microbial evolution etc. The possible linkage between the massive metallogenesis of the Cryogenian Datangpo manganese deposits in the South China and Neoproterozoic major geological events is established. The break-up of Rodinia supercontinent led to the widespread rift basin systems in the world since the Middle Neoproterozoic. The Nanhua Basin in South China,which is a manganese-forming sedimentary basin,developed from the rift basin. The rift basin provided space for manganese deposits and controlled the distribution of manganese deposit. The hydrothermal activities at the bottom of the basin provided favorable manganese source. During the Neoproterozoic ice period(“Snowball Earth”event),global ice-sheets cut off or hindered exchanges of mass and energy between different spheres of Earth,which may lead to the widespread anoxic condition in the ice age ocean. The palaeoclimate changes during the glacial-interglacial period led to the disappearance of ice-sheets and the triggering of mass and energy exchanges between different sub-systems of Earth,followed by the variation of redox condition of the ancient sea. For the Nanhua Basin,the oxidation of surface water and the oxygen-bearing base flow provided the oxidation environment for the precipitation of manganese. Besides,new evidence indicated that manganese microbiological mineralization was the potential mechanism for manganese deposit under the microbial resuscitation condition during the interglacial period. All these major geological events have complicated connections and they provided essential metallogenic conditions for the sedimentary mineralization of “Datangpo”manganese deposit. It is believed that there is a coupling between the sedimentary metallogenesis of the Cryogenian Datangpo-type manganese deposit in South China and Neoproterozoic major geological events. 相似文献
5.
穆呼锰矿床位于西昆仑造山带玛尔坎苏锰矿带东段,研究程度相对薄弱。穆呼锰矿床的含矿地层为上石炭统喀拉阿特河组,自下而上可分为角砾灰岩、钙质杂砂岩和含炭质泥灰岩3个岩性段,具有完整的海侵层序特征,反映了由逐步断陷到稳定沉积的盆地演化过程。锰矿层赋存于第三岩性段炭质泥灰岩中,矿石矿物主要为化学组分纯净的泥晶菱锰矿。根据详细的矿相学观察并综合前人研究成果,笔者认为菱锰矿是初始沉淀的锰（氢）氧化物与有机质通过成岩反应形成的。这种成矿机制需要3个基本条件：丰富的锰质来源、氧化还原分层的海水和有机质的大量埋藏。在穆呼一带,有利于满足以上条件的主要控矿因素包括：伸展拉张的构造背景、强烈的海底热液活动、海侵事件和温暖潮湿的古气候。笔者根据w（Ba）-w（P2O5）图解并结合区域对比分析,初步认为穆呼锰矿床的成矿模式可能属于最小含氧量带扩张型。 相似文献
6.
重庆高燕地区菱锰矿热水沉积成因地球化学证据 总被引：1，自引：0，他引：1
重庆高燕锰矿床位于晚震旦世秦巴成锰沉积盆地,主要赋存于陡山沱组顶部,以鲕粒或球粒状产出.为了查明其成因,在收集该区锰矿相关成果的基础上,对ZK129-3#、ZK115-7#、ZK127-7#、ZK133-7#、ZK115-11#五个钻孔的陡山沱组鲕状菱锰矿进行系统采样,并测试了包括Mn、Fe、P、SiO2、CaO、MgO、Al2O3和LOI在内的8个地球化学指标,进而运用指相元素地球化学分析了Mn/Al、（MgO/Al2O3）×102、Al/（Al+Fe+Mn）和SiO2/Al2O3比值.结果表明：重庆高燕菱锰矿受陆源物质的影响很小,与海洋沉积有关,主要是海洋自生产物;Al/（Al+Fe+Mn）和SiO2/Al2O3值则指示其沉积过程中有热水参与,是热水沉积的产物. 相似文献
7.
A. N. Derkachev N. A. Nikolaeva A. V. Mozherovsky T. N. Grigor’eva E. D. Ivanova S. P. Pletnev N. N. Barinov V. M. Chubarov 《Russian Journal of Pacific Geology》2007,1(3):203-229
This paper reports specific mineralogical and geochemical characteristics of deposits from the local depressions of the Derugin Basin. They were formed in an environment with periodic changes from oxic to anoxic conditions and show evidence for the presence of hydrogen sulfide in bottom waters. The deposits of this type can be considered as a modern model for ancient ore-bearing black shale associations. Compared with typical metalliferous black shale sequences, which are characterized by high contents of organic matter, the sediments described here are depleted in the elements of the organophilic association (Mo, Ni, Cu, Zn, V, and U) but have higher Mn contents. 相似文献
8.
We studied calcite and rhodochrosite from exploratory drill cores (TH‐4 and TH‐6) near the Toyoha deposit, southwestern Hokkaido, Japan, from the aspect of stable isotope geochemistry, together with measuring the homogenization temperatures of fluid inclusions. The alteration observed in the drill cores is classified into four zones: ore mineralized zone, mixed‐layer minerals zone, kaolin minerals zone, and propylitic zone. Calcite is widespread in all the zones except for the kaolin minerals zone. The occurrence of rhodochrosite is restricted in the ore mineralized zone associated with Fe, Mn‐rich chlorite and sulfides, the mineral assemblage of which is basically equivalent to that in the Toyoha veins. The measured δ18OSMOW and δ13CPDB values of calcite scatter in the relatively narrow ranges from ?2 to 5‰ and from ?9 to ?5‰, respectively; those of rhodochrosite from 3 to 9‰ and from ?9 to ?5‰, excluding some data with large deviations. The variation of the isotopic compositions with temperature and depth could be explained by a mixing process between a heated surface meteoric water (100°C δ18O =?12‰, δ13C =?10‰) and a deep high temperature water (300°C, δ18O =?5‰, δ13C =?4‰). Boiling was less effective in isotopic fractionation than that of mixing. The plots of δ18O and δ13C indicate that the carbonates precipitated from H2CO3‐dominated fluids under the conditions of pH = 6–7 and T = 200–300°C. The sequential precipitation from calcite to rhodochrosite in a vein brought about the disequilibrium isotopic fractionation between the two minerals. The hydrothermal fluids circulated during the precipitation of carbonates in TH‐4 and TH‐6 are similar in origin to the ore‐forming fluids pertaining to the formation of veins in the Toyoha deposit. 相似文献
9.
10.
藏南扎西康Sb-Pb-Zn-Ag矿床Sm-Nd、Rb-Sr成矿年龄 总被引：1，自引：0，他引：1
由于成矿作用的多期性与复杂性,如何精确获取铅锌矿床成矿年龄一直是成矿年代学研究的难点之一。近年来,随着矿物提纯技术及分析测试手段不断完善,基于Sm-Nd及Rb-Sr体系测定热液矿物年龄逐渐成为一种有效的定年方法。通过测定西藏南部扎西康超大型Sb-Pb-Zn-Ag矿床中热液成因菱锰矿Sm-Nd与黄铁矿Rb-Sr同位素组成,获得菱锰矿和黄铁矿对应等时线年龄分别为(99.1±0.9)Ma和(98.0±1.8)Ma,记录了一次重要的热液成矿事件。此外,菱锰矿初始143Nd/144Nd值在0.512 301～0.512 849之间,经99 Ma球粒陨石CHUR计算出εNd值在-6.573 84～4.115 965之间,黄铁矿87Sr/86Sr值在0.714 021～0.719 708之间。这2种矿物均具有盆地流体同位素组成特征。结合前人对成矿物质和成矿流体特征的研究,笔者认为:扎西康矿床主成矿期形成于印度板块向北偏移过程中产生的张性构造系中,矿床属于盆地构造环境控制的铅锌矿床。 相似文献