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LIU Xiangwen YANG Guangming ZOU Huamin QU Jing & ZHAO Wenxia . Graduate School China University of Geosciences Wuhan China . Test Center China University of Geosciences Wuhan China . Physics Technology College Wuhan University Wuhan China . Test Center Zhongshan University Guangzhou China 《中国科学D辑(英文版)》2004,47(3)
Sakhaite was first discovered by Ostrovskaya, Pertsev and Nikitina at Siberia in the former Soviet Union. By using the X-ray diffraction technique, they proved that the crystal system of sakhaite was cubic (a = 1.464 nm), its possible space groups were Fm3m, F432, F43m, Fm3, F23, and its crystal chemical for-mula was Ca48Mg16(CO3)16(BO3)28Cl4(OH)8 4H2O[1]. Chichagov, Simonov and Belov studied the crystal structure of synthetic sakhaite and determined that its space group was F4132, … 相似文献
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本文对萨碳硼镁钙石(sakhaite)Ca_(48)Mg_(16)(BO_3)_(28)(CO_3)_(16)(Cl,F)_6(OH)_6·nH_2O的晶体结构进行了重新测定,求得晶胞参数:a=b=c=1.46151(9)nm。晶胞体积:V=3.1218(3)nm~3。单位晶胞中分子数Z=1,空间群为Fd3。结构测定的精度偏离因子R=0.0504。根据矿物化学成分及晶体结构特征,与前人报道的萨碳硼镁钙石及其人工合成矿物晶体结构特征进行了对比,指出本次测定的矿物与前人报道的天然萨碳硼镁钙石或人工合成矿物在矿物成分与结构上的差异,据此,讨论了我国产出的“萨碳硼镁钙石”有待重新命名的必要性。 相似文献
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