Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo)   总被引：1，自引：1，他引：0  

Ph. Muchez  P. Vanderhaeghen  H. El Desouky  J. Schneider  A. Boyce  S. Dewaele  J. Cailteux 《Mineralium Deposita》2008,43(5):575-589

The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz, whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction (BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation of H₂S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity (8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. ⁸⁷Sr/⁸⁶Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium isotopic composition of Neoproterozoic marine carbonates (⁸⁷Sr/⁸⁶Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement. The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite, V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR.  相似文献   

The sandstone-hosted stratiform copper mineralization at Mwitapile and its relation to the mineralization at Lufukwe, Lufilian foreland, Democratic Republic of Congo   总被引：2，自引：0，他引：2  

Hamdy A. El Desouky  Philippe Muchez  Roger Tyler 《Ore Geology Reviews》2008,34(4):561-579

The Lufilian foreland is a triangular-shaped area located in the SE of the Democratic Republic of Congo and to the NE of the Lufilian arc, which hosts the well-known Central African Copperbelt. The Lufilian foreland recently became an interesting area with several vein-type (e.g., Dikulushi) and stratiform (e.g., Lufukwe and Mwitapile) copper occurrences. The Lufilian foreland stratiform Cu mineralization is, to date, observed in sandstone rock units belonging to the Nguba and Kundelungu Groups (Katanga Supergroup).The Mwitapile sandstone-hosted stratiform Cu prospect is located in the north eastern part of the Lufilian foreland. The host rock for the Cu mineralization is the Sonta Sandstone of the Ngule Subgroup (Kundelungu Group). A combined remote sensing, petrographic and fluid inclusion microthermometric analysis was performed at Mwitapile and compared with similar analysis previously carried out at Lufukwe to present a metallogenic model for the Mwitapile- and Lufukwe-type stratiform copper deposits. Interpretation of ETM+ satellite images for the Mwitapile prospect and the surrounding areas indicate the absence of NE–SW or ENE–WSW faults, similar to those observed controlling the mineralization at Lufukwe. Faults with these orientations are, however, present to the NW, W, SW and E of the Mwitapile prospect. At Mwitapile, the Sonta Sandstone host rock is intensely compacted, arkosic to calcareous with high silica cementation (first generation of authigenic quartz overgrowths). In the Sonta Sandstone, feldspar and calcite are present in disseminated, banded and nodular forms. Intense dissolution of these minerals caused the presence of disseminated rectangular, pipe-like and nodular dissolution cavities. Sulfide mineralization is mainly concentrated in these cavities. The hypogene sulfide minerals consist of two generations of pyrite, chalcopyrite, bornite and chalcocite, separated by a second generation of authigenic quartz overgrowth. The hypogene sulfide minerals are replaced by supergene digenite and covellite. Fluid inclusion microthermometry on the first authigenic quartz phase indicates silica precipitation from an H₂O–NaCl–CaCl₂ fluid with a minimum temperature between 111 and 182 °C and a salinity between 22.0 and 25.5 wt.% CaCl₂ equiv. Microthermometry on the second authigenic quartz overgrowths and in secondary trails related to the mineralization indicate that the mineralizing fluid is characterized by variable temperatures (Th = 120 to 280 °C) and salinities (2.4 to 19.8 wt.% NaCl equiv.) and by a general trend of increasing temperatures with increasing salinities.Comparison between Mwitapile and Lufukwe indicates that the stratiform Cu mineralization in the two deposits is controlled by similar sedimentary, diagenetic and structural factors and likely formed from a similar mineralizing fluid. A post-orogenic timing is proposed for the mineralization in both deposits. The main mineralization controlling factors are grain size, clay and pyrobitumen content, the amount and degree of feldspar and/or calcite dissolution and the presence of NE–SW to ENE–WSW faults. The data support a post-orogenic fluid-mixing model for the Mwitapile- and Lufukwe-type sandstone-hosted stratiform Cu deposits, in which the mineralization is related to the mixing between a Cu-rich hydrothermal fluid, with a temperature up to 280 °C and a maximum salinity of 19.8 wt.% NaCl equiv., with a colder low salinity reducing fluid present in the sandstone host rock. The mineralizing fluid likely migrated upwards to the sandstone source rocks along NE–SW to ENE–WSW orientated faults. At Lufukwe, the highest copper grades at surface outcrops and boreholes were found along and near to these faults. At Mwitapile, where such faults are 2 to 3 km away, the Cu grades are much lower than at Lufukwe. Copper precipitation was possibly promoted by reduction from pre-existing hydrocarbons and non-copper sulfides and by the decrease in fluid salinity and temperature during mixing. Based on this research, new Cu prospects were proposed at Lufukwe and Mwitapile and a set of recommendations for further Cu exploration in the Lufilian foreland is presented.  相似文献   

Chemistry and Sulfur Isotopes in a Chert-dominant Sequence around the Stratiform Manganese Deposit of the Noda-Tamagawa Mine, Northern Kitakami Terrane, Northeast Japan: Implication for Paleoceanographic Environmental Setting     

Kosei Komuro    Katsuyuki Yamaguchi  Yoshimichi Kajiwara 《Resource Geology》2005,55(4):337-351

Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ³⁴S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ³⁴S values in the lower bedded chert, and an upward‐increasing trend in δ³⁴S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.  相似文献   

Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography     

Kosei Komuro  Koji Wakita 《Resource Geology》2005,55(4):321-336

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.  相似文献   

四川盆地云和降水观测科学试验设计与实践     

范思睿  王维佳 《气象科技》2019,47(2):191-200

2014—2017年四川地区开展了大范围云系观测科学试验。观测对象以盆地层状云系和积层混合云系为主,积状云(对流云)为辅。本文围绕试验目标、区域、观测要素、观测布局设计、观测方案设计、设备技术参数和典型个例等7个方面进行介绍,根据不同类型云系和降水变化特征,设计有针对性的观测方案,获得了不同类型云系和降水的多尺度连续性观测数据,为四川地区开展云和降水关系研究提供详实的综合型外场观测数据。层状降水云典型个例云高可达8km,云强核心部位的云雷达反射率可达28dBz,径向速度可达-6m·s~(-1),在0℃附近,反射率和退偏振因子LDR上有一条明显的亮带,表现为极大值,液态水主要集中于4.5km以下,随着雨强增大,液水含量增加,降水滴谱分布较窄,随着雨强减小,雨滴谱和速度谱变窄,但小粒径数浓度增加,说明对层状云雨强起主导作用的是雨滴直径,而不是数浓度;无降水层状云典型个例云层厚度为3.2km,云顶约为4km,云雷达反射率不超过0dBz,径向速度不超过5m·s~(-1),层状云内整层水汽含量和液水含量较为稳定,云中主要为液态粒子且粒径偏小、小粒径数浓度较高。  相似文献   

一次层状云降雨过程多源遥感特征参量演变分析     

杨文霞  范皓  杨洋  赵利伟 《气象》2019,45(9):1278-1287

利用河北省邢台市皇寺国家观测站布设的Ka波段云雷达、微波辐射计和微雨雷达以及地面雨量计等观测资料,对2017年5月3日一次西南涡天气过程的降水云系进行了综合分析,结果表明:本次降水过程为稳定性层状云过程,云内粒子下落速度由高空向地面逐渐增大,第一轮降水出现在云的发展阶段,第二轮降水出现在云的成熟阶段,每次降水开始前云内的相对湿度、水汽含量、液态水含量和温度曲线同时出现跃增和峰值,各指标在降水结束后出现较明显下降,之后得到恢复,出现第二三次峰值并产生降水;利用微波辐射计资料在时间和空间上连续反演计算云中水汽压和冰面饱和水汽压差值场("e—E_i"差值场),当云中过冷水和过冷水汽大值区与"e—E_i"差值场的正值区重合时,冷云中贝吉龙过程较强,有利于精细化定量判断强降水出现和人工增雨潜力区位置,综合以上遥感探测资料分析结果,可以认为本次天气过程有利的人工增雨作业时机出现两次,第一次在13:45降水刚刚开始至云顶下降到6 km前;第二次时间较长,云层条件更为有利,即17:40—21:15云顶高度维持在8~10 km的时段;作业适宜高度为4~8 km(-20~0℃)。  相似文献   

河北春季一次飞机人工增雪的综合分析   总被引：1，自引：0，他引：1  

李宝东  孙玉稳  孙霞  刘伟  韩洋  蒋元华 《干旱气象》2014,(5):819-829

2013年4月19日,河北省人工影响天气办公室在河北中南部地区根据云系特点首次采用多层次水平催化和垂直验证的方式对层状云进行人工催化和探测。本文利用机载仪器所取得的飞机探测资料,结合实时天气、卫星、雷达、探空和雨量观测资料,分析了河北春季层状云增雪作业的技术指标,探讨了航测微物理参量和卫星、雷达、探空等资料在作业中的应用。结果表明：云在发展期雷达回波由15 dBZ逐步上升到25-35 dBZ,卫星反演的云顶高度、云顶温度、有效粒子半径、光学厚度等都有增加;云在中后期有效粒子半径、光学厚度、液水路径迅速下降,雷达回波同时减弱。在高度3 177-5 723 m之间过冷云滴达100-700个/cm^3,含水量在0.01 g·m^-3左右,最大0.081 g·m^-3,云粒子主要在此增长,形成降水粒子,该区间适宜催化。作业后,影响区内云体发展,雷达回波增强,出现35 dBZ强回波,且强回波中心扩大;卫星反演的云顶高度、光学厚度等比对比区有明显增加。  相似文献   

一次冷锋云系的宏微观物理特征分析     

孟宪罗  汤达章  郭金平  裴宇杰  赵娜  秦彦硕  段宇辉  赵利品 《南京气象学院学报》2014,6(6):539-548

利用常规气象资料、自动站资料、卫星云图、CINRAD-SA多普勒天气雷达资料以及NCEP再分析资料,结合飞行探测数据,对影响2011年4月17日河北抚宁县森林大火的一次冷锋云系进行分析.结果表明:1)宏观分析,过程降水的水汽仅来自冷锋自身所携带的微弱水汽,水汽辐合值较小,不利降水;2)微观分析,冷锋层状云系在水平和垂直方向上存在较薄的过冷水云区,小粒子数浓度大于20 cm^-3的云区占一定比例.飞机催化作业后,雷达回波强度增强,CAS(云气溶胶粒子探头)探测的小粒子数浓度、云含水量及粒子平均直径均有明显变化,说明该次冷锋云系有一定的增雨潜力.  相似文献   

Surface rainfall and cloud budgets associated with mei-yu torrential rainfall over eastern China during June 2011     

ZHAI Guoqing  LI Xiaofan  ZHU Peijun  SHEN Hangfeng  ZHANG Yuanzhi 《大气科学进展》2014,31(6):1435-1444

Surface rainfall and cloud budgets associated with three heavy rainfall events that occurred over eastern China during the mei-yu season in June 2011 were analyzed using 2D cumulus ensemble model simulation data.Model domain mean rainfall showed three peaks in response to three prescribed ascending motion maxima,primarily through the mean moisture convergence during the torrential rainfall period.Prescribed ascending motion throughout the troposphere produced strong convective rainfall during the first （9 June） and third （17-18 June） rainfall events,whereas strong prescribed ascending motion in the mid and upper troposphere and weak subsidence near the surface generated equally important stratiform and convective rainfall during the second rainfall event （14 June）.The analysis of surface rainfall budgets reveals that convective rainfall was associated with atmospheric drying during the first event and moisture convergence during the third event.Both stratiform and convective rainfall responded primarily to moisture convergence during the second event.An analysis of grid data shows that the first and third mean rainfall maxima had smaller horizontal scales of the precipitation system than the second.  相似文献   

山西地区一次层状云降水过程的微观特征观测分析     

封秋娟  李培仁  丁建芳  申东东  晋立军 《南京气象学院学报》2013,(5):537-545

针对山西省2010年5月27日一次层状云降水过程,利用机载DMT探头和Parsivel激光降水粒子谱仪进行探测试验,分析了云微物理特征,并对空中和地面雨滴谱进行比较。结果显示：空中云垂直和水平结构分布不均匀,CDP、CIP探测最大粒子浓度分别为165．20、1．08cm^（-3）。地面雨滴微物理量的平均值说明本次降水是典型的层状云降水,雨强主要由雨滴数密度决定,雨滴微物理参量随时间分布不均匀。建立地面雨强,与雷达反射率因子Z、雨水含量W、雨滴数浓度N、Gamma分布的谱参数眠、A的相关关系,Z-I、W-I,相关性很好,N-I、N_0-I、λ-I,相关性较差。地面平均雨滴谱较空中平均雨滴谱窄、谱型陡。结合粒子图像和雨滴特征量分析空中雨滴谱随高度的分布发现,本次降水是冷云和暖云降水共存。  相似文献