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Ricardo Arevalo Jr William F. McDonough Philip M. Piccoli 《Geostandards and Geoanalytical Research》2011,35(2):253-273
An in situ, medium‐resolution LA‐ICP‐MS method was developed to measure the abundances of the first‐row transition metals, Ga and Ge in a suite of geological materials, namely the MPI‐DING reference glasses. The analytical protocol established here hinged on maximising the ablation rate of the ultraviolet (UV) laser system and the sensitivity of the ICP‐MS, as well minimising the production of diatomic oxides and argides, which serve as the dominant sources of isobaric interferences. Non‐spectral matrix effects were accounted for by using multiple external calibrators, including NIST SRM 610 and the USGS basaltic glasses BHVO‐2G, BIR‐1G and BCR‐2G, and utilising 43Ca as an internal standard. Analyses of the MPI‐DING reference glasses, which represent geological matrices ranging from basaltic to rhyolitic in composition, included measurements of concentrations as low as < 100 μg g?1 and as high as > 104 μg g?1. The new data reported here were found to statistically correlate with the ‘preferred’ reference values for these materials at the 95% confidence level, though with significantly better precision, typically on the order of ≤ 3% (2sm). This analytical method may be extended to any matrix‐matched geological sample, particularly oceanic basalts, silicate minerals and meteoritic materials. 相似文献
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Sébastien Castelltort Stéphane Pochat Jean Van den Driessche 《Comptes Rendus Geoscience》2004,336(2):151-158
High-frequency stratigraphic cycles (10 s to 100 s ka) often show, at a specific location, an alternation of ‘dynamic’ (proximal-energetic), and ‘non-dynamic’ (distal-pelagic) processes with time. When sedimentation is syn-deformation, these processes tend respectively to fill-up tectonically-induced topography or to drape it. As a consequence, growth strata are alternatively thickened and isopach across the growth structure. High-resolution kinematic studies of growth structures (folds and faults), which assume that sedimentation always fills up topographies (‘fill-to-the-top’ model), may therefore mistake sedimentary cyclicity for tectonic cyclicity. We address this problem with one example of growth anticline in the Spanish Pyrenees, and we discuss the fill-to-the-top model. To cite this article: S. Castelltort et al., C. R. Geoscience 336 (2004). 相似文献
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Impacts of the dumping site on the environment: Case of the Henchir El Yahoudia Site, Tunis, Tunisia
The Henchir El Yahoudia landfill is one among many uncontrolled dumping sites in Tunisia with no bottom liner. It is located at the southeastern edge of Sijoumi Sebkha. The site has been exploited since 1963 until 1994. It constitutes a peculiar case because of its situation, its exploitation mode and the nature of buried wastes. Leachate analysis shows that they are strongly charged with nitrogen (especially ammoniacal and kadjedahl), organic compounds with a high biodegradability and a charge of metallic elements exceeding the Tunisian norm NT 106-002. Sediment analyses show that the highest rate of heavy metals and organic matter coincides with clay-richest layers, characterized by the highest specific-surface values. The percolation of these pollutants until the groundwater between 0.5 and 5 m has provoked a pollution characterized by high rates of organic matter (BOD, COD and nitrogen) and heavy metals. To cite this article: A. Marzougui, A. Ben Mammou, C. R. Geoscience 338 (2006). 相似文献
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《水文科学杂志》2013,58(6)
Abstract The hydrological data (since 1953) of the Llanganuco basin (87.0 km2, 39% glacierized) show an increase of the glacial melting during the last quarter of the 20th century. These results were supplemented (since the end of 2000) by the data of the small basin of Artesoncocha (8.4 km2, 79% glacierized). The basin runoff is well correlated to the atmospheric temperature derived from the NOAA-NCEP re-analysis above the Cordillera Blanca. At the monthly time scale, the temperature is a good proxy of the glacier melting. The retreat of several glaciers in the Cordillera Blanca has been well documented for 50 years, highlighting an acceleration of the deglaciation in the mid-1970s. The use of these data of various origins permits one to model the behaviour of glaciers, especially the meltwater production, and then to predict their future evolution. The model was calibrated over the 1950–2000 period, thus providing a possible optimistic evolution range (underestimation if the climate change becomes more intense). The forcing of the model by forecasts of the future temperature evolution above the Cordillera Blanca, derived from the regionalization of global climatic models, allows improvement of the estimations only based on past glacial behaviour. 相似文献
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《水文科学杂志》2013,58(5)
Abstract Abstract The water storage capacity (WSC) of dehiscent fruits that constitute a portion of litter on the forest floor is inadequately understood. This study has quantified the WSC of empty fruiting heads of sweetgum (Liquidambar styraciflua L.) in an effort to reduce the data gap on the WSC and interception of fruit litter. In a laboratory experiment, empty fruiting heads of sweetgum were found to have a mean WSC of 399% of their oven-dried weight. The maximum volume of water detained by fruiting heads in the field was 507 ml container-1. Interception by the empty fruiting heads is considerable, ranging from 2.6 to 218.5% of the incident gross precipitation, with a mean of 42.7%. The data indicate that the interception storage capacity of empty fruiting heads is reached at 2.5 cm depth equivalent of incident gross precipitation. A logarithmic relationship was observed between the volume of water detained by the fruiting heads and the length of time since precipitation. Results of the study suggest that fruit litter may have a considerable influence on the seasonal water balance and ecohydrology of plantations and forests with significant proportions of sweetgum. 相似文献
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David R. Montgomery 《Comptes Rendus Geoscience》2003,335(16):1121
Functional relationships between erosion rates and topography are central to understanding controls on global sediment flux and interactions among tectonics, climate, and erosion in shaping topography. Based on such relations digital elevation models (DEMs) allow predicting landscape-scale erosion rates to the degree that process models can be calibrated and to the extent that such processes reflect elevation, drainage area, and aspect, or their derivatives such as slope and curvature. Digital elevation models allow investigating the influence of erosional processes on landscape form and evolution through generalized quantitative expressions often referred to as ‘erosion laws’. The analytical forms of such expressions are derived from physical principles, but only limited data are available to guide calibration to particular landscapes. In addition, few studies have addressed how different transport laws interact to set landscape-scale erosion rates in different environments. Conventionally, landscape-scale sediment flux is considered to be linearly related to slope or relief, but recent analyses point toward non-linear relations for steep terrain in which changes in the frequency of landsliding accommodate increased rates of rock uplift. In such situations, landscape-scale erosion rates are more closely tied to erosion potential predicted by models of bedrock river incision. Consequently, I propose that using DEMs to predict absolute or relative erosion rates at the landscape-scale counter-intuitively involves the rate of fluvial processes as governing the sediment flux from steep landscapes, and rates of hillslope processes as governing sediment flux from low-gradient landscapes. To cite this article: D.R. Montgomery, C. R. Geoscience 335 (2003). 相似文献
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The mattes resulting from lead smelting have been studied in order to determine the distribution of heavy metals and metalloids in primary phases. The chemical analysis (EPMA) revealed the presence of various metals (Pb, Sb, Cu), sulphides (galena, wurtzite, pyrrhotite, bornite, digenite, cubanite), arsenides (koutekite, löllingite) and other complex intermetallic compounds. Extreme saturation of the initial matte melt in heavy metals and metalloids as well as a relatively rapid cooling regime are responsible for numerous elemental substitutions in the crystal structures of all the involved phases. To cite this article: V. Ettler, Z. Johan, C. R. Geoscience 335 (2003). 相似文献
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Guillaume Pierre 《Geodinamica Acta》2013,26(1):45-54
RésuméLa question de la capture de la Meuse lorraine est abordée par le biais de l’étude des sables tertiaires qui jalonnent les plateaux de l’Ardenne méridionale. Toujours polygéniques, ces sables ont une histoire plus ou moins longue qui débute à l’Éocène où l’altération poussée du socle produit un épais manteau sableux. Certains gisements in situ fossilisés sont restés quasiment intacts (Régniowez) tandis que d’autres (Doisches) portent la marque de remaniements successifs (marins et/ou continentaux) qui se suivent jusqu’au Miocène sans que leur filiation avec le matériau d’origine, attestée par la nature de leurs barylites, ne se perde. Comme les sables fluviatiles miocènes (in fine) du plateau ardennais ne portent pas la signature minéralogique d’une Meuse lorraine, à l’inverse de la Traînée mosane (datée du Miocène moyen), la capture se trouve à la fois confirmée et datée. L’ancien réseau de la Meuse lorraine, quant à lui, n’a pu se mettre en place qu’après l’Oligocène, époque à laquelle un glacis incliné de l’Ardenne vers le Bassin parisien fonctionnait encore. © 2000 Éditions scientifiques et médicales Elsevier SAS 相似文献
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This work compares the quantities of labile metals removed from the Vire River (Normandy) sediments by a sequential extraction procedure to those liberated by single leaches (Mg(NO3)2, HCl and EDTA). Compared to the other extractions, Mg(NO3)2 underestimated the mobility results. The sequential procedure was the most aggressive, except for Ca and Pb. The hypothetic correlation between quantities of an element removed by single leaches and its fractionation in the sediment according to the sequential procedure was not satisfying. Finally, it should be underlined that enrichments of Cd, Pb and Zn were noticed in the Vire sediments. To cite this article: L. Leleyter, F. Baraud, C. R. Geoscience 337 (2005). 相似文献
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