The range of effects of azimuthal isotropy and EDA anisotropy in sedimentary basins   总被引：4，自引：0，他引：4  

Philip Wild  Stuart Crampin 《Geophysical Journal International》1991,107(3):513-529

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Prediction of lateral variability in fracture intensity using multicomponent shear-wave surface seismic as a precursor to horizontal drilling in the Austin Chalk   总被引：1，自引：0，他引：1  

Michael C. Mueller 《Geophysical Journal International》1991,107(3):409-415

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Micro-XANES mapping of sulphur and its association with magnesium and phosphorus in the shell of the brachiopod, Terebratulina retusa     

Maggie Cusack  Yannicke Dauphin  Jean-Pierre Cuif  Murielle Salom  Andy Freer  Huabing Yin 《Chemical Geology》2008,253(3-4):172-179

Biominerals are natural composite materials comprising organic and inorganic components. Detailed knowledge of the nature and distribution of both components is a crucial requirement in order to advance our understanding of biomineral formation, their material properties and preservation potential as well as the interpretation of environmental data. Detailed chemical data are essential for our understanding of the nature and distribution of such components. Micro-XANES mapping at the sulphur K-edge reveals that, in the brachiopod Terebratulina retusa, the sulphate concentration is higher in the outer (primary) layer than in the calcite fibres of the secondary layer. This is co-incident with a higher magnesium concentration. In contrast, the sheaths surrounding the calcite fibres contain sulphur as thiol, confirming the presence of protein while, the sulphur within the fibres themselves, occurs as sulphate. Micro-XANES analysis of the insoluble organic extract from T. retusa indicates the presence of organic sulphate while Micro-Raman spectroscopy confirms that structurally substituted sulphate (SSS) is also present although semi-quantitative Raman spectroscopy carried out in this spectral region (wavenumbers 900–1200) indicates that the sulphate present is at the threshold of detection by Raman spectroscopy. The distribution of phosphorus in the shell of T. retusa correlates well with that of protein indicating the presence of phosphorylated proteins in the periostracum, the sheaths surrounding the calcite fibres and the interface between the primary and secondary layer.  相似文献   

An Atomic Force Microscopy study of the growth of calcite in the presence of sodium sulfate   总被引：1，自引：0，他引：1  

Aikaterini I. Vavouraki  Christine V. Putnis  Andrew Putnis  Petros G. Koutsoukos   《Chemical Geology》2008,253(3-4):243-251

In situ atomic force microscopy (AFM) has been used to compare the growth of pure calcite and the growth of calcite in the presence of sulfate ions from aqueous solutions at a constant value of supersaturation (S.I. = 0.89) with respect to calcite. The effect of sulfate ions on calcite growth rates is determined and a potential incorporation of sulfate ions is identified in the calcite during growth. Solutions supersaturated with respect to calcite with solution concentration ratio of one and a constant pH of 10.2, were prepared and sulfate was added as Na₂SO₄ aqueous solution. The solution composition was readjusted in order to keep the supersaturation and pH constant. PHREEQC was used to determine relevant solution concentrations. In situ AFM experiments of calcite growth were performed using a fluid cell and flowing solutions passed over a freshly cleaved calcite surface. Growth rates were determined from the closure of the rhombohedral etch pits induced by initial dissolution with pure water. The spreading rate of 2-dimensional nuclei was also measured. At low concentrations of sulfate (≤ 0.5 mM), no effect on the growth rate of the calcite was observed. At higher concentrations (2 to 3 mM) of sulfate, the growth rate increased, possibly because a higher concentration of calcium and carbonate was necessary to maintain the supersaturation constant. At much higher concentrations of additional sulfate (up to 60 mM) the growth rate of the calcite was substantially decreased, despite the fact that a further increase of calcium and carbonate was required. The morphology of 2-dimensional growth nuclei became increasingly elongated with increasing sulfate content. Measurements of step height showed that newly grown steps were approximately 1 Å higher when grown in high sulfate concentrations, compared to steps grown in sulfate-free solutions. At sulfate concentrations above 5 mM the growth mechanism changes from layer growth to surface roughening. These observations suggest that the new growth has incorporated sulfate into the calcite surface.  相似文献   

Proximate Constituents, Biomass, and Energy in Posidonia oceanica (Potamogetonaceae)     

J. M. Lawrence  Ch.-F. Boudouresque  F. Maggiore 《Marine Ecology》1989,10(3):263-270

Abstract. The proximate composition of the various components of Posidonia oceanica is given in terms of gravimetric and energetic level and amount of plants from 2 depths at Port-Cros (Var. France). The level of proximate constituents differed little between the leaves (regardless of age) and the roots, but the rhizome contained much more soluble carbohydrate and less structural carbohydrate and ash. Because of this, the energy level in the leaves was more in terms of organic material and less in terms of total material than the energy level in the rhizome. The leaves of a P. oceanica shoot at 2 m depth in July contained 1.6 g organic material. 29.0 kJ. The weight and energy of the soluble carbohydrate in the rhizome from the base of the leaves to the 18th sheath scale decreased by ca. 40% from October to March and increased by ca. 100% from March to July.  相似文献   

成都经济区天降水与下渗水元素地球化学特征及土壤元素输入输出通量   总被引：2，自引：0，他引：2  

刘东盛  杨忠芳  夏学齐  侯青叶  余涛 《地学前缘》2008,15(5):74

论文研究了成都经济区天降水和下渗水中元素含量、在农田耕层中的输入输出通量及其影响因素.研究表明,研究区雨水中含有大量SO2-4、NO-3等酸性物质,雨水中SO2-4 >NO-3>Cl-.雨水中Ca2 和NH 4含量最高,且NH 4>Ca2 >K >Na >Mg2 .雨水的pH与阴、阳离子摩尔浓度差值具有显著相关性.下渗水中以Ca2 为主要阳离子,且Ca2 >Na >Mg2 >K >NH 4;HCO-3为主要阴离子,且HCO-3>NO-3>SO2-4>Cl->F-,下渗水pH与阳、阴离子摩尔浓度差值具有显著相关性.不同地区雨水中Pb>As>Cd>Se>Hg,下渗水中Pb>As>Se>Cd>Hg,因此,Cd、Pb、Se和Hg等元素累积在耕层中,而As则被下渗水携带迁移出耕层进入地下水.由降雨输入土壤中的Cd通量均大于下渗水输出Cd的通量,局部地区As下渗通量高于雨水输入通量的5.45～13.16倍.土壤中元素的下渗比与土壤质地、pH有关.  相似文献   

An overview of focuses of research on otolith element characteristics and general testing methods     

GAO Yong-Hua LI Qing-Rong LIN Dong-Ni JIAO Chi FENG Qiang-Ling 《地学前缘》2008,15(6):11

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Microfabrics of calcite ultramylonites as records of coaxial and non-coaxial deformation kinematics: Examples from the Rocher de l'Yret shear zone (Western Alps)     

Ghislain Trullenque  Karsten Kunze  Renee Heilbronner  Holger Stünitz  Stefan M. Schmid 《Tectonophysics》2006,424(1-2):69-97

Microfabrics were analysed in calcite mylonites from the rim of the Pelvoux massif (Western Alps, France). WNW-directed emplacement of the internal Penninic units onto the Dauphinois domain produced intense deformation of an Eocene-age nummulitic limestone under lower anchizone metamorphic conditions (slightly below 300 °C). Two types of microfabrics developed primarily by dislocation creep accompanied by dynamic recrystallisation in the absence of twinning. Coaxial kinematics are inferred for samples exhibiting grain shape fabrics and textures with orthorhombic symmetry. Their texture (crystallographic preferred orientation, CPO) is characterised by two c-axis maxima, symmetrically oriented at 15° from the normal to the macroscopic foliation. Non-coaxial deformation is evident in samples with monoclinic shape fabrics and textures characterised by a single oblique c-axis maximum tilted with the sense of shear by about 15°. From the analysis of suitably oriented slip systems for the main texture components under given kinematics it is inferred that the orthorhombic textures, which developed in coaxial kinematics, favour activity of <10–11> and <02–21> slip along the f and r planes, respectively, with minor contributions of basal-<a> slip. In contrast, the monoclinic textures, which developed during simple shear, are most suited for duplex <a> slip along the basal plane. The transition between the dominating slip systems for the orthorhombic and monoclinic microfabrics is interpreted to be due to the effects of dynamic recrystallisation upon texture development. Since oblique c-axis maxima documented in the literature are most often rotated not with but against the shear sense, calcite textures alone should not be used as unequivocal shear sense indicators, but need to be complemented by microstructural criteria such as shape preferred orientations, grain size estimates and amount of twinning.  相似文献   

Diagenesis and fracturing of Paleocene–Eocene carbonate turbidite systems in the Ionian Basin: The example of the Kelçyra area (Albania)     

Nadge Vilasi  Rudy Swennen  Franois Roure 《Journal of Geochemical Exploration》2006,89(1-3):409

The Kelçyra area is emplaced in a foreland fold-and-thrust belt (FFTB), characterized by a westward thrusting with the Triassic evaporites as the major décollement level. Several secondary features related with this evolution, like backthrusting, folding, duplex structures, evaporite diapirism are present. During the FFTB evolution, the study area has been subjected to several fracturing events with associated stages of fluid migration. During the pre-deformational stage, complex textures such as crack-and-seal features most likely reflect expulsion of overpressured fluids. These fluids were dominantly host-rock buffered. Within the post-deformational stage, a meteoric fluid caused cementation and development of a karst network during a period of emergence after the thrust emplacement. Subsequently, Mg calcite reprecipitated in the more stable carbonate phase calcite and dolomite, which filled part of the karts network. The latter is finally dedolomitized and locally partially dissolved by a second meteoric fluid flow, which greatly increased the secondary porosity.  相似文献   

Fe and Mn in calcites cementing red beds: A record of oxidation–reduction conditions: Examples from the Catalan Coastal Ranges (NE Spain)     

D. Parcerisa  D. Gmez-Gras  A. Trav  J.D. Martín-Martín  E. Maestro 《Journal of Geochemical Exploration》2006,89(1-3):318

Fe and Mn occur in calcite cements depending on the oxidizing–reducing conditions of cementing waters, which may change according to depositional and diagenetic environments. In red beds, Mn and Fe are available from the ferruginous matrix. Thus, it is possible to know the oxidizing–reducing conditions of fluids that precipitated calcite as a function of Mn and Fe content in calcite cement. A detailed petrological (with special attention to cathodoluminescence) and geochemical analysis of these cements is a useful tool to constrain the diagenetic evolution of red beds and the history of the basin where they deposited.  相似文献