Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Detailed <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of geologic events associated with the Mantos Blancos copper deposit,northern Chile     

Verónica Oliveros  Gilbert Féraud  Luis Aguirre  Luis Ramírez  Michel Fornari  Carlos Palacios  Miguel Parada 《Mineralium Deposita》2008,43(3):281-293

The ⁴⁰Ar/³⁹Ar geochronological method was applied to date magmatic and hydrothermal alteration events in the Mantos Blancos mining district in the Coastal Cordillera of northern Chile, allowing the distinction of two separate mineralization events. The Late Jurassic Mantos Blancos orebody, hosted in Jurassic volcanic rocks, is a magmatic-hydrothermal breccia-style Cu deposit. Two superimposed mineralization events have been recently proposed. The first event is accompanied by a phyllic hydrothermal alteration affecting a rhyolitic dome. The second mineralization event is related to the intrusion of bimodal stocks and sills inside the deposit. Because of the superposition of several magmatic and hydrothermal events, the obtained ⁴⁰Ar/³⁹Ar age data are complex; however, with a careful interpretation of the age spectra, it is possible to detect complex histories of successive emplacement, alteration, mineralization, and thermal resetting. The extrusion of Jurassic basic to intermediate volcanic rocks of the La Negra Formation is dated at 156.3 ± 1.4 Ma (2σ) using plagioclase from an andesitic lava flow. The first mineralization event and associated phyllic alteration affecting the rhyolitic dome occurred around 155–156 Ma. A younger bimodal intrusive event, supposed to be equivalent to the bimodal stock and sill system inside the deposit, is probably responsible for the second mineralization event dated at ca. 142 Ma. Other low-temperature alteration events have been dated on sericitized plagioclase at ca. 145–146, 125, and 101 Ma. This is the first time that two distinct mineralization events have been documented from radiometric data for a copper deposit in the metallogenic belt of the Coastal Cordillera of northern Chile. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

The sandstone-hosted stratiform copper mineralization at Mwitapile and its relation to the mineralization at Lufukwe, Lufilian foreland, Democratic Republic of Congo   总被引：2，自引：0，他引：2  

Hamdy A. El Desouky  Philippe Muchez  Roger Tyler 《Ore Geology Reviews》2008,34(4):561-579

The Lufilian foreland is a triangular-shaped area located in the SE of the Democratic Republic of Congo and to the NE of the Lufilian arc, which hosts the well-known Central African Copperbelt. The Lufilian foreland recently became an interesting area with several vein-type (e.g., Dikulushi) and stratiform (e.g., Lufukwe and Mwitapile) copper occurrences. The Lufilian foreland stratiform Cu mineralization is, to date, observed in sandstone rock units belonging to the Nguba and Kundelungu Groups (Katanga Supergroup).The Mwitapile sandstone-hosted stratiform Cu prospect is located in the north eastern part of the Lufilian foreland. The host rock for the Cu mineralization is the Sonta Sandstone of the Ngule Subgroup (Kundelungu Group). A combined remote sensing, petrographic and fluid inclusion microthermometric analysis was performed at Mwitapile and compared with similar analysis previously carried out at Lufukwe to present a metallogenic model for the Mwitapile- and Lufukwe-type stratiform copper deposits. Interpretation of ETM+ satellite images for the Mwitapile prospect and the surrounding areas indicate the absence of NE–SW or ENE–WSW faults, similar to those observed controlling the mineralization at Lufukwe. Faults with these orientations are, however, present to the NW, W, SW and E of the Mwitapile prospect. At Mwitapile, the Sonta Sandstone host rock is intensely compacted, arkosic to calcareous with high silica cementation (first generation of authigenic quartz overgrowths). In the Sonta Sandstone, feldspar and calcite are present in disseminated, banded and nodular forms. Intense dissolution of these minerals caused the presence of disseminated rectangular, pipe-like and nodular dissolution cavities. Sulfide mineralization is mainly concentrated in these cavities. The hypogene sulfide minerals consist of two generations of pyrite, chalcopyrite, bornite and chalcocite, separated by a second generation of authigenic quartz overgrowth. The hypogene sulfide minerals are replaced by supergene digenite and covellite. Fluid inclusion microthermometry on the first authigenic quartz phase indicates silica precipitation from an H₂O–NaCl–CaCl₂ fluid with a minimum temperature between 111 and 182 °C and a salinity between 22.0 and 25.5 wt.% CaCl₂ equiv. Microthermometry on the second authigenic quartz overgrowths and in secondary trails related to the mineralization indicate that the mineralizing fluid is characterized by variable temperatures (Th = 120 to 280 °C) and salinities (2.4 to 19.8 wt.% NaCl equiv.) and by a general trend of increasing temperatures with increasing salinities.Comparison between Mwitapile and Lufukwe indicates that the stratiform Cu mineralization in the two deposits is controlled by similar sedimentary, diagenetic and structural factors and likely formed from a similar mineralizing fluid. A post-orogenic timing is proposed for the mineralization in both deposits. The main mineralization controlling factors are grain size, clay and pyrobitumen content, the amount and degree of feldspar and/or calcite dissolution and the presence of NE–SW to ENE–WSW faults. The data support a post-orogenic fluid-mixing model for the Mwitapile- and Lufukwe-type sandstone-hosted stratiform Cu deposits, in which the mineralization is related to the mixing between a Cu-rich hydrothermal fluid, with a temperature up to 280 °C and a maximum salinity of 19.8 wt.% NaCl equiv., with a colder low salinity reducing fluid present in the sandstone host rock. The mineralizing fluid likely migrated upwards to the sandstone source rocks along NE–SW to ENE–WSW orientated faults. At Lufukwe, the highest copper grades at surface outcrops and boreholes were found along and near to these faults. At Mwitapile, where such faults are 2 to 3 km away, the Cu grades are much lower than at Lufukwe. Copper precipitation was possibly promoted by reduction from pre-existing hydrocarbons and non-copper sulfides and by the decrease in fluid salinity and temperature during mixing. Based on this research, new Cu prospects were proposed at Lufukwe and Mwitapile and a set of recommendations for further Cu exploration in the Lufilian foreland is presented.  相似文献   

金川镍铜矿床数学模型对深部矿化变化趋势的指示     

田毓龙  把多恒  高志武  洪托  陈兴义  卢耀军 《地质与勘探》2008,44(1):82-88

按矿化特征将金川X矿区主矿体分为致密块状特富矿、海绵状富矿和浸染状贫矿.应用MicroMine软件对3类矿化体分别建立了数学模型,并应用距离平方反比法对模型单元块进行了镍、铜品位估值.通过分析和对比矿床数学模型900m至1300m不同水平剖面上的Ni、Cu品位及Ni/Cu比值的变化,得出在X矿区的中部西侧是一个Ni和Cu的矿化中心,并且向深部Cu的矿化强度高于Ni.  相似文献   

碱性磷酸酶在文昌鱼体内的分布     

王锐  张士璀 《中国海洋大学学报(自然科学版)》2001,31(1):81

采用组化方法首次探讨碱性磷酸酶在文昌鱼体内的分布。结果发现 :碱性磷酸酶存在于腹褶部分表皮、围腮腔上皮、构成背鳍腔的内皮、肌膜、中肠腔和肝盲囊腔细胞纹状缘、生殖上皮和精原细胞中  相似文献   

Local Distribution and Seasonal Variation of Fe, Pb, Zn, Cu, Cd, Na, K, Ca, and Mg Concentrations in the Seagrass Cymodocea nodosa (ucria) Aschers. in the Antikyra Gulf, Greece     

P. Malea  S. Haritonidis 《Marine Ecology》1995,16(1):41-56

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梭鱼标准代谢、内源氮排泄与体重和温度的关系   总被引：5，自引：0，他引：5  

线薇薇  朱鑫华 《中国海洋大学学报(自然科学版)》2002,32(3):368-374

在 13.5 ,18,2 1.5 ,2 4和 2 7℃ 5个温度条件下测定了梭鱼 (体重范围 1.88～ 14.0 2 g)的标准代谢率和内源氮排泄率。梭鱼标准代谢率随体重的增加而增加 ,二者的关系为幂函数关系 ;随温度的升高而增加 ,二者的关系为指数关系 ;标准代谢率与体重和温度的关系可用如下方程表示 :RS=0 .12 4 6 W0 .9954 e0 .0 84 1T(r2 =0 .92 2 0 )。梭鱼的氨氮、尿素、总氮及能量的排泄率随体重和温度的增加而增加 ,与体重为幂函数关系 ,与温度的关系为多项式形式。梭鱼氨氮和尿素日排泄率的变幅分别为 0 .15～ 0 .88mg N/d和 0 .0 3～ 0 .2 9mg N/d。不同温度下 ,尿素排泄量占总氮比例在 9.9%～2 2 .4 9%之间 ,随温度升高该值有逐渐增大的趋势。  相似文献   

Distribution of As, Cr and V species in the Po-Adriatic mixing area, (Italy)   总被引：1，自引：0，他引：1  

M. Pettine  D. Mastroianni  M. Camusso  L. Guzzi  W. Martinotti 《Marine Chemistry》1997,58(3-4)

The distribution of dissolved and participate concentrations of As, Cr and V was investigated in the mixing area of the Po river in five surveys over the period March 1992-March 1995. The data obtained indicate noticeable contamination of coastal waters of the northern Adriatic with Cr but not As or V. Total dissolved concentrations for As and V were comparable with oceanic levels but were higher by a factor of 4 for Cr. These results suggest either low anthropogenic inputs of As and V, from terrigenous and atmospheric sources, or efficient removal mechanisms. The investigated metals had low reactivity during freshwater-seawater mixing and the distribution of concentrations in the dissolved and solid phases suggests that the dilution process is the main factor controlling the transport of these metals to the sea in low-to-medium solid transport conditions. Further investigations are required to elucidate the behavior of these metals during high solid transport conditions. Significant changes in the speciation of As occurred during the transition between the two end-member matrices. In the coastal waters of the northern Adriatic, the arsenite fraction in winter, and the arsenite and dimethylarsinate fractions in summer increased with respect to riverine waters. Changes in the speciation of chromium were minor, but also showed a small increase in reduced species in marine waters.  相似文献   

Fe(OH)_3胶体与铜离子作用的研究     

张恩仁  田玉红  张正斌  刘莲生 《热带海洋学报》2001,(4)

使用切向流超滤系统得到粒度较均匀的Fe(OH)3胶体,进而对Fe(OH)3胶体粒子与Cu2 的作用进行了研究,并将实验结果与南沙群岛海区表层水中铜与胶体物质结合状况的调查数据进行了比较分析,得到如下结果:(1)在海水介质中,铜在Fe(OH)3胶体上结合的百分率(pH>5)随pH的升高而下降,随着Fe(OH)3胶体浓度的减小而下降?(2)在天然海水介质中,使铜在Fe(OH)3胶体上结合的百分率在50%-70%的有机物浓度为1.0mg·L-1,有机物浓度的增大使铜与无机胶体结合的百分率有下降的趋势?  相似文献   

重金属锌,铅对菲律宾蛤仔的急性毒性试验   总被引：14，自引：1，他引：14  

刘琼玉  洪华生 《台湾海峡》1997,16(1):50-54

本文研究了必需元素Ｚｎ及非必需元素Ｐｂ对菲律宾蛤仔的急性毒性作用，得到Ｚｎ对其的４８ｈＬＤ５０和９６ｈＬＤ５０分别为１４７．９１、１６．４０ｍｇ／ｄｍ＾３；Ｐｂ对其的４８ｈＬＤ５０和９６ｈＬＤ５０分别为３１．６２、１４．２８ｍｇ／ｄｍ＾３。估算得到Ｚｎ、Ｐｂ对菲律宾蛤仔的安全浓度分别为０．８２、０．７１ｍｇ／ｄｍ＾３。  相似文献