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锌、铝及其合金涂层对钢铁的防护，不仅对阴极起保护作用(Gartland，1987)， 对涂层本身也具有良好的抗腐蚀性能。此外，涂层中金属微粒表面形成的致密氧化膜，也起到了防腐蚀的作用。在不同大气环境下，锌、铝有良好的耐蚀性，其腐蚀速率比钢铁要低得多(李言涛，1998)。采用热喷涂锌、铝及其合金涂层对钢铁构件和构筑物进行长效防护早在20世纪20年代就已开始应用，至今仍是普遍采用的防护措施，并在继续发展(李守本等，1989)。20年代初，法国首先用于海水闸门的防腐；40年代美国用于墨西哥湾的海上井架和海上输油管以及舰船的防腐；60年代英、法、德等国海军将这一技术扩大应用到舰船的上部结构和船壳。而金属热喷涂技术在海洋工程中使用非常有限，第一次使用热喷铝涂层防护近海平台的实例是Conoco公司在北海的Murchison结构上的锥形塔，并且已获得了4a良好的使用效能(Fisher et al.，1987；Shaw et al.，1985)。1984年6月，Hutton张力支柱平台(TLP)在北海下水(水深148 m)安装。系链、升降机和锥形塔均采用火焰热喷涂技术喷涂铝涂层进行防护(Tyson，1985)。1992年6月，Hotton平台使用8a后，对升降机绳索进行观察，在飞溅区没有发现腐蚀现象，也没有检测到褐色渗漏效应(Fisher et al.，1995)。 相似文献
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阐述了改性聚乙烯醇胶水的制备工艺,并以此作彩粒成型剂,应用羟乙基纤维素———膨润土复合增稠剂作抗沉剂和稳定剂,与苯丙乳液等成膜剂、无机颜料等制成无毒、阻燃的水性多彩涂料。 相似文献
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INTRODUCTIONBiologicalfoulingonthehullsofshipsandothersubmergedmarinestructurescausesgreatha~s.Inadditiontodecreasingship'sspeed,andincreasingitsfuelconsumption,biologicalfoulingalsoincreasestheweightofnavigationalbuoys,interfereswithoperatingequipmentandsounddevices,clogsseawaterpipingsystems,adverselyaffectsheat-exchangerperformance,andpromotescorrosionofmetalsurface(HuangandCat,1984).UPtothepresent,antifoulingpaintshaveachievedtheireffectivenessbyreleasingattheirsurfacebiocides,allcom… 相似文献
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Waste red mud and natural pumice/volcanic slag particles were surface modified and their selenium adsorption from waters was investigated. Acid activation/heat treatment of original red mud (ORM) particles significantly increased their micropore and external surface area and cumulative volume of pores. Iron oxide coating of pumice/slags and acid activation of ORM decreased their pHpzc values and increased surface acidity. Selenite/selenate adsorption on iron oxide surfaces and acid activated red mud (AARM) was very fast with approximately first‐order adsorption kinetics. Iron oxide coating of pumice/slag and acid activation of ORM particles significantly enhanced their selenite and selenate uptakes. Maximum Se adsorption capacities as high as 6.3 (mg Se/g adsorbent) were obtained by AARM. The extent of selenate uptakes by the surface modified particles was generally lower than those of selenite. Due to competition among Se species and other background water matrix for iron oxide adsorption sites, reduced selenite/selenate uptakes were found in natural water compared to single solute tests. Higher Se uptakes by iron oxide surfaces were found at pH 7.5 compared to pH 8.9, due to increased electrostatic repulsion among iron oxides and Se species at higher pH. The most effective adsorbents among the tested 17 different particles for Se uptake were AARM and iron oxide coated pumice. Se concentrations less than drinking water standards (5–10 µg/L) can be achieved by these particles. These low‐cost, natural, or recyclable waste particles appear to be promising adsorbents for Se removal after their surface modification. 相似文献
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Long-term earthquake observations at different tunnel sites within a variety of alluvial soil deposits have clearly demonstrated that a tunnel, which exhibits rather flexible nature within its surrounding soil, follows closely the motion of the soil mass during an earthquake. Therefore, coating a tunnel with a soft material will be a possible measure for minimizing damage to tunnels. This paper provides a clear perspective on the feasibility of this measure by using simple solutions to idealized problems. 相似文献
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有机硅涂层表面能对海生物附着的影响 总被引：16，自引：0，他引：16
随着海洋生态环境保护和防止海洋生物污损的要求,人们试图用具有特殊表面性能的涂层取代有毒涂层来减弱或消除海生物的附着。本文通过对含有机硅防污涂层表面能的测量计算,探讨了涂层表面能各分量对附着生物的影响。实验结果表明,在表面能低色散分量的含有机硅涂层上,随涂层与水的相互作用力分量减小,绿藻和玻璃海鞘的污损增加。 相似文献
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