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1.
The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters
and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption
were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the
metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary.
As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of
estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important
in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals
remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L−1). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto
SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated
using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during
mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary
can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural
SPM as a simple surfaced molecule. 相似文献
2.
María Gabriela García Ondra Sracek Diego Sebastián Fernández Margarita del Valle Hidalgo 《Environmental Geology》2007,52(7):1261-1275
The concentration of arsenic measured in groundwater from three aquifers in the study area located in the Eastern Tucuman
province, Argentina, mostly depends on the lithology, but the spatial and temporal variations of concentrations seem to be
also controlled by pH changes, climatic factors, and human perturbations. The highest concentrations of As (more than 1,000 μg
L−1) were found in the shallow aquifer, made of As-rich loess, while the lowest concentrations were measured in the deep confined
aquifer, consisting of alternating layers of alluvial sands/gravels and clays. Intermediate values were measured in the semiconfined
aquifer made of the fluvial sediments deposited in the Salí River valley, that alternate in the upper part of the sedimentary
sequence with layers of loess. Because most of As in the loess is considered to be adsorbed onto Fe-oxyhydroxide coatings,
the increase of pH in the flow direction (west-east) leads to increasing arsenic concentrations towards the eastern border
of the study area. The decomposition of organic wastes poured into the Salí River or associated with local and diffuse sources
of contamination in the eastern part of the study area depletes dissolved oxygen, which leads to the reductive dissolution
of Fe and Mn oxyhydroxides, and to the subsequent release of the adsorbed and co-precipitated As. This process mainly affects
shallow groundwater and the upper part of the semiconfined aquifer. Geochemical and hydrological data also suggest that rising
water table levels at the end of the wet season may also lead to reductive dissolution of As-rich Fe oxyhydroxides in the
shallow aquifer. 相似文献
3.
Melania Jiménez-Reyes Jaime Jiménez-Becerril Marcos Solache-Ríos Perla Tatiana Almazán-Sánchez 《国际泥沙研究》2023,38(4):566-575
The sediment deposited behind a dam(DS) and its inorganic materials(IM-DS) were characterized and used for the removal of praseodymium(Pr) from aqueous solutions. Quartz, albite, and kaolinite were found in the sediment by X-ray diffraction. Kinetic data fit well to a pseudo second-order model, the equilibrium time for DS and IM-DS was 2 h and 3 min, respectively, and the adsorption capacity was higher for Pr/DS(qe= 4.91 mg/g) than for Pr/IM-DS(qe= 3.01 mg/g) in these condi... 相似文献
4.
Pedro Alonso‐Davila Oliva L. Torres‐Rivera Roberto Leyva‐Ramos Raul Ocampo‐Perez 《洁净——土壤、空气、水》2012,40(1):45-53
Pyridine is a very toxic pollutant that has to be removed from wastewater. In this work, adsorption of pyridine on activated carbon cloth (ACC) is studied as a possible alternative for eliminating pyridine from aqueous solution. The ACC was produced from polyacrylonitrile. The adsorption equilibrium data of pyridine on ACC was obtained in a batch adsorber. The experimental data was interpreted with the isotherms of Langmuir, Freundlich, and Prausnitz‐Radke (PR), and the PR isotherm better represented the experimental data. The capacity of ACC for adsorbing pyridine was favored increasing the solution pH from 3 to 6, and this effect was due to the π–π dispersive and electrostatic interactions between the pyridine species in solution and the surface complexes of ACC. The modified Langmuir model fitted reasonably well the influence of pH on the adsorption capacity. In this model was assumed that both neutral pyridine and pyridinium were simultaneously adsorbed on ACC accordingly to the experimental results. The adsorption capacity was almost independent of temperature. The reversibility study revealed that 75% of the pyridine can be desorbed from ACC indicating that part of the pyridine was irreversibly adsorbed, and possibly chemisorbed. 相似文献
5.
Lepidocrocite (γ‐FeOOH) nanoparticles were synthesized from iron(II) sulfate solution and characterized using X‐ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform‐IR (FT‐IR), nitrogen adsorption, and point of zero charge pH (pHPZC) analyses. TEM, XRD, and FT‐IR analyses proved the synthesis of nano‐lepidocrocite. Surface area and pHPZC of the synthesized lepidocrocite were 68.1 m2 g?1 and 4.8, respectively. Utilization of the synthesized lepidocrocite in the adsorption of Lanacron brown S‐GL (LBS‐GL) from aqueous solutions was investigated, and the effect of lepidocrocite dosage, pH, temperature, and contact time on this process were optimized and modeled using response surface methodology approach. The lepidocrocite dosage of 0.015 g, pH 3.5, temperature of 38°C, and contact time of 100 min were determined as optimum adsorption conditions. Isotherm and kinetics of the adsorption process were analyzed at the optimum conditions. The equilibrium data were fitted well to the Langmuir isotherm model. The maximum monolayer adsorption capacity was 528.21 mg g?1. The adsorption process was described by the pseudo‐second‐order kinetic model. Furthermore, the effect of pH on the desorption of LBS‐GL was investigated. High LBS‐GL desorption efficiency was achieved at a high pH value. 相似文献
6.
7.
Water treatment residuals (WTRs) are effective phosphorus (P) immobilizers that have been used in constructed wetlands (CWs). In CWs, dissolved oxygen (DO) levels vary from location to location and fluctuate over time. Therefore, this work accessed the stability of P saturated ferric and alum water treatment residuals (FARs) under low (<1 mg/L), medium (2–4 mg/L), and high (5–8 mg/L) DO levels. In the experiments, which had a 40‐day duration, three stages of P release from the P saturated FARs were observed: an initial rapid P desorption stage, followed by a P re‐adsorption stage, and a P desorption balance stage. The strongest bonding between P and FARs occurred at the low DO level. A limited amount of Fe and Al was released from the P saturated FARs. Interestingly, the P in the FARs tended to transform from the Al bound P to the Fe bound P, and this transformation was stronger at lower DO levels. However, no more than 1.12% of the total P in the P saturated FARs was desorbed under any of these DO levels. Therefore, FARs can be considered as a safe P adsorption medium for CWs. 相似文献
8.
Erdal Eren 《洁净——土壤、空气、水》2010,38(8):758-763
The adsorption behavior of methyl orange (MO) from aqueous solution onto raw bentonite (RB) sample was investigated as a function of parameters such as pH, inorganic anion, contact time, and temperature. The Langmuir and Freundlich adsorption models were applied to describe the equilibrium isotherms. Langmuir adsorption capacity was found to be 34.34 mg/g at pH 4.0. The pseudo‐first‐order, pseudo‐second‐order kinetic, and the intra‐particle diffusion models were used to describe the kinetic data. The values of the energy (Ea), enthalpy (ΔH≠), and entropy of activation (ΔS≠) were calculated as 38.62 kJ/mol, 36.04 kJ/mol, and ?150.05 J/mol K, respectively, at pH 4.0. 相似文献
9.
Meagan Eagle Gonneea Paul J. Morris Henrieta Dulaiova Matthew A. Charette 《Marine Chemistry》2008,109(3-4):250
Over the past decade, radium isotopes have been frequently applied as tracers of submarine groundwater discharge (SGD). The unique radium signature of SGD is acquired within the subterranean estuary, a mixing zone between fresh groundwater and seawater in coastal aquifers, yet little is known about what controls Ra cycling in this system. The focus of this study was to examine controls on sediment and groundwater radium activities within permeable aquifer sands (Waquoit Bay, MA, USA) through a combination of field and laboratory studies. In the field, a series of sediment cores and corresponding groundwater profiles were collected for analysis of the four radium isotopes, as well as dissolved and sediment associated manganese, iron, and barium. We found that in addition to greater desorption at increasing salinity, radium was also closely tied to manganese and iron redox cycling within these sediments. A series of laboratory adsorption/desorption experiments helped elucidate the importance of 1) contact time between sediment and water, 2) salinity of water in contact with sediment, 3) redox conditions of water in contact with sediment, and 4) the chemical characteristics of sediment on radium adsorption/desorption. We found that these reactions are rapid (on the order of hours), desorption increases with increasing salinity and decreasing pH, and the presence of Fe and Mn (hydr)oxides on the sediment inhibit the release of radium. These sediments have a large capacity to sorb radium from fresh water. Combined with these experimental results, we present evidence from time series groundwater sampling that within this subterranean estuary there are cyclic periods of Ra accumulation and release controlled by changing salinity and redox conditions. 相似文献
10.
Tapan K. Saha Nikhil C. Bhoumik Subarna Karmaker Mahmooda G. Ahmed Hideki Ichikawa Yoshinobu Fukumori 《洁净——土壤、空气、水》2011,39(10):984-993
Adsorption of reactive black 5 (RB5) from aqueous solution onto chitosan was investigated in a batch system. The effects of solution pH, initial dye concentration, and temperature were studied. Adsorption data obtained from different batch experiments were modeled using both pseudo first‐ and second‐order kinetic equations. The equilibrium adsorption data were fitted to the Freundlich, Tempkin, and Langmuir isotherms over a dye concentration range of 45–100 µmol/L. The best results were achieved with the pseudo second‐order kinetic and Langmuir isotherm equilibrium models, respectively. The equilibrium adsorption capacity (qe) was increased with increasing the initial dye concentration and solution temperature, and decreasing solution pH. The chitosan flakes for the adsorption of the dye was regenerated efficiently through the alkaline solution and was then reused for dye removal. The activation energy (Ea) of sorption kinetics was estimated to be 13.88 kJ/mol. Thermodynamic parameters such as changes in free energy (ΔG), enthalpy (ΔH), and entropy (ΔS) were evaluated by applying the van't Hoff equation. The thermodynamics of reactive dye adsorption by chitosan indicates its spontaneous and endothermic nature. 相似文献