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1.
Simulations of seasonal variations of sulfur compounds in the remote marine atmosphere 总被引：1，自引：0，他引：1
A photochemical box model is used to simulate seasonal variations in concentrations of sulfur compounds at latitude 40° S. It is assumed that the hydroxyl radical (OH) addition reaction to sulfur in the dimethyl sulfide (DMS) molecule is the predominant pathway for methanesulfonic acid (MSA) production, and that the rate constant increases as the air temperature decreases. Concentration of the nitrate radical (NO3) is a function of the DMS flux, because the reaction of DMS with NO3 is the most important loss mechanism of NO3. While the diurnally averaged concentration of OH in winter is a factor of about 8 smaller than in summer, due to the weak photolysis process, the diurnally averaged concentration of NO3 in winter is a factor of about 4–5 larger than in summer, due to the decrease of DMS flux. Therefore, at middle and high latitudes in winter, atmospheric DMS is mainly oxidized by the reaction with NO3. The calculated ratio of the MSA to SO2 production rates is smaller in winter than in summer, and the MSA to non-sea-salt sulfate (nssSO4
2-) molar ratio varies seasonally. This result agrees with data on the seasonal variation of the MSA/nssSO4
2- molar ratio obtained at middle and high latitudes. The calculations indicate that during winter the reaction of DMS with NO3 is likely to be a more important sink of NOx (NO+NO2) than the reaction of NO2 with OH, and to serve as a significant pathway of the HNO3 production. If dimethyl sulfoxide (DMSO) is produced through the OH addition reaction and is heterogeneously oxidized in aqueous solutions, half of the nssSO4
2- produced in summer may be through the oxidation process of DMSO. It is necessary to further investigate the oxidation products by the reaction of DMS with OH, and the possibility of the reaction of DMS with NO3 during winter. 相似文献
2.
分析了威德尔海周边雪冰和大气中ＭＳＡ和ｎｓｓＳＯ２－４浓度资料。结果表明,威德尔海是造成这一地区大气中高含量生物硫化物的“源”,其周边岛屿及冰架表层雪冰记载和反映了大气中生物硫化物的空间分布和季节变化特点。源区产出硫化物的强度存在显著差异：靠近南极半岛一侧高于靠近Ｆｉｌｃｈｎｅｒ－Ｒｏｎｎｅ冰架一侧。尽管诸多因素对输运和沉降过程发生影响,表层积雪ＭＳＡ和ｎｓＳＯ２－４浓度仍呈现出很有规律性的空间分布：随沉降地点离海距离和海拔高度的增加,浓度值递减;但在一定海拔之下,“高程效应”不显著。冰芯中ＭＳＡ浓度垂向分布显示出季节分配“滞后”现象,在表层表现为受天气条件制约的输运过程造成的相位差,在深层则归因于有待验证的“迁移”机制作用的结果。大气和雪冰样品对比研究结果表明,在类似威德尔海这样的高纬地区,大气中的ＳＯ２－４和ＭＳＡ“信号”在雪冰样品中会遭到不同程度的减弱。但就空间变化趋势和季节分布而言,表层雪冰仍是大气中组分（在本文是ＳＯ２－４和ＭＳＡ）的良好载体。十分接近的大气和雪冰ＭＳＡ对ｎｓｓＳＯ２－４（或ＳＯ２－４）比率证实,这两种大气组分在由大气洗净和沉降到冰雪过程中只发生微弱的分离作用。这也就是大气和雪冰中 相似文献
3.
Methanesulphonate was investigated as a potential contributor to the sulphur budget based on the analysis on Antarctic snow/ice from Coffins Ice Cap, King George Island (62°10' S, 58°50,W). The anion was found to be present at a mean concentration of 0. 17 μeq. L-1 with a maximum of 0.73 μeq. L-1. A distinct seasonal variation exists in the top 10 m of the core, equivalent to more than two years of deposition. Dating resulted from δ18O profile suggests that the principal peaks of methanesulphonate are associated with snow deposited in autumn and secondary peaks in spring. The seasonal patterns of methanesulphonate in the subantarctic snow displays a phase difference from that observed in marine air from low and middle latitudes. 相似文献
4.
中国第二次北极科学考察沿线气溶胶成分分析 总被引：7，自引：2，他引：5
对2003年7月15~9月28日间中国第二次北极科学考察沿线所采集的气溶胶样品进行分析,获得了Na+、NH4+ 、Ca2+、Cl-、MSA、SO42- 等11种离子的浓度数据(文中使用当量浓度).根据相关分析, 可将11种离子分为3类: 海盐源离子, 包括Na+、Mg2+、K+、Ca2+、Cl-、SO42-; 人为源, 包括NH4+ 、NO3-; 其它源, 包括 CH3COO-、MSA、C2O42-. 气溶胶以海盐气溶胶为主, Cl-、Na+ 离子分别是阴阳离子中含量最大的离子, (Na+ +Cl-)对气溶胶载量(所测定的阴阳离子的总和)的贡献平均为60.2%, 占气溶胶总量的一半以上. NH4+ /SO42- 的比值的平均为0.45, 根据当地的大气环境和气溶胶的离子平衡, 认为气溶胶样品中NH4+ 和 SO42- 主要是以 NH4HSO4的形式结合. 根据考察沿线 NO3- 浓度的变化, 把考察沿线大致分为3个区: 日本海区, 中值为15.2 neq·m-3; 鄂霍次克海及白令海区, 中值为1.8 neq·m-3; 北冰洋区, 其浓度较低, 中值为0.4 neq·m-3. 考察沿线白令海是MSA的高产区. 相似文献
5.
During a cruise aboard the R/V Hakuho-maru in the northwestern North Pacific in the summer of 1998 the particle number concentrations
and the major ionic components of size fractionated aerosols were measured to investigate the aerosol produced by marine biological
activity. Continuous low concentrations of nitrate (<1.8 nmol m−3), similar to the marine air background level, were found over the northwestern North Pacific (40–45°N) and the Sea of Okhotsk
(44–45°N). Over the Sea of Okhotsk, a high concentration of chlorophyll-a (5.4 mg m−3) in seawater was observed, and atmospheric concentrations of non sea-salt (nss-) sulfate (44 nmol m−3), methane sulfonic acid (MSA) (1.8 nmol m−3) and particle number in the size range of 0.1 < D < 0.5 μm (199 cm−3) were found to be 9, 7, and 2 times, respectively, higher than those in the background marine air. The increase in particle
number concentrations mainly in the size range of 0.2 < D < 0.3 μm was likely caused by the increase of biogenic sulfate over the high productive region of the Sea of Okhotsk. In
humid air conditions (R.H. > 96%), the increased biogenic sulfate that condensed the large amount of water vapor would not
have sufficient solute mass to activate as cloud condensation nuclei (CNN) and would remain as aerosol particles in the marine
air with frequent sea-fogs over the high productive region. Biogenic sulfate originating from dimethyl sulfide (DMS) would
gradually grow into the CCN size and continuously supply a great number of CCN to the marine air in the northwestern North
Pacific.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
6.
The relationship between exports and economic growth is a paradigmatic element of modern economic growth policy, despite the absence of strong evidence of a connection. Until recently, data on export production prevented an extensive empirical analysis of metropolitan-scale trade. This article examines the export growth dynamics across large metropolitan statistical areas (MSAs) within the southern United States, a region that has been impacted by economic globalization. These analyses found that some Southern metropolitan areas differ from regional and national averages in selected measures of export performance. Additionally, the export performance of Southern cities was not correlated with all indicators of economic development. This article concludes that export dynamics should be viewed increasingly from an urban frame, with particular emphasis on the production of globally consumed knowledge products and advanced manufacturing. Moreover, export policy should be directed toward the individual strengths of urban regions. 相似文献
7.
冰芯中MSA含量具有季节性变化规律, 夏季出现峰值, 冬季为低值. 一定地区MSA高含量和海冰扩展存在相关关系, 有的地区MSA含量还与ENSO事件有一定相关性. MSA/ nssSO42-比值对温度和来源区域都有很好的指示意义. 在一定的条件下冰芯中的MSA可以发生迁移和再定位, 由此也对利用冰芯MSA含量反演当时大气气溶胶中成分含量的准确性提出了质疑. 总结了近几年来冰芯研究中的MSA和nssSO42-, 特别是极地冰芯MSA的研究进展, 并对利用MSA来研究全球变化的前景进行了预测和展望. 相似文献
8.
2015年4月25日尼泊尔8．1级强烈地震前后,拉萨地磁台(以下简称“拉萨台”)地电场观测数据出现了长时间、大幅度异常变化。在对拉萨台地电场观测条件、观测系统以及观测结果进行初步讨论的基础上,利用“能量合成累加”和“MSA功率谱分析”等数据处理方法,从“时间域”和“频率域”两个方面,对该异常变化的主要特征和演化过程进行了分析。结果显示,尼泊尔8.1级地震前后,拉萨台的地电场观测数据异常变化,经历了“趋势变化一扰动变化一发震期一恢复期”等发展阶段,以及“低频变化一高频变化一平稳变化高频变化”等演化过程。综合分析认为,拉萨台地电场观测异常变化特征和演化过程,与相关现象和机理研究结果基本吻合,能够完整反映强烈地震孕育、发生和发展全过程,是具有一定客观性、典型性和代表性的珍贵资料。 相似文献
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