Possible chemical structures and biological precursors of different vitrinites in coal measure in Northwest China     

Dayong Liu  Ping'an Peng   《International Journal of Coal Geology》2008,75(4):204-212

Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state ¹³C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in ¹³C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in ¹³C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and ¹³C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite.  相似文献   

Study of macroaggregate composition using FT-IR and H-NMR spectroscopy     

N. Kovac  O. Bajt  J. Faganeli  B. Sket  B. Orel 《Marine Chemistry》2002,78(4)

Mucous macroaggregates, recently observed in the northern Adriatic in summer of 1997 and late spring of 2000, are primarily the product of phytoplankton (diatom) exudates during favourable environmental conditions in late spring, and can be viewed as macrogels. The FT-IR and ¹H-NMR spectra of macroaggregate samples from the northern Adriatic, collected in different formation stages in July 1997, August 1997, September 1997 and June 2000, as well as of cultured diatom Skeletonema costatum, showed that they are similar and composed of aliphatic components and polysaccharides bonded through carboxylic and amide groups, and organosilicon compounds. The stability of macrogels of macroaggregates is, according to FT-IR and X-ray analyses, most probably enhanced by interactions with entrapped particles of calcite, quartz and clay minerals. These organic-mineral associations seem to be important for mucous phenomena. According to ¹H-NMR spectra, the temporal differences in macroaggregate composition show a relative increasing percentage of organosilicon compounds and aliphatic components bonded to carbohydrates through ester and amide groups, and an increasing ratio between aliphatic structures and carbohydrates. This indicates that aliphatic chains bonded to Si and carbohydrates may contribute to the persistence and stability of macroaggregates in the summer stratified waters in the northern Adriatic, while the temporal decrease of carbohydrate content is most probably due to microbial and photochemical degradation of algal reserve polysaccharides.  相似文献   

利用核磁共振方法研究水文地质问题及应用实例   总被引：14，自引：1，他引：14  

李振宇  潘玉玲  张兵  许顺芳  袁照令  李大明  顾涛 《水文地质工程地质》2003,30(4):50-54

地面核磁共振找水方法是目前唯一直接找水的物探新方法。本文在介绍NMR方法原理的基础上,结合NMR方法技术特点和在中国的应用实例,论述了NMR方法在探测地下水、地下水资源评价等方面的效果,并提出了进一步开展新方法的工作建议。  相似文献   

磁共振用于医学成像与地面找水方法的技术对比研究     

李俊丽  李振宇  李进站  潘玉玲 《CT理论与应用研究》2003,12(1):39-42

目的 医学核磁共振与地面核磁共振找水是核磁共振技术应用的不同领域。本文通过对二者在方法原理、技术、应用等方面的对比研究，提出了地面核磁共振找水工作建议。  相似文献   

高岭石—莫来石反应系列：^27Al和^29SiMAS NMR研究   总被引：21，自引：2，他引：21  

郭九皋  何宏平 《矿物学报》1997,17(3):250-259

根据艰我国八个不同成因和特征的高岭土样品在４５０－１４５０℃热处理产物的ＭＡＳ ＮＭＲ谱和ＸＲＤ，ＩＲ，ＤＴＡ等研究结果，结合有关资料讨论了高岭石－莫来石反应序列的几个重要问题：１．高岭石的结构，尤其是五配位铝；２．９８０℃放热峰后的高温相是γ－Ａｌ２Ｏ３而不是Ａｌ－Ｓｉ尖晶石；３．对于莫来石化过程，认为初始莫来石８５０－９５０℃变高岭石形成，二次莫来石由分凝的ＳｉＯ２和γ－Ａｌ２Ｏ３在１２００－  相似文献   

Characterizing the properties of dissolved organic matter isolated by XAD and C-18 solid phase extraction and ultrafiltration   总被引：1，自引：0，他引：1  

Sara B. Schwede-Thomas  Yu-Ping Chin  Karl J. Dria  Patrick Hatcher  Edith Kaiser  Barbara Sulzberger 《Aquatic Sciences - Research Across Boundaries》2005,67(1):61-71

  相似文献   

围压和孔隙结构对不同粒级砂岩孔隙度渗透率的影响实验研究     

张丽华  潘保芝  单刚义 《地质与资源》2018,27(3):288-292

孔隙度和渗透率是储层评价的两个重要参数.岩石毛管压力曲线和核磁共振T2谱图是描述储层微观结构特征的重要参数.通过测量不同压力条件下岩心样品的孔隙度和渗透率,得到了孔隙度和渗透率随压力的变化情况.实验结果表明：孔隙度和渗透率随着压力的增加而降低,并且与压力服从对数函数变化规律.不同孔隙度渗透率区间的砂岩样品,孔隙度和渗透率随着压力变化的趋势不同.通过测量不同粒级砂岩样品的毛管压力曲线和核磁共振T2谱图,证实了孔隙结构对孔隙度和渗透率的影响,微观孔隙结构是决定渗透性好坏的关键因素.  相似文献   

Quantitative characterization of different coal rank reservoirs permeability based on NMR and X-CT technology     

GUO Guangshang  XING Liren  LI Hao 《中国地质调查》2021,7(6):103-108

With the increasing development of coalbed methane (CBM) field, the quantitative characterization and evaluation of coal reservoir physical properties is becoming more and more important to CBM scale development. In order to solve the limitations of conventional methods for testing coal reservoir physical properties, the authors used the high-tech technologies such as nuclear magnetic resonance technology and CT scanning technology to effectively solve the problems of in-situ and integrity of rock samples and acquire the porosity and permeability. Nuclear magnetic resonance and CT scanning experiments of coal samples were carried out to rapidly obtain the pore type, pore size distribution and connectivity, effective porosity, spatial distribution of pore fissures and other refined coal reservoir physical parameters, based on the samples of middle and low rank coal in Shenfu block and high rank coal in Shizhuangnan block. So a set of quantitative characterization analysis technology that can be applied to coal reservoirs with different coal rank was formed.  相似文献   

Dynamic metabolite alterations of Portunus trituberculatus during larval development     

SHI Ce  ZENG Tinglan  LI Ronghua  WANG Chunlin  YE Yangfang  MU Changkao 《海洋湖沼学报（英文）》2019,(1):361-372

A mass mortality often occurs from molting to the megalopa stage during the larval development of the swimming crab Portunus trituberculatus. Larvae with insuffcient nutrient accumulation during the zoeal stages are probably unable to develop into juvenile swimming crabs. However, the nutritional information such as the primary metabolites is scarce for P. trituberculatus larvae. The aim of this work is to obtain an insight into the metabolite traits of P. trituberculatus at early developmental stages. 1 H nuclear magnetic resonance spectroscopy coupled with multivariate data analysis was used to determine how the metabolite pro?les shift during larval development in P. trituberculatus. Our results show that the trend of total metabolites exhibited a rise from zoea 1 to zoea 3, followed by a drop from zoea 4 to megalopa and recovery during the ?rst juvenile stage. A large-scale depletion of total metabolites in the zoea 4 and megalopa stages suggests a deep depression of metabolic activity, which may be linked to the mass mortality from molting to the megalopa stage. These ?ndings provided essential metabolic information about the larval development of P. trituberculatus and important clues for understanding the nutritional requirements of P. trituberculatus in early developmental stages.  相似文献   

基于NMR的库区滑坡三维稳定性数值模拟   总被引：4，自引：2，他引：2  

胡新丽  唐辉明  马淑芝  章广成 《地球科学》2006,31(2):279-284

传统的勘探、测试手段, 难以获取可靠的滑坡岩土体水文参数, 直接影响滑坡研究的建模、评价工作.应用核磁共振找水方法并结合其他方法建立滑坡三维地质模型, 并提出基于NMR技术的库区滑坡稳定性研究思路.以赵树岭滑坡进行测试, 获取了岩土体的水文地质参数数据, 确定出该滑坡具有两层地下水, 上部潜水含水层, 下部微承压含水层; 具有两层滑面.该技术的分析结果与钻孔数据吻合较好, 可为建立符合实际的滑坡模型提供可靠依据.利用自编渗流-应力耦合有限元程序和ANSYS进行了145 m、175 m及175m降至145 m滑坡的稳定性模拟.结果表明: 145 m及175 m水位, 该滑坡整体处于稳定状态, 前缘随水位抬升局部破坏范围扩大; 175 m降到145 m时, 坡整体稳定性接近极限状态.且滑坡后缘局部位置出现小规模变形破坏的可能.   相似文献