水样及生物体内微量锌、锰、硒的极谱催化波同时测定   总被引：1，自引：0，他引：1  

刘爱骅  王瑾  杨孙楷 《台湾海峡》1996,(3)

本文提出了在酒石酸盐-乙二胺-高氯酸-亚硫酸钠-高碘酸钾-EDTA体系中同时测定微量锌、锰、硒的极谱催化波，波峰敏锐，波形稳定。Zn2 浓度在0．4～40μg／dm3，Mn2 浓度在1．6～80μg／dm3，Se（Ⅳ）浓度在0．02～3．0μg／dm3范围内浓度与峰电流呈线性关系。取天然水样平行12份测定，变异系数在10％以内。  相似文献   

Selenium attenuation via reductive precipitation in unsaturated waste rock as a control on groundwater impacts in the Idaho phosphate patch     

《Applied Geochemistry》2016

Phosphate mining in southeastern Idaho has historically resulted in the release of dissolved metals and inorganics to groundwater and surface water, primarily due to leachate from waste rock in backfilled pits and overburden storage piles. Selenium (Se) is of particular concern due to its high concentration in leachate and its limited attenuation downgradient of source zones under oxic conditions. Assessments of potential groundwater/surface water impacts from waste rock typically involve laboratory characterization using saturated and unsaturated flow columns packed with waste rock. In this study, we compare the results of saturated and unsaturated column tests with groundwater quality data from the Mountain Fuel, Champ, South and Central Rasmussen Ridge Area (SCRRA), Smoky Canyon, Ballard, Henry, and Enoch Valley Mines, to understand the release and attenuation of Se in different geochemical environments. Column studies and field results demonstrate that the ratio of aqueous Se to aqueous sulfate (Se:SO₄ ratio) is a useful metric for understanding Se release and attenuation, where the extent of sulfate reduction is much less than Se reduction. Comparison of dissolved Se and sulfate results suggests that the net leachability of Se from unsaturated waste rock is variable. Overall, Se concentrations in groundwater directly beneath waste rock dumps is not as high as would be predicted from unsaturated columns. Lower Se:SO₄ ratios are observed immediately beneath waste rock dumps and backfilled pits relative to areas receiving shallow waste rock runoff. It is hypothesized that Se released in the oxic upper portions of the waste rock is subsequently attenuated via reductive precipitation at depth in unsaturated, low-oxygen portions of the waste rock. This highlights an important mechanism by which Se may be naturally attenuated within waste rock piles prior to discharge to groundwater and surface water. These results have important implications for mining practices in the region. A better understanding of Se dynamics can help drive waste rock management during active mining and capping/water management options during post-mining reclamation.  相似文献   

多元素与大骨节病关系的稳定性研究     

侯少范  王卫中 《地理研究》1994,13(4):28-35

对内蒙古三个典型大骨节病区<15岁人群发中21个元素和病情进行了三年连续定期观察,统计分析结果表明:(1)病区食物对人体元素含量的影响可以分为二种情况,一是元素在食物链中含量过低,食物的变化虽可使机体该元素发生变化,但变幅甚小,致使其代谢处于缺乏状态;另一类是机体内这些元素的含量因食物的改变而发生较大变化,显示这些元素与病情无内在联系.(2)对发中硒等2l个元素与病情分别作单相关和多元逐步回归分析,结果证明,硒缺乏是导致大骨节病早期病变的基本因素,而其它元素与病情的关系具有不确定性.  相似文献   

单纯克山病病区与单纯大骨节病病区生态化学环境的对比研究   总被引：6，自引：0，他引：6  

李日邦  谭见安 《地理学报》1995,50(3):272-278

本文对云南省牟定县申平村单纯克山病病区和陕北榆林县蟒坑村单纯大骨节病病区的生态化学环境进行了对比研究，表明两地生态化学环境仍处于低Ｓｅ水平。申平村人群仍有潜在型克山病病例，蟒坑村人群的骨质病变则出现很高的Ｘ线阳性检出率，说明两地的致病因子仍然活跃，从生态系物质含Ｓｅ量看出，蟒坑村的缺Ｓｅ程度较申平村高。此外，单纯克山病病区申平村土壤，粮食，人发中的Ａｓ明显高于蟒坑村和非病区。为此，从Ａｓ与Ｓｅ具有  相似文献   

暖温带地理景观中土壤硒的分异特征   总被引：17，自引：0，他引：17  

侯少范  李德珠等 《地理学报》1992,47(1):31-39

本文按垂直自然带谱研究了暖温带地理景观中山地草旬土、山地棕壤、山地淋溶褐土和潮土中硒的分异特征。结果表明：（1）硒在土剖面上的分异，除受生物富集的影响外，淋溶和粘人作用强烈地制约着硒在剖面上的迁移；（2）不同机械组分中的硒含量以粘粒中最高，呈明显的粘粒＞细粉粒＞中粉粒＞砂粒序列。因此，成土过程中，不同机械组分以及次生或们生矿物和垂直运动和自然分选作用对土壤硒的地理分异具有非常重要的作用。（3）易于淋溶失的有机态或钙结合的硒对所研究的土壤表层硒的贡献都大于50％。提出淋溶作用是我国低硒带形成的主要外营力。  相似文献   

Geological factors influencing the concentration of trace elements in the Philippi peatland, eastern Macedonia, Greece     

K. Christanis  A. Georgakopoulos  J. L. Fernndez-Turiel  A. Bouzinos 《International Journal of Coal Geology》1998,36(3-4)

Six peat samples obtained from the Holocene and the Weichselian of the Philippi peat deposit, eastern Macedonia, Greece, were analyzed for 48 trace elements by Inductively Coupled Plasma–Mass Spectrometry (ICP–MS). The ash contents of these samples were also determined. Most of the trace elements are associated with the minerals in the peat, while Ge, Mo, Pb, Se, Ta, Tl, U, and W display a greater affinity with the organic matter. Compared with crustal averages (Clarke concentrations), the Philippi peat is enriched in some elements (Ag, As, Au, Cd, Mo, Se, Te, U, and W) because of the respective mineralizations in the area. The Philippi peat is also enriched in Cr, Cu, Mo, Pb, Sc, Sn, T, V, Y, and Zn in comparison with typical fen peats, as well as in As, Cr, Mo, Se, and U in comparison with typical coals. Climatic and hydrogeological conditions strongly influenced the peat-forming environment resulting in a differentiation between Holocene and Weichselian peat. Generally, the Holocene peat contains lower concentrations of trace elements in the northern and southern part of the fen, than the Weichselian one. The opposite trend is observed in the fen area close to the western basin margins.  相似文献   

Selenium and other trace element in phosphorites: A comparison between those of the Bayovar-Sechura and other provenances     

J. Bech  M. Suarez  F. Reverter  P. Tume  P. Sánchez  N. Roca  A. Lansac 《Journal of Geochemical Exploration》2010

Data of trace element composition of phosphorites are scarce and incomplete. Phosphorites of different origins can vary substantially in trace element contents. In this paper 20 trace element concentrations of 35 sample phosphorites are reported. The geographical provenance is: Bayovar-Sechura (Peru), Khouribga, Youssoufia and Boucraa (Morocco), Gafsa (Tunisia), Florida (USA), Idaho and Phosphoria Formation (USA), North Carolina (USA), Algeria, Israel, Senegal, Syria and Togo. Aqua regia extracts were used to estimate the “pseudototal” values, following standard procedures (ISO 11466, 2002) and measured by ICP-AES and ICP-MS.  相似文献   

Selenium content in soils from Murcia Region (SE,Spain)     

C. Pérez-Sirvent  M.J. Martínez-Sánchez  M.L. García-Lorenzo  J. Molina  M.L. Tudela  W. Mantilla  J. Bech 《Journal of Geochemical Exploration》2010

The objective of this study was to determine the selenium content in soils from the Region of Murcia (SE, Spain) and to study the possible relationship between mineralogical composition, soil properties and selenium content. In addition, generic reference level (GRL) for selenium was determined according to Spanish legislation. For this study, 490 samples were selected in areas subjected to agricultural activity or abandoned agricultural soils with natural vegetation. Five different zones were established in order to study selenium variability. Four different mineralogical groups were established, based on significant relationship with the mineralogical composition, and each sample was included in one mineralogical group. The results showed that the concentration of selenium is correlated with the electrical conductivity, sulphate content and with the mineralogical composition, particularly positively with quartz and in a negative way with calcite percentage. In addition, selenium level was positively correlated with the phyllosilicate content. Established GRL for selenium varies with the mineralogical group, having a great transcendence from the legal and economic points of view.  相似文献   

Selenium concentration in food and blood of residents of Abeokuta Metropolis,Southwestern Nigeria     

Adewole Michael Gbadebo  Olusegun O. BabalolaFelicia L. Ajigbotesho 《Journal of Geochemical Exploration》2010

Selenium like any other element can both be essential and toxic depending upon the concentration at which it occurs in human diet. This paper assessed the level of this trace element in twenty different (20) types of locally produced food items around Abeokuta town and the blood obtained from the antecubital fossa vein of eighty-eight (88) healthy adults resident in Abeokuta.  相似文献   

Freezing of sediments inappropriate for pore water selenium analysis     

Jung RF  Batley GE 《Marine pollution bulletin》2004,49(4):295-298

The common practice of freezing sediment cores for later chemical investigation was shown to be inappropriate for samples containing selenium. Pore waters from frozen estuarine sediment cores contained up to eighty times the selenium content of those extracted from chilled but unfrozen cores. Experiments suggested that the increase in selenium concentrations resulted from rupturing the cells of selenium-accumulating bacteria present in the samples.  相似文献